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Journal of Sol-Gel Science and Technology

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26-04-2019 | Original Paper:Sol-gel and hybrid materials with surface modification for applications

Amine functionalized mesoporous hybrid materials: influence of KCl and xylene on the textural characteristics and CO₂ sorption

Authors: Nina Velikova, Ivanka Spassova

Published in: Journal of Sol-Gel Science and Technology | Issue 2/2019

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Abstract

Amine-functionalized mesoporous silica materials were prepared by sol–gel method in the system tetraethylortosilicate: bis[(3- trimethoxysilyl)propyl]amine (TEOS: BTPA). The hybrid amine functionalized silica materials were synthesized by co-condensation reaction between TEOS and BTPA precursors in acidic media. Soft template approach for pore formation was applied and as a structural directing agent was used surfactant Pluronic P123. For improving of pore ordering and textural characteristics xylene and KCl were used and their influence on the structural and morphological characteristics was investigated by FTIR, ¹³C CP MAS NMR, ²⁹Si MAS NMR, BET, PSD and XRD techniques. CO₂ adsorption properties of the synthesized amine functionalized hybrid materials were investigated. The simultaneous presence of xylene and KCl leads to improvement of the pore ordering, increasing of the textural characteristics values and formation of cylindrical pores. The determined heats of CO₂ adsorption evidenced chemisorption process between CO₂ and the amine groups of the hybrid materials.

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Title: Amine functionalized mesoporous hybrid materials: influence of KCl and xylene on the textural characteristics and CO2 sorption
Authors: Nina Velikova
Ivanka Spassova
Publication date: 26-04-2019
Publisher: Springer US
Published in: Journal of Sol-Gel Science and Technology / Issue 2/2019
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-019-04998-1

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