Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Metallurgical and Materials Transactions B
Published in: Metallurgical and Materials Transactions B 5/2018

27-07-2018

Critical Evaluation and Thermodynamic Optimization of the Li2O-Al2O3 and Li2O-MgO-Al2O3 Systems

Authors: Bikram Konar, Marie-Aline Van Ende, In-Ho Jung

Published in: Metallurgical and Materials Transactions B | Issue 5/2018

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The thermodynamic and phase diagram data of the Li2O-Al2O3 and Li2O-MgO-Al2O3 systems were critically evaluated and optimized to obtain a set of consistent Gibbs energy functions for all phases in the systems. The LiAl5O8-MgAl2O4 spinel solid solution was modeled with the two-sublattice compound energy formalism by considering the cation distribution between the tetrahedral and octahedral sites and excess vacancy in octahedral sites. The liquid phase and monoxide solid solution were also described using the modified quasichemical model with pair approximation and the Bragg–Williams random mixing model, respectively. The thermodynamic models with optimized model parameters enable the reproduction of all reliable thermodynamic and phase diagram as well as spinel structural data in the system.
previous article Study on the Extraction of Aluminum From Aluminum Dross Using Alkali Roasting and Subsequent Synthesis of Mesoporous γ-Alumina
next article Discussion of the Paper “A New Method Based on the F-Curve for Characterizing Fluid Flow in Continuous Casting Tundishes” by Li et al.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
W. Jiang, J. Zhang, L. Kovarik, Z. Zhu, L. Price, J. Gigax, E. Castanon, X. Wang, L. Shao and D.J. Senor, J. Nucl. Mater., 2017, vol. 484, pp. 374-81.CrossRef
2.
D. Guggi, H.R. Ihle and A. Neubert, Symposium on Fusion Technology, Pergamon Press, Garmisch-Partenkirchen, Germany, 1976, pp. 635-44.CrossRef
3.
M. Nishikawa, A. Baba and Y. Kawamura, J. Nucl. Mater., 1997, vol. 246, pp. 1-8.CrossRef
4.
F. Rosciano, P.P. Pescarmona, K. Houthoofd, A. Persoons, P. Bottke and M. Wilkening, Phys. Chem. Chem. Phys., 2013, vol. 15, pp. 6107-12.CrossRef
5.
Z.-K. Fang, Y.-R. Zhu, T.-F. Yi and Y. Xie, ACS Sustain. Chem. Eng., 2016, vol. 4, pp. 1994-2003.CrossRef
6.
B. Put, P.M. Vereecken, M.J. Mees, F. Rosciano, L.P. Radu and A. Stesmans, Phys. Chem. Chem. Phys., 2015, vol. 17, pp. 29045-56.CrossRef
7.
R. Djenadic, M. Botros and H. Hahn, Solid State Ionics, 2016, vol. 287, pp. 71-76.CrossRef
8.
C.V. Chandran and P. Heitjans, Solid-State NMR Studies of Lithium Ion Dynamics Across Materials Classes, in: Annual Reports on NMR Spectroscopy, Academic Press.
9.
M. Raja, G. Sanjeev, T.P. Kumar and A.M. Stephan, Ceram. Int., 2015, vol. 41, pp. 3045-50.CrossRef
10.
J.S. Park, X. Meng, J.W. Elam, S. Hao, C. Wolverton, C. Kim and J. Cabana, Chem. Mater., 2014, vol. 26, pp. 3128-34.CrossRef
11.
K. Zaghib, A. Mauger, H. Groult, J. Goodenough and C. Julien, Materials, 2013, vol. 6, pp. 1028-49.CrossRef
12.
13.
S.J. Heo, B. Hu, M.A. Uddin, A. Aphale, A. Hilmi, C.-Y. Yuh, A. Surendranath and P. Singh, J. Electrochem. Soc., 2017, vol. 164, pp. H5086-92.CrossRef
14.
[14] K. Takizawa and A. Hagiwara, J. Power Sources, 2002, vol. 109, pp. 127-35.CrossRef
15.
[15] S. Terada, I. Nagashima, K. Higaki and Y. Ito, J. Power Sources, 1998, vol. 75, pp. 223-29.CrossRef
16.
17.
18.
[18] C. Yang, G. Wen and P. Tang, Steel Res. Int., 2016, vol. 87, pp. 880-89.CrossRef
19.
[19] T. Wu, Q. Wang, S. He, J. Xu, X. Long and Y. Lu, Steel Res. Int., 2012, vol. 83, pp. 1194-1202.CrossRef
20.
[20] J.-W. Cho, K. Blazek, M. Frazee, H. Yin, J.H. Park and S.-W. Moon, ISIJ Int., 2013, vol. 53, pp. 62-70.CrossRef
21.
[21] B. Lu, K. Chen, W. Wang and B. Jiang, Metall. Mater. Trans. B, 2014, vol. 45B, pp. 1496-1509.CrossRef
22.
[22] X.J. Fu, G.H. Wen, P. Tang, Q. Liu and Z.Y. Zhou, Ironmak. Steelmak., 2014, vol. 41, pp. 342-41.CrossRef
23.
[23] T. Ávalos-Rendón, J. Casa-Madrid and H. Pfeiffer, J. Phys. Chem. A, 2009, vol. 113, pp. 6919-23.CrossRef
24.
[24] T. Ávalos-Rendón, V.H. Lara and H. Pfeiffer, Ind. Eng. Chem. Res., 2012, vol. 51, pp. 2622-30.CrossRef
25.
[25] N.S. Kulkarni, T.M. Besmann and K.E. Spear, J. Am. Ceram. Soc., 2008, vol. 91, pp. 4074-83.CrossRef
26.
[26] Q. Guan, X. Chen, T. Gao, C. Xiao, L. Zhao, J. He and X. Long, J. Nucl. Mater., 2015, vol. 465, pp. 170-76.CrossRef
27.
[27] S.Q. Wu, Z.F. Hou and Z.Z. Zhu, Comput. Mater. Sci., 2009, vol. 46, pp. 221-24.CrossRef
28.
[28] E.S. Blaakmeer, F. Rosciano and E.R.H. van Eck, J. Phys. Chem. C, 2015, vol. 119, pp. 7565-77.CrossRef
29.
[29] M.J. Mees, G. Pourtois, F. Rosciano, B. Put, P.M. Vereecken and A. Stesmans, Phys. Chem. Chem. Phys., 2014, vol. 16, pp. 5399-5406.CrossRef
30.
[30] S.C. Jung and Y.-K. Han, J. Phys. Chem. Lett., 2013, vol. 4, pp. 2681-85.CrossRef
31.
[31] H.J. Byker, I. Eliezer, N. Eliezer and R.A. Howald, J. Phys. Chem., 1979, vol. 83, pp. 2349-55.CrossRef
32.
[32] L.P. Cook and E.R. Plante, Ceram. Trans., 1992, vol. 27, pp. 193-222.
33.
[33] C.W. Bale, E. Bélisle, P. Chartrand, S.A. Decterov, G. Eriksson, A.E. Gheribi, K. Hack, I.H. Jung, Y.B. Kang, J. Melançon, A.D. Pelton, S. Petersen, C. Robelin, J. Sangster, P. Spencer and M.A. Van Ende, CALPHAD, 2016, vol. 54, pp. 35-53.CrossRef
34.
[34] B. Konar, M.A. Van-Ende and I.H. Jung, J. Eur. Ceram. Soc., 2017, vol. 37, pp. 2189-2207.CrossRef
35.
[35] C.W. Bale, P. Chartrand, S.A. Degterov, G. Eriksson, K. Hack, R. Ben Mahfoud, J. Melançon, A.D. Pelton and S. Petersen, CALPHAD, 2002, vol. 26, pp. 189-228.CrossRef
36.
[36] A.D. Pelton and P. Chartrand, Metall. Mater. Trans. A, 2001, vol. 32A, pp. 1355-60.CrossRef
37.
[37] A.D. Pelton, S.A. Degterov, G. Eriksson, C. Robelin and Y. Dessureault, Metall. Mater. Trans. B, 2000, vol. 31B, pp. 651-59.CrossRef
38.
B. Konar, D.G. Kim, and I.-H. Jung, J. Eur. Ceram. Soc., 2018, vol. 38, pp. 881-3904.
39.
E. Jak, P. Hayes, A.D. Pelton and S.A. Decterov: Proc VIII Int’l Conf on Molten Slags, Fluxes and Salts, Thermodynamic modelling of the Al 2O3 -CaO-FeO-Fe 2O3 -PbO-SiO 2 -ZnO system with addition of K and Na with metallurgical applications, 2009, pp. 473-490.
40.
41.
[41] W.B. Badger and F.A. Hummel, J. Am. Ceram. Soc., 1985, vol. 68, pp. C46-47.
42.
43.
[43] B. Konar, D.-G. Kim and I.-H. Jung, Ceram. Int., 2017, vol. 43, pp. 13055-62.CrossRef
44.
[44] I.-H. Jung, S.A. Decterov and A.D. Pelton, J. Phase Equilib. Diffus., 2004, vol. 25, pp. 329-45.CrossRef
45.
46.
[46] T.R.N. Kutty and M. Nayak, J. Alloys Compd., 1998, vol. 269, pp. 75-87.CrossRef
47.
[47] M. Hillert, B. Jansson and B. Sundman, Z. Metallkd., 1988, vol. 79, pp. 81-87.
48.
[48] S.A. Degterov, A.D. Pelton, E. Jak and P.C. Hayes, Metall. Mater. Trans. B, 2001, vol. 32B, pp. 643-57.CrossRef
49.
50.
[50] I.-H. Jung, S. Decterov and A.D. Pelton, J. Am. Ceram. Soc., 2005, vol. 88, pp. 1921-28.CrossRef
51.
[51] I.-H. Jung, S.A. Decterov and A.D. Pelton, J. Phys. Chem. Solids, 2004, vol. 65, pp. 1683-95.CrossRef
52.
[52] S. Chatterjee and I.-H. Jung, J. Eur. Ceram. Soc., 2014, vol. 34, pp. 1611-21.CrossRef
53.
[53] P. Wu, G. Eriksson and A.D. Pelton, J. Am. Ceram. Soc., 1993, vol. 76, pp. 2065-75.CrossRef
54.
[54] F.Y. Galakhov, Izv. Akad. Nauk SSSR, Ser. Khim., 1959, vol. 4, pp. 575-81.
55.
[55] D.W. Strickler and R. Roy, J. Am. Ceram. Soc., 1961, vol. 44, pp. 225-30.CrossRef
56.
57.
[57] Y. Ikeda, H. Ito, G. Matsumoto and H. Hayashi, J. Nucl. Mater., 1981, vol. 97, pp. 47-58.CrossRef
58.
G.K. Duncan, Phase diagram studies of the beta-aluminas, in: Department of Chemistry, University of Aberdeen, Aberdeen, 1985.
59.
60.
[60] A.M. Lejus and R. Collongues, Compt. Rend., 1962, vol. 254, pp. 2005-07.
61.
[61] I. Levin and D. Brandon, J. Am. Ceram. Soc., 1998, vol. 81, pp. 1995-2012.CrossRef
62.
[62] G. Lambotte and P. Chartrand, J. Chem. Thermodyn., 2013, vol. 57 pp. 306-34.CrossRef
63.
[63] F. Stewner and R. Hoppe, Z. Anorg. Allg. Chem., 1971, vol. 380, pp. 241-43.CrossRef
64.
[64] O.L. Andreev, G.V. Zelyutin, Z.S. Martem’yanova and N.N. Batalov, Inorg. Mater., 2001, vol. 37, pp. 177-79.CrossRef
65.
[65] M. Marezio and J.P. Remeika, J. Chem. Phys., 1966, vol. 44, pp. 3143-44.CrossRef
66.
[66] M.W. Chase: NIST-JANAF Thermochemical Tables, American Institute of Physics for the National Institute of Standards and Technology, Washington, DC, Woodbury, 1998
67.
[67] P. Tarte, Compt. Rend., 1962, vol. 254, pp. 2008-10.
68.
[68] G.K. Duncan and A.R. West, Solid State Ionics, 1983, vol. 9-10, pp. 259-64.CrossRef
69.
[69] C. Kroger and E. Fingas, Z. Anorg. Allg. Chem., 1935, vol. 224, pp. 289-304.CrossRef
70.
T.F. Fedorov and F.I. Shamrai, Primenenie Vakuuma v Met., Akad. Nauk S.S.S.R., Inst. Met. im. A. A. Baikova, 1960, pp. 137-42.
71.
[71] A. La Ginestra, M. Lo Jacono and P. Porta: J. Therm. Anal., 1972, vol. 4, pp. 5-17.CrossRef
72.
[72] S.K. Rakshit, Y.P. Naik, S.C. Parida, S. Dash, Z. Singh, B.K. Sen and V. Venugopal, J. Solid State Chem., 2008, vol. 181, pp. 1402-12.CrossRef
73.
74.
G.W. Hollenberg and D.E. Baker, HEDL-SA-2674-FP, 84th Annual Meeting of American Ceramic Society, Cincinnati, 1982.
75.
[75] A.U. Christensen, K.C. Conway and K.K. Kelley, Bur. Mines Rep. Invest., 1960, vol. 5565, pp. 7.
76.
[76] M. Asou, T. Terai and Y. Takahashi, J. Nucl. Mater., 1990, vol. 175, pp. 42-46.CrossRef
77.
78.
I. Barin, La-Lu2O3, in: Thermochemical data of pure substances, Wiley-VCH Verlag GmbH, 2008, pp. 925–92.
79.
[79] S.-G. Ma, Y.-H. Shen, T. Gao and P.-H. Chen, Int. J. Hydrogen Energy, 2015, vol. 40, pp. 3762-70.CrossRef
80.
D.L. Hildenbrand, L.P. Thread, W.F. Hall, F. Ju, F.S. La Viola and N.D. Potter, An experimental program for obtaining the thermodynamic properties of propellant combustion products, in: U-2055, Ford Motor Company, 1963.
81.
[81] E.R. Plante and L.P. Cook, Adv. Ceram., 1990, vol. 27, pp. 129-45.
82.
[82] A.F. Venero and E.F. Westrum Jr., J. Chem. Thermodyn., 1975, vol. 7, pp. 693-702.CrossRef
83.
N.D. Potter, M.H. Boyer, F. Ju, D.L. Hildenbrand and E. Murad, Thermodynamic properties of propellant combustion products, in, Philco-Ford Corp., 1970, pp. 160.
84.
[84] D.-G. Kim, M.-A. Van Ende, P. Hudon and I.-H. Jung, J. Non-Cryst. Solids, 2017, vol. 471, pp. 51-64.CrossRef
85.
[85] E. Kordes and E. Rottig, Z. Anorg. Allg. Chem., 1951, vol. 264, pp. 34-47.CrossRef
86.
E. Kordes, Z. Kristallogr., Kristallgeom., Kristallphys., Kristallchem., 1935, vol. 91, pp. 193-228.
87.
[87] E.J.W. Verwey and E.L. Heilmann, J. Chem. Phys., 1947, vol. 15, pp. 174-80.CrossRef
88.
89.
[89] R. Famery, F. Queyroux, J.-C. Gilles and P. Herpin, J. Solid State Chem., 1979, vol. 30, pp. 257-63.CrossRef
90.
[90] L. Debray and A. Hardy, Compt. Rend., 1960, vol. 251, pp. 725-26.
91.
N.T. Melamed, F.D.S. Barros, P.J. Viccaro and J.O. Artman, Phys. Rev. B, 1972, vol. 5, pp. 3377-87CrossRef
92.
[92] R.C. Doman and R.N. McNally, J. Mater. Sci., 1973, vol. 8, pp. 189-91.CrossRef
93.
[93] L.T. Menzheres, N.P. Kotsupalo and A.S. Berger, Z. Neorg. Khim., 1978, vol. 23, pp. 2804-09.
94.
[94] G. Izquierdo and A.R. West, J. Am. Ceram. Soc., 1980, vol. 63, pp. 227.CrossRef
95.
S. Hafner and F. Laves, Ordnung / Unordnung und Ultrarotabsorption III. Die Systeme MgAl2O4–Al2O3 und MgAl2O4–LiAl5O8, Z. Kristallogr.- Crys. Mat., vol. 115, 1961, pp. 321-30.
96.
[96] R.K. Datta and R. Roy, Amer. Mineral., 1968, vol. 53, pp. 1456-75.
97.
[97] Y. Mordekovitz and S. Hayun, J. Am. Ceram. Soc., 2016, vol. 99, pp. 2786-94.CrossRef
98.
99.
100.
O. Kubaschewski, C.B. Alcock and P.J. Spencer: Materials Thermochemistry, Pergamon Press., 1993
Metadata
Title
Critical Evaluation and Thermodynamic Optimization of the Li2O-Al2O3 and Li2O-MgO-Al2O3 Systems
Authors
Bikram Konar
Marie-Aline Van Ende
In-Ho Jung
Publication date
27-07-2018
Publisher
Springer US
Published in
Metallurgical and Materials Transactions B / Issue 5/2018
Print ISSN: 1073-5615
Electronic ISSN: 1543-1916
DOI
https://doi.org/10.1007/s11663-018-1349-x

Other articles of this Issue 5/2018

Metallurgical and Materials Transactions B 5/2018 Go to the issue

OriginalPaper

Effect of Processing Parameters and Shape of Blade on the Solidification of Single-Crystal CMSX-4 Ni-Based Superalloy

Communication

Compositional and Thermal Characterization of Potential Nano-Carbon Copper Composite

OriginalPaper

Effect of Hydrogen Addition on Softening and Melting Reduction Behaviors of Ferrous Burden in Gas-Injection Blast Furnace

OriginalPaper

Modelling of Blast Furnace with Respective Chemical Reactions in Coke and Ore Burden Layers

OriginalPaper

Similarity Criteria for the Study of Removal of Spherical Non-metallic Inclusions in Physical Models of Continuous Casting Tundishes: A More Fundamental Approach

OriginalPaper

Yttria-Stabilized Zirconia Aided Electrochemical Investigation on Ferric Ions in Mixed Molten Calcium and Sodium Chlorides

Premium Partners

    Image Credits