Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Cellulose
Published in: Cellulose 1/2018

02-11-2017 | Original Paper

Cellulose nanofibers/silk fibroin nanohybrid sponges with highly ordered and multi-scale hierarchical honeycomb structure

Authors: Kezheng Gao, Yaqing Guo, Qingyuan Niu, Lifeng Han, Linsen Zhang, Yong Zhang, Lizhen Wang

Published in: Cellulose | Issue 1/2018

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Highly ordered cellulose nanofibers/silk fibroin nanohybrid (CSN) honeycomb materials with multi-scale hierarchical architectures are successfully prepared from CSN hydrogel precursors using unidirectional freeze-drying technique. Cellulose nanofibers have an outstanding highly ordered honeycomb structure-directing function in composite hydrogel. However, silk fibroin does not have such function. Therefore, the properties of the CSN sponges can be effectively adjusted by simple changing the ratio of cellulose nanofibers to silk fibroin. When the content of silk fibroin reaches 50%, the CSN-50 sponge exhibits a nearly perfect highly ordered honeycomb structure with multi-scale hierarchical architectures. And the Brunauer–Emmett–Teller specific surface area is about 120 m2 g−1.
previous article Nanofibrous alginate membrane coated with cellulose nanowhiskers for water purification
next article Mechanisms contributing to mechanical property changes in composites of polypropylene reinforced with spray-dried cellulose nanofibrils

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now
Appendix
Available only for authorised users
Literature
Besbes I, Alila S, Boufi S (2011) Nanofibrillated cellulose from TEMPO-oxidized eucalyptus fibres: effect of the carboxyl content. Carbohydr Polym 84(3):975–983CrossRef
Chen J, Zhuang A, Shao H, Hu X, Zhang Y (2017) Robust silk fibroin/bacterial cellulose nanoribbon composite scaffolds with radial lamellae and intercalation structure for bone regeneration. J Mater Chem B 5(20):3640–3650CrossRef
Deville S (2008) Freeze-casting of porous ceramics: a review of current achievements and issues. Adv Eng Mater 10(3):155–169CrossRef
Deville S, Saiz E, Nalla RK, Tomsia AP (2006) Freezing as a path to build complex composites. Science 311(5760):515–518CrossRef
Fratzl P, Weinkamer R (2007) Nature’s hierarchical materials. Prog Mater Sci 52(8):1263–1334CrossRef
Fujisawa S, Okita Y, Fukuzumi H, Saito T, Isogai A (2011) Preparation and characterization of TEMPO-oxidized cellulose nanofibril films with free carboxyl groups. Carbohydr Polym 84(1):579–583CrossRef
Gao K, Shao Z, Li J, Wang X, Peng X, Wang W, Wang F (2013a) Cellulose nanofiber–graphene all solid-state flexible supercapacitors. J Mater Chem A 1(1):63–67CrossRef
Gao K, Shao Z, Wang X, Zhang Y, Wang W, Wang F (2013b) Cellulose nanofibers/multi-walled carbon nanotube nanohybrid aerogel for all-solid-state flexible supercapacitors. RSC Adv 3(35):15058–15064CrossRef
Isogai A, Saito T, Fukuzumi H (2011) TEMPO-oxidized cellulose nanofibers. Nanoscale 3(1):71–85CrossRef
Kim KN, Chun J, Chae SA, Ahn CW, Kim IW, Kim S-W, Wang ZL, Baik JM (2015) Silk fibroin-based biodegradable piezoelectric composite nanogenerators using lead-free ferroelectric nanoparticles. Nano Energy 14:87–94CrossRef
Lasseuguette E, Roux D, Nishiyama Y (2008) Rheological properties of microfibrillar suspension of TEMPO-oxidized pulp. Cellulose 15(3):425–433CrossRef
Lee JM, Kim JH, Lee OJ, Park CH (2013) The fixation effect of a silk fibroin–bacterial cellulose composite plate in segmental defects of the zygomatic arch an experimental study. JAMA Otolaryngol 139(6):629–635
Li X-G, Wu LY, Huang MR, Shao H-L, Hu X-C (2008) Conformational transition and liquid crystalline state of regenerated silk fibroin in water. Biopolymers 89(6):497–505CrossRef
Li WL, Lu K, Walz JY (2012) Freeze casting of porous materials: review of critical factors in microstructure evolution. Int Mater Rev 57(1):37–60CrossRef
Lin N, Cao L, Huang Q, Wang C, Wang Y, Zhou J, Liu X-Y (2016) Functionalization of silk fibroin materials at mesoscale. Adv Funct Mater 26(48):8885–8902CrossRef
Matsubara EY, Lala SM, Rosolen JM (2010) Lithium storage into carbonaceous materials obtained from sugarcane bagasse. J Braz Chem Soc 21(10):1877–1884CrossRef
Montanari S, Rountani M, Heux L, Vignon MR (2005) Topochemistry of carboxylated cellulose nanocrystals resulting from TEMPO-mediated oxidation. Macromolecules 38(5):1665–1671CrossRef
Niu QY, Guo YQ, Gao KZ, Shao ZQ (2016) Polypyrrole/cellulose nanofiber aerogel as a supercapacitor electrode material. RSC Adv 6(110):109143–109149CrossRef
Ochi A, Hossain KS, Magoshi J, Nemoto N (2002) Rheology and dynamic light scattering of silk fibroin solution extracted from the middle division of Bombyx mori silkworm. Biomacromol 3(6):1187–1196CrossRef
Okita Y, Saito T, Isogai A (2009) TEMPO-mediated oxidation of softwood thermomechanical pulp. Holzforschung 63(5):529–535CrossRef
Okita Y, Saito T, Isogai A (2010) Entire surface oxidation of various cellulose microfibrils by TEMPO-mediated oxidation. Biomacromol 11(6):1696–1700CrossRef
Oliveira Barud HG, Barud HDS, Cavicchioli M, do Amaral TS, de Oliveira Junior OB, Santos DM, de Oliveira Almeida Petersen AL, Celes F, Borges VM, de Oliveira CI, de Oliveira PF, Furtado RA, Tavares DC, Ribeiro SJL (2015) Preparation and characterization of a bacterial cellulose/silk fibroin sponge scaffold for tissue regeneration. Carbohydr Polym 128:41–51CrossRef
Pan Z-Z, Nishihara H, Iwamura S, Sekiguchi T, Sato A, Isogai A, Kang F, Kyotani T, Yang Q-H (2016) Cellulose nanofiber as a distinct structure-directing agent for xylem-like microhoneycomb monoliths by unidirectional freeze-drying. ACS Nano 10(12):10689–10697CrossRef
Qin DC, Zhang F, Dong SY, Zhao YZ, Xu GY, Zhang XG (2016) Analogous graphite carbon sheets derived from corn stalks as high performance sodium-ion battery anodes. RSC Adv 6(108):106218–106224CrossRef
Saito T, Nishiyama Y, Putaux J-L, Vignon M, Isogai A (2006) Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose. Biomacromol 7(6):1687–1691CrossRef
Saito T, Kimura S, Nishiyama Y, Isogai A (2007) Cellulose nanofibers prepared by TEMPO-mediated oxidation of native cellulose. Biomacromol 8(8):2485–2491CrossRef
Saito T, Hirota M, Tamura N, Isogai A (2010) Oxidation of bleached wood pulp by TEMPO/NaClO/NaClO2 system: effect of the oxidation conditions on carboxylate content and degree of polymerization. J Wood Sci 56(3):227–232CrossRef
Saito T, Uematsu T, Kimura S, Enomae T, Isogai A (2011) Self-aligned integration of native cellulose nanofibrils towards producing diverse bulk materials. Soft Matter 7(19):8804–8809CrossRef
Schoof H, Apel J, Heschel I, Rau G (2001) Control of pore structure and size in freeze-dried collagen sponges. J Biomed Mater Res 58(4):352–357CrossRef
Si Y, Wang X, Yan C, Yang L, Yu J, Ding B (2016) Ultralight biomass-derived carbonaceous nanofibrous aerogels with superelasticity and high pressure-sensitivity. Adv Mater 28(43):9512–9518CrossRef
Song L, Li L, Gao X, Zhao J, Lu T, Liu Z (2015) A facile synthesis of a uniform constitution of three-dimensionally ordered macroporous TiO2-carbon nanocomposites with hierarchical pores for lithium ion batteries. J Mater Chem A 3(13):6862–6872CrossRef
Taylor CM, Smith CW, Miller W, Evans KE (2011) The effects of hierarchy on the in-plane elastic properties of honeycombs. Int J Solids Struct 48(9):1330–1339CrossRef
Terry AE, Knight DP, Porter D, Vollrath F (2004) PH induced changes in the rheology of silk fibroin solution from the middle division of Bombyx mori silkworm. Biomacromol 5(3):768–772CrossRef
Wicklein B, Kocjan A, Salazar-Alvarez G, Carosio F, Camino G, Antonietti M, Bergstrom L (2015) Thermally insulating and fire-retardant lightweight anisotropic foams based on nanocellulose and graphene oxide. Nat Nanotechnol 10(3):277–283CrossRef
Yun YS, Cho SY, Shim J, Kim BH, Chang S-J, Baek SJ, Huh YS, Tak Y, Park YW, Park S, Jin H-J (2013) Microporous carbon nanoplates from regenerated silk proteins for supercapacitors. Adv Mater 25(14):1993–1998CrossRef
Zhang F, Lu Q, Ming J, Dou H, Liu Z, Zuo B, Qin M, Li F, Kaplan DL, Zhang X (2014) Silk dissolution and regeneration at the nanofibril scale. J Mater Chem B 2(24):3879–3885CrossRef
Metadata
Title
Cellulose nanofibers/silk fibroin nanohybrid sponges with highly ordered and multi-scale hierarchical honeycomb structure
Authors
Kezheng Gao
Yaqing Guo
Qingyuan Niu
Lifeng Han
Linsen Zhang
Yong Zhang
Lizhen Wang
Publication date
02-11-2017
Publisher
Springer Netherlands
Published in
Cellulose / Issue 1/2018
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-017-1545-x

Other articles of this Issue 1/2018

Cellulose 1/2018 Go to the issue

Original Paper

Nanofibrous alginate membrane coated with cellulose nanowhiskers for water purification

Original Paper

Hydroxyalkylation of xylan using propylene carbonate: comparison of products from homo- and heterogeneous synthesis by HRMAS NMR and rheology

Original Paper

Bamboo cellulose-derived cellulose acetate for electrospun nanofibers: synthesis, characterization and kinetics

Original Paper

Imidazole-doped nanocrystalline cellulose solid proton conductor: synthesis, thermal properties, and conductivity

Original Paper

Exploring the composition of raw and delignified Colombian fique fibers, tow and pulp

Original Paper

Cellulose nanofibres as biomaterial for nano-reinforcement of poly[styrene-(ethylene-co-butylene)-styrene] triblock copolymer