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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 3/2015

01.06.2015 | Original Paper

Bridged mesoporous silsesquioxanes as potential CO2 adsorbents

verfasst von: Odette Esam, Guannan Zhou, Aleksey Vasiliev

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2015

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Abstract

Mesoporous amino-functionalized adsorbents for post-combustion CO2 capture were synthesized by grafting and sol–gel methods. The silsesquioxane obtained by polycondensation of bis[3-(trimethoxysilyl)-propyl]amine without a cross-linker had the highest amount of surface amino groups. Their content was 8.4 times higher than in the grafted material prepared with the same precursor. All obtained materials were tested in CO2 reversible adsorption from a gas stream. The bridged silsesquioxane adsorbent had the adsorption capacity 4.7 times higher than the grafted sample obtained from the same precursor. Porosity study of this material revealed wide pore size distribution with notable fraction of macropores. The nature of adsorbed species was determined from the FTIR spectrum after adsorption. It was found that CO2 formed carbamate and bicarbonate species on the surface.

Graphical Abstract

Vorheriger Artikel Formation and characterization of γ-Fe2O3@SiO2@Ag
Nächster Artikel Three modes of high-efficient photocatalysis using composites of TiO2-nanocrystallite-containing mesoporous SiO2 and Au nanoparticles

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Literatur
1.
Gray ML, Soong Y, Champagne KJ, Pennline H, Baltrus JP, Stevens RW, Khatri R, Chuang SSC, Filburn T (2005) Improved immobilized carbon dioxide capture sorbents. Fuel Process Technol 86:1449–1455CrossRef
2.
Choi S, Drese JH, Jones CW (2009) Adsorbent materials for carbon dioxide capture from large anthropogenic point sources. ChemSusChem 2:796–854CrossRef
3.
Abu-Khader MM (2006) Recent progress in CO2 capture/sequestration: a review. Energy Source Part A 28:1261–1279CrossRef
4.
Rao AB (2007) Technologies: separation and capture. In: Wilson EJ, Gerard D (eds) Carbon capture and sequestration: integrating technology, monitoring, regulation. Wiley, Weinheim
5.
6.
Steeneveldt R, Berger B, Torp TA (2006) CO2 capture and storage: closing the knowing-doing gap. Chem Eng Res Design 84:739–763CrossRef
7.
Yang HQ, Xu ZH, Fan MH, Gupta R, Slimane RB, Bland AE, Wright I (2008) Progress in carbon dioxide separation and capture: a review. J Environ Sci China 20:14–27CrossRef
8.
Benson SM, Orr FM (2008) Carbon dioxide capture and storage. MRS Bull 33:303–305CrossRef
9.
Dumée L, Scholes C, Stevens G, Kentish S (2012) Purification of aqueous amine solvents used in post combustion CO2 capture: a review. Int J Greenh Gas Con 10:443–455CrossRef
10.
Ma’mun S, Svendsen HF, Hoff KA, Juliussen O (2006) Selection of new absorbents for carbon dioxide capture. Energy Convers Manag 48:251–258CrossRef
11.
Shao R, Stangeland A (2009) Amines used in CO2 capture—health and environmental impacts. Belonna Report Sept 2009, The Bellona Foundation, Oslo
12.
Gray ML, Soong Y, Champagne KJ, Pennline HW, Baltrus J, Stevens RW, Khatri R, Chuang SC (2004) Capture of carbon dioxide by solid amine sorbents. Int J Environ Technol Manag 4:82–88CrossRef
13.
Hiyoshi N, Yogo K, Yashima T (2004) Adsorption of carbon dioxide on amine modified SBA-15 in the presence of water vapor. Chem Lett 33:510–511CrossRef
14.
Huang HY, Yang RT, Chinn D, Munson CL (2003) Amine-grafted MCM-48 and silica xerogel as superior sorbents for acidic gas removal from natural gas. Ind Eng Chem Res 42:2427–2433CrossRef
15.
Zheng F, Tran DN, Busche BJ, Fryxell GE, Addleman RS, Zemanian TS, Aardahl CL (2005) Ethylenediamine-modified SBA-15 as regenerable CO2 sorbent. Ind Eng Chem Res 44:3099–3105CrossRef
16.
Husing N (2007) Porous hybrid materials. In: Kickelbick G (ed) Hybrid materials: synthesis, characterization, and applications. Wiley, Weinheim
17.
Loy DA (2007) Sol-gel processing of hybrid organic-inorganic materials based on polysilsesquioxanes. In: Kickelbick G (ed) Hybrid materials: synthesis, characterization, and applications. Wiley, Weinheim
18.
Sanchez C, Julian B, Belleville P, Popall M (2005) Applications of hybrid organic-inorganic nanocomposites. J Mater Chem 15:3559–3592CrossRef
19.
Stein A, Melde BJ, Schroden RC (2000) Hybrid inorganic-organic mesoporous silicates—nanoscopic reactors coming of age. Adv Mater 12:1403–1419CrossRef
20.
Bollini P, Didas SA, Jones CW (2011) Amine-oxide hybrid materials for acid gas separations. J Mater Chem 21:15100–15120CrossRef
21.
Hoffmann F, Cornelius M, Morell J, Froba M (2006) Silica-based mesoporous organic–inorganic hybrid materials. Angew Chem Int Ed 45:3216–3251CrossRef
22.
Vasiliev AN, Golovko LV, Trachevsky VV, Hall GS, Khinast JG (2009) Adsorption of heavy metal cations by organic ligands grafted on porous materials. Micropor Mesopor Mater 118:251–257CrossRef
23.
Vassylyev O, Chen J, Panarello AP, Khinast JG (2005) Catalytic properties of several supported Pd(II) complexes for Suzuki coupling reactions. Tetrahedron Lett 46:6865–6869CrossRef
24.
Hicks JC, Drese JH, Fauth DJ, Gray ML, Qi G, Jones CW (2008) Designing adsorbents for CO2 capture from flue gas—hyperbranched aminosilicas capable of capturing CO2 reversibly. J Am Chem Soc 130:2902–2903CrossRef
25.
Drese JH, Choi S, Lively RP, Koros WJ, Fauth DJ, Gray ML, Jones CW (2009) Synthesis–structure–property relationships for hyperbranched aminosilica CO2 adsorbents. Adv Funct Mater 19:3821–3832CrossRef
26.
Choi S, Drese JH, Eisenberger PM, Jones CW (2011) Application of amine-tethered solid sorbents for direct CO2 capture from the ambient air. Environ Sci Technol 45:2420–2427CrossRef
27.
Chaikittisilp W, Kim H-J, Jones CW (2011) Mesoporous alumina-supported amines as potential steam-stable adsorbents for capturing CO2 from simulated flue gas and ambient air. Energy Fuels 25:5528–5537CrossRef
28.
Husing N (2004) Porous inorganic-organic hybrid materials. In: Gómez-Romero P, Sánchez C (eds) Functional hybrid materials. Wiley, Weinheim
29.
Macquarrie DJ, Rousseau H (2003) High-loading aminopropyl silicas as novel scavenger resins for high throughput synthesis. Synlett 2:244–246CrossRef
30.
Mdoe JEG, Macquarrie DJ, Clark JH (2003) One-pot preparation of polyamine–silica hybrids and their use in the epoxidation of cyclohex-2-ene-1-one. J Mol Catal A Chem 198:241–247CrossRef
31.
Loy DA, Shea KJ (1995) Bridged polysilsesquioxanes. Highly porous hybrid organic-inorganic materials. Chem Rev 95:1431–1442CrossRef
32.
Asefa T, MacLachlan MJ, Coombs N, Ozin GA (1999) Periodic mesoporous organosilicas with organic groups inside the channel walls. Nature 402:867–871
33.
Inagaki S, Guan S, Fukushima Y, Ohsuna T, Terasaki O (1999) Novel mesoporous materials with a uniform distribution of organic groups and inorganic oxide in their frameworks. J Am Chem Soc 121:9611–9614CrossRef
34.
Hunks WJ, Ozin GA (2005) Challenges and advances in the chemistry of periodic mesoporous organosilicas (PMOs). J Mater Chem 15:3716–3724CrossRef
35.
Mehdi A, Reye C, Corriu R (2011) From molecular chemistry to hybrid nanomaterials. Design and functionalization. Chem Soc Rev 40:563–574CrossRef
36.
Zhou G, Simerly T, Golovko L, Tychinin I, Trachevsky V, Gomza Y, Vasiliev A (2012) Highly functionalized bridged silsesquioxanes. J Sol-Gel Sci Technol 62:470–482CrossRef
37.
Loy DA, Baugher BM, Baugher CR, Schneider DA, Rahimian K (2000) Substituent effects on the sol-gel chemistry of organotrialkoxysilanes. Chem Mater 12:3624–3632CrossRef
38.
Pal N, Bhaumik A (2013) Soft templating strategies for the synthesis of mesoporous materials: inorganic, organic–inorganic hybrid and purely organic solids. Adv Colloid Interface Sci 189–190:21–41CrossRef
39.
Díaz U, García T, Velty A, Corma A (2009) Hybrid organic–inorganic catalytic porous materials synthesized at neutral pH in absence of structural directing agents. J Mater Chem 19:5970–5979CrossRef
40.
Bernardoni F, Fadeev AY (2011) Adsorption and wetting characterization of hydrophobic SBA-15 silicas. J Colloid Interface Sci 356:690–698CrossRef
41.
Tanthana J, Chuang SSC (2010) In situ infrared study of the role of PEG in stabilizing silica-supported amines for CO2 capture. ChemSusChem 3:957–964CrossRef
42.
Fisher JC II, Tanthana J, Chuang SSC (2009) Oxide-supported tetraethylenepentamine for CO2 capture. Environ Prog Sustain Energy 28:589–598CrossRef
43.
Chang ACC, Chuang SSC, Gray M, Soong Y (2003) In-situ infrared study of CO2 adsorption on SBA-15 grafted with γ-(aminopropyl)triethoxysilane. Energy Fuels 17:468–473CrossRef
44.
Tsuda T, Fujiwara T, Taketani Y, Saegusa T (1992) Amino silica gels acting as a carbon dioxide absorbent. Chem Lett 21:2161–2164CrossRef
45.
Hao SY, Xiao QA, Yang H, Zhong YJ, Pepe F, Zhu WD (2010) Synthesis and CO2 adsorption property of amino-functionalized silica nanospheres with centrosymmetric radial mesopores. Micropor Mesopor Mater 132:552–558CrossRef
46.
Bacsik Z, Atluri R, Garcia-Bennett AE, Hedin N (2010) Temperature-induced uptake of CO2 and formation of carbamates in mesocaged silica modified with n-propylamines. Langmuir 26:10013–10024CrossRef
47.
Stegmeier S, Fleischer M, Tawil A, Hauptmann P, Egly K, Rose K (2009) Mechanism of the interaction of CO2 and humidity with primary amino group systems for room temperature CO2 sensors. Procedia Chem 1:236–239CrossRef
48.
Hiyoshi N, Yogo K, Yashima T (2005) Adsorption characteristics of carbon dioxide on organically functionalized SBA-15. Micropor Mesopor Mater 84:357–365CrossRef
49.
Khatri RA, Chuang SSC, Soong Y, Gray M (2005) Carbon dioxide capture by diamine-grafted SBA-15: a combined Fourier transform infrared and mass spectrometry study. Ind Eng Chem Res 44:3702–3708CrossRef
50.
Steiner T (2002) The hydrogen bond in the solid state. Angew Chem Int Ed 41:49–76
51.
Jeffrey GA (1997) An introduction to hydrogen bonding. Oxford University Press, Oxford
52.
Li Z, Zhang B (2012) Experimental and theoretical investigation of homogeneous gaseous reaction of CO2(g) + nH2O(g) + nNH3(g) → Products (n = 1,2). J Phys Chem A 116:8989–9000CrossRef
53.
Adams JM, Small RWH (1973) The crystal structure of ammonium carbamate. Acta Crystallogr B B29:2317–2319CrossRef
Metadaten
Titel
Bridged mesoporous silsesquioxanes as potential CO2 adsorbents
verfasst von
Odette Esam
Guannan Zhou
Aleksey Vasiliev
Publikationsdatum
01.06.2015
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2015
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-015-3657-9

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