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Published in: Polymer Science, Series D 1/2023

01-03-2023

Amphiphilic Properties of Methacrylic Macromonomers with Oligo(ethylene glycol) and Oligo(propylene glycol) Blocks

Authors: M. V. Savinova, A. S. Simagin, K. V. Shirshin, D. V. Orekhov, S. V. Orekhov, D. M. Kamorin, O. A. Kazantsev

Published in: Polymer Science, Series D | Issue 1/2023

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Abstract

The effect of the structure of novel synthesized macromonomers of methoxy oligo(ethylene glycol)-block-oligo(propylene glycol) methacrylates on their manifestation of amphiphilic properties in water and a water–hexane mixture is studied. The effect of the length of the hydrophilic and hydrophobic blocks of the macromonomers on the surface or interfacial tension and partition between the phases in water and a water–hexane mixture on the position of the macromonomers in the two-dimensional amphiphilicity diagram of organic substances is shown.

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Literature
1.
go back to reference X. Zhang and Y. Dai, “Recent development of brush polymers via polymerization of poly (ethylene glycol)-based macromonomers,” Polym. Chem. 10, 2212–2222 (2019).CrossRef X. Zhang and Y. Dai, “Recent development of brush polymers via polymerization of poly (ethylene glycol)-based macromonomers,” Polym. Chem. 10, 2212–2222 (2019).CrossRef
2.
go back to reference N. Badi, “Non-linear PEG-based thermoresponsive polymer systems,” Prog. Polym. Sci. 66, 54–79 (2017).CrossRef N. Badi, “Non-linear PEG-based thermoresponsive polymer systems,” Prog. Polym. Sci. 66, 54–79 (2017).CrossRef
3.
go back to reference A. Tochwin, A. El-Betany, H. Tai, K. Chan, C. Blackburn, and W. Wang, “Thermoresponsive and reducible hyperbranched polymers synthesized by RAFT polymerisation,” Polymers 9, 443 (2017).CrossRefPubMedPubMedCentral A. Tochwin, A. El-Betany, H. Tai, K. Chan, C. Blackburn, and W. Wang, “Thermoresponsive and reducible hyperbranched polymers synthesized by RAFT polymerisation,” Polymers 9, 443 (2017).CrossRefPubMedPubMedCentral
4.
go back to reference W. Wang, H. Liang, R. Ghanami, L. Hamilton, M. Fraylich, K. Shakesheff, B. Saunders, and C. Alexander, “Biodegradable thermoresponsive microparticle dispersions for injectable cell delivery prepared using a single-step process,” Adv. Mater. 21, 1809–1813 (2009).CrossRef W. Wang, H. Liang, R. Ghanami, L. Hamilton, M. Fraylich, K. Shakesheff, B. Saunders, and C. Alexander, “Biodegradable thermoresponsive microparticle dispersions for injectable cell delivery prepared using a single-step process,” Adv. Mater. 21, 1809–1813 (2009).CrossRef
5.
go back to reference S. Takahashi, T. Saito, and T. Kasemura, “Synthesis of amphiphilic copolymers having capability as emulsifiers and their surface chemical properties,” J. Adh. 79, 287–309 (2003).CrossRef S. Takahashi, T. Saito, and T. Kasemura, “Synthesis of amphiphilic copolymers having capability as emulsifiers and their surface chemical properties,” J. Adh. 79, 287–309 (2003).CrossRef
6.
go back to reference D. M. Kamorin, A. S. Simagin, D. V. Orekhov, O. A. Kazantsev, E. A. Bolshakova, A. P. Sivokhin, M. V. Savinova, and S. V. Orekhov, “Synthesis and thermoresponsive properties of polymethacrylate molecular brushes with oligo (ethylene glycol)-block-oligo (propylene glycol) side chains,” Polym. Bull. 79, 1–18 (2021). D. M. Kamorin, A. S. Simagin, D. V. Orekhov, O. A. Kazantsev, E. A. Bolshakova, A. P. Sivokhin, M. V. Savinova, and S. V. Orekhov, “Synthesis and thermoresponsive properties of polymethacrylate molecular brushes with oligo (ethylene glycol)-block-oligo (propylene glycol) side chains,” Polym. Bull. 79, 1–18 (2021).
7.
go back to reference R. Z. Miladinovic, M. Micic, A. Mrakovic, and E. Suljovrujic, “Smart hydrogels with ethylene glycol propylene glycol pendant chains,” J. Polym. Res. 25, 1–10 (2018).CrossRef R. Z. Miladinovic, M. Micic, A. Mrakovic, and E. Suljovrujic, “Smart hydrogels with ethylene glycol propylene glycol pendant chains,” J. Polym. Res. 25, 1–10 (2018).CrossRef
8.
go back to reference A. P. Sivokhin, D. V. Orekhov, O. A. Kazantsev, O. V. Gubanova, D. M. Kamorin, I. S. Zarubina, and S. D. Zaitsev, “amphiphilic thermo-responsive copolymer brushes: synthesis, characterization and self-assembly into flower-like micelles,” Polym. J. 53, 655–665 (2021).CrossRef A. P. Sivokhin, D. V. Orekhov, O. A. Kazantsev, O. V. Gubanova, D. M. Kamorin, I. S. Zarubina, and S. D. Zaitsev, “amphiphilic thermo-responsive copolymer brushes: synthesis, characterization and self-assembly into flower-like micelles,” Polym. J. 53, 655–665 (2021).CrossRef
9.
go back to reference D. V. Orekhov, D. M. Kamorin, A. S. Simagin, I. R. Arifullin, O. A. Kazantsev, A. P. Sivokhin, and M. V. Savinova, “Molecular brushes based on copolymers of alkoxyoligo(ethylene glycol) methacrylates and dodecyl(meth)acrylate: features of synthesis by conventional free radical polymerization,” Polym. Bull. 78 (10), 5833–5850 (2020).CrossRef D. V. Orekhov, D. M. Kamorin, A. S. Simagin, I. R. Arifullin, O. A. Kazantsev, A. P. Sivokhin, and M. V. Savinova, “Molecular brushes based on copolymers of alkoxyoligo(ethylene glycol) methacrylates and dodecyl(meth)acrylate: features of synthesis by conventional free radical polymerization,” Polym. Bull. 78 (10), 5833–5850 (2020).CrossRef
10.
go back to reference H. Tai, W. Wang, T. Vermonden, F. Heath, W. E. Hennink, C. Alexander, K. Shakesheff, and S. M. Howdle, “Thermoresponsive and photocrosslinkable PEGMEMA-PPGMA-EGDMA copolymers from a one-step ATRP synthesis,” Biomacromolecules 10, 822–828 (2009).CrossRefPubMed H. Tai, W. Wang, T. Vermonden, F. Heath, W. E. Hennink, C. Alexander, K. Shakesheff, and S. M. Howdle, “Thermoresponsive and photocrosslinkable PEGMEMA-PPGMA-EGDMA copolymers from a one-step ATRP synthesis,” Biomacromolecules 10, 822–828 (2009).CrossRefPubMed
11.
go back to reference H. Tai, D. Howard, S. Takae, W. Wang, T. Vermonden, W. E. Hennink, P. S. Stayton, A. S. Hoffman, A. Endruweit, C. Alexander, S. M. Howdle, and K. M. Shakesheff, “Photo-cross-linked hydrogels from thermoresponsive PEGMEMA-PPGMA-EGDMA copolymers containing multiple methacrylate groups: Mechanical property, swelling, protein release, and cytotoxicity,” Biomacromolecules 10, 2895–2903 (2009).CrossRefPubMed H. Tai, D. Howard, S. Takae, W. Wang, T. Vermonden, W. E. Hennink, P. S. Stayton, A. S. Hoffman, A. Endruweit, C. Alexander, S. M. Howdle, and K. M. Shakesheff, “Photo-cross-linked hydrogels from thermoresponsive PEGMEMA-PPGMA-EGDMA copolymers containing multiple methacrylate groups: Mechanical property, swelling, protein release, and cytotoxicity,” Biomacromolecules 10, 2895–2903 (2009).CrossRefPubMed
12.
go back to reference S. Takahashi, N. Shibamiya, and T. Kasemura, “Emulsion polymerization of co-polymers having both hydrophilic and hydrophobic side chains and their adhesion properties,” Adhesion and Interface 3, 13–19 (2002). S. Takahashi, N. Shibamiya, and T. Kasemura, “Emulsion polymerization of co-polymers having both hydrophilic and hydrophobic side chains and their adhesion properties,” Adhesion and Interface 3, 13–19 (2002).
13.
go back to reference H. Okamoto, Y. Kano, S. Nakashima, T. Kotaka, T. Kasemura, and Y. Nozawa, “Terpolymers composed of ethyl acrylate, methoxypolyethyleneglycol methacrylate and methoxypolypropyleneglycol methacrylate as pressure sensitive adhesives and their blood compatibility,” J. Adh. 71, 263–278 (1999).CrossRef H. Okamoto, Y. Kano, S. Nakashima, T. Kotaka, T. Kasemura, and Y. Nozawa, “Terpolymers composed of ethyl acrylate, methoxypolyethyleneglycol methacrylate and methoxypolypropyleneglycol methacrylate as pressure sensitive adhesives and their blood compatibility,” J. Adh. 71, 263–278 (1999).CrossRef
14.
go back to reference R. Paris and I. Quijada-Garrido, “Synthesis and aggregation properties in water solution of comblike methacrylic polymers with oligo (propylene glycol)-block-oligo (ethylene glycol) as side chains,” J. Polym. Sci. Part A: Polym. Chem. 49, 1928–1932 (2011).CrossRef R. Paris and I. Quijada-Garrido, “Synthesis and aggregation properties in water solution of comblike methacrylic polymers with oligo (propylene glycol)-block-oligo (ethylene glycol) as side chains,” J. Polym. Sci. Part A: Polym. Chem. 49, 1928–1932 (2011).CrossRef
15.
go back to reference M. Simonova, D. Kamorin, O. Kazantsev, M. Nepomnyashaya, and A. Filippov, “Conformation, self- organization and thermoresponsibility of polymethacrylatemolecular brushes with oligo (ethylene glycol)-block-oligo (propylene glycol) side chains,” Polymers 13, 2715 (2021).CrossRefPubMedPubMedCentral M. Simonova, D. Kamorin, O. Kazantsev, M. Nepomnyashaya, and A. Filippov, “Conformation, self- organization and thermoresponsibility of polymethacrylatemolecular brushes with oligo (ethylene glycol)-block-oligo (propylene glycol) side chains,” Polymers 13, 2715 (2021).CrossRefPubMedPubMedCentral
16.
go back to reference E. Suljovrujic, R. Z. Miladinovic, and M. Krstic, “Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature,” Polym. Bull. 78, 2405–2425 (2020).CrossRef E. Suljovrujic, R. Z. Miladinovic, and M. Krstic, “Swelling properties and drug release of new biocompatible POEGOPGMA hydrogels with VPTT near to the human body temperature,” Polym. Bull. 78, 2405–2425 (2020).CrossRef
17.
go back to reference D. V. Orekhov, O. A. Kazantsev, S. V. Orekhov, A. P. Sivokhin, D. M. Kamorin, A. S. Simagin, M. V. Savinova, E. A. Bolshakova, and M. S. Korotaev, “Synthesis of amphiphilic (meth)acrylates with oligo(ethylene glycol) and (or) oligo(propylene glycol) blocks by the esterification of (meth)acrylic acid,” J. Appl. Polym. Sci. 138, 1–12 (2021).CrossRef D. V. Orekhov, O. A. Kazantsev, S. V. Orekhov, A. P. Sivokhin, D. M. Kamorin, A. S. Simagin, M. V. Savinova, E. A. Bolshakova, and M. S. Korotaev, “Synthesis of amphiphilic (meth)acrylates with oligo(ethylene glycol) and (or) oligo(propylene glycol) blocks by the esterification of (meth)acrylic acid,” J. Appl. Polym. Sci. 138, 1–12 (2021).CrossRef
18.
go back to reference P. Becher, “Hydrophile-lipophile balance: History and recent developments Langmuir lecture–1983,” J. Dispersion Sci. Technol. 5, 81–96 (1984).CrossRef P. Becher, “Hydrophile-lipophile balance: History and recent developments Langmuir lecture–1983,” J. Dispersion Sci. Technol. 5, 81–96 (1984).CrossRef
19.
go back to reference I. A. Gritskova, R. M. Panich, and S. S. Voyutskii, “The physicochemical properties of oxyethylated non-ionic surface-active substances,” Russ. Chem. Rev. 34, 867–882 34, 1989–2019 (1965). I. A. Gritskova, R. M. Panich, and S. S. Voyutskii, “The physicochemical properties of oxyethylated non-ionic surface-active substances,” Russ. Chem. Rev. 34, 867–882 34, 1989–2019 (1965).
20.
go back to reference I. M. Okhapkin, E. E. Makhaeva, and A. R. Khokhlov, “Two-dimensional classification of amphiphilic monomers based on interfacial and partitioning properties. 1. Monomers of synthetic water-soluble polymers,” Colloid Polym. Sci. 284, 117–123 (2005).CrossRef I. M. Okhapkin, E. E. Makhaeva, and A. R. Khokhlov, “Two-dimensional classification of amphiphilic monomers based on interfacial and partitioning properties. 1. Monomers of synthetic water-soluble polymers,” Colloid Polym. Sci. 284, 117–123 (2005).CrossRef
Metadata
Title
Amphiphilic Properties of Methacrylic Macromonomers with Oligo(ethylene glycol) and Oligo(propylene glycol) Blocks
Authors
M. V. Savinova
A. S. Simagin
K. V. Shirshin
D. V. Orekhov
S. V. Orekhov
D. M. Kamorin
O. A. Kazantsev
Publication date
01-03-2023
Publisher
Pleiades Publishing
Published in
Polymer Science, Series D / Issue 1/2023
Print ISSN: 1995-4212
Electronic ISSN: 1995-4220
DOI
https://doi.org/10.1134/S1995421223010276

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