Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 9/2017

03-02-2017

CVD grown graphene/CNT composite as additive material to improve the performance of electric double layer capacitors (EDLCs)

Authors: Shu Ye, Ick-Jun Kim, Sun-hye Yang, Jae-won Lee, Won-Chun Oh

Published in: Journal of Materials Science: Materials in Electronics | Issue 9/2017

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

In this work, large area graphene-carbon nanotube (G-CNT) composite as additive material for EDLC performance was grown on copper foil at low temperature (500 °C) and at atmospheric pressure by using chemical vapor deposition (CVD). The growth state was characterized by field emission scanning electron microscope (FESEM), high-resolution transmission electron microscopy (HRTEM), and Raman spectroscopy. EDLC electrodes based on high surface area activated carbon (YP50F) and G-CNT were then fabricated by a facile step. Coin-type EDLC cells with two symmetrical carbon electrodes were assembled using the prepared carbon materials. The electrochemical performance of G-CNT based eletrodes were examined in an electrolyte solution of tetraethylammonium tetrafluoroborate ((C2H5)4NBF4, TEABF4) in propylene carbonate (C4H6O3, PC) and measured by galvanostatic charge/discharge and cyclic voltammetry methods.
previous article Dielectric relaxation in CoFe2−xYxO4 (x = 0.2, 0.4, 0.6) prepared by hydrothermal method
next article Preparation of anatase/TiO2(B) TiO2 nanosheet for high performance of photocatalytic reduction of CO2

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
T.Y. Kim, H.W. Lee, M. Stoller, D.R. Dreyer, C.W. Bielawski, R.S. Ruoff, K.S. Suh, High-performance supercapacitors based on poly(ionic liquid)-modified graphene electrodes. ACS Nano 5, 436 (2011)CrossRef
2.
V. Khomenko, E. Raymundo-Pi˜nero, F. B’eguin, High-energy density graphite/AC capacitor in organic electrolyte. J. Power Sources 177, 643 (2008)CrossRef
3.
G. Hirankumar, S. Selvasekarapandian, N. Kuwata, J. Kawamura, T. Hattori, Thermal, electrical and optical studies on the poly(vinyl alcohol) based polymer electrolytes. J. Power Sources 144, 262–267 (2005)CrossRef
4.
M. Patel, M. Gnanavel, A.J. Bhattacharyya, Utilizing an ionic liquid for synthesizing a soft matter polymer “gel” electrolyte for high rate capability lithium-ion batteries. J. Mater. Chem. 21, 17419–17424 (2011)CrossRef
5.
G.P. Pandey, S.A. Hashmi, Ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate-based gel polymer electrolyte for electrochemical capacitors. J. Mater. Chem. A 1, 3372–3378 (2013)CrossRef
6.
A. Burke, Ultracapacitors: why, how, and where is the technology. J. Power Sources 91, 37 (2000)CrossRef
7.
Y. Zhang, H. Feng, X. Wu, L. Wang, A. Zhang, T. Xia, H. Dong, X. Li, L. Zhang, Progress of electrochemical capacitor electrode materials: a review. Int. J. Hydrog. Energy 34, 4889 (2009)CrossRef
8.
C.-W. Liew, S. Ramesh, Comparing triflate and hexafluorophosphate anions of ionic liquids in polymer electrolytes for supercapacitor applications. Materials 7, 4019–4033 (2014)CrossRef
9.
A.K. Arof, M.Z. Kufian, M.F. Syukur, M.F. Aziz, A.E. Abdelrahman, S.R. Majid, Electrical double layer capacitor using poly(methyl methacrylate)-C4BO8Li gel polymer electrolyte and carbonaceous material from shells of matakucing (Dimocarpuslongan) fruit. Electrochim. Acta 74, 39–45 (2012)CrossRef
10.
S. Mitra, A.K. Shukla, S. Sampath, Electrochemical capacitors with plasticized gel–polymer electrolytes. J. Power Sources 101, 213–219 (2001)CrossRef
11.
L.L. Zhang, X.S. Zhao, Carbon-based materials as supercapacitor electrodes. Chem. Soc. Rev. 38, 2520 (2009)CrossRef
12.
S.-I. Lee, K. Saito, K. Kanehashi, M. Hatakeyama, S. Mitani, S.-H. Yoon, Y. Korai, I. Mochida, 11B NMR study of the BF4–anion in activated carbons at various stages of charge of EDLCs in organic electrolyte. Carbon 44, 2578 (2006)CrossRef
13.
C. Lei, P. Wilson, C. Lekakou, Effect of poly(3,4-ethylenedioxythiophene) (PE.) in carbon-based composite electrodes for electrochemical supercapacitors. J. Power Sources 196, 7823 (2011)CrossRef
14.
T.M. Alam, D.R. Dreyer, C.W. Bielwaski, R.S. Ruoff, Measuring molecular dynamics and activation energies for quaternary acyclic ammouium and cyclic pyrrolidinium ionic liquids using 14 N NMR spectroscopy. J. Phys. Chem. A 115, 4307 (2011)CrossRef
15.
R.K. Harris, T.V. Thompson, P. Forshaw, N. Foley, K.M. Thomas, P.R. Norman, C. Pottage, A magic-angle spinning NMR study into the adsorption of deuterated water by activated carbon. Carbon 34, 1275 (1996)CrossRef
16.
P. Azais, L. Duclaux, P. Florian, D. Massiot, M.-A. Lillo-Rodenas, A. LinaresSolano, J.-P. Peres, F. Beguin, Causes of supercapacitors ageing in organic electrolyte. J. Power Sources 171, 1046 (2007)CrossRef
17.
K. Kiyohara, T. Sugino, K. Asaka, Phase transition in porous electrodes. J. Chem. Phys. 134, 15710 (2011)CrossRef
18.
B. Fang, L. Binder, A modified activated carbon aerogel for high-energy storage in electric double layer capacitors. J. Power Sources 163, 616 (2006)CrossRef
19.
C.-C. Hu, C.-C. Wang, F.-C. Wu, R.-L. Tseng, Characterization of pistachio shellderived carbons activated by a combination of KOH and CO2 for electric doublelayer capacitors. Electrochim. Acta 52, 2498 (2007)CrossRef
20.
A. Tanimura, A. Kovalenko, F. Hirata, Molecular theory of an electrochemical double layer in a nanoporous carbon supercapacitor. Chem. Phys. Lett. 378, 638 (2003)CrossRef
21.
C. Dangler, M. Rane-Fondacaro, T.S. Devarajan, S. Higashiya, J. Snyder, P. Haldar, Role of conducting carbon in electrodes for electric double layer capacitors. Mater. Lett. 65, 300 (2011)CrossRef
22.
C. Emmenegger, P. Mauron, P. Sudan, P. Wenger, V. Hermann, R. Gallay, A. Züttel, Investigation of electrochemical double-layer (EDLC) capacitors electrodes based on carbon nanotubes and activated carbon materials. J. Power Sources 124, 321–329 (2003)CrossRef
23.
G.-X. Wang, B.-L. Zhang, Z.-L. Yu, M.-Z. Qu, Manganese oxide/MWNTs composite electrodes for supercapacitors. Solid State Ionics 176, 1169–1174 (2005)CrossRef
24.
S. Mitani, S.-I. Lee, M. Hatakeyama, K. Kanehashi, K. Saito, Y. Korai, I. Mochida, Behavior of electrolyte ions under high voltage in the electric double layer evaluated multi nuclear magnetic resonance, in: Proc. Internatinal Conference of Carbon, Gyeongju, 2005, p. 3–7
25.
P. Simon, Y. Gogotsi, Materials for electrochemical capacitors. Nat. Mater. 7, 845 (2008)CrossRef
26.
G.W. Wangner, B.K. Maclver, Y.-C. Yang, Magic angle spinning NMR study of adsorbate reactions on activated charcoal. Langmuir 11, 1439 (1995)CrossRef
27.
H. Wang, T.K.-J. Köster, N.M. Trease, J. Ségalini, P.-L. Taberna, P. Simon, Y. Gogotsi, C.P. Grey, Real-time NMR studies of electrochemical double-layer capacitors. J. Am. Chem. Soc. 133, 19270 (2012)CrossRef
28.
C.C. Yang, G.M. Wu, Study of microporous PVA/PVC composite polymer membrane and its application to MnO2 capacitors. Mater. Chem. Phys. 114, 948–955 (2009)CrossRef
29.
H.-C. Wu, Y.-P. Lin, E. Lee, W.-T. Lin, J.-K. Hu, H.-C. Chen, N.-L. Wu, High-performance carbon-based supercapacitors using Al current-collector with conformal carbon coating. Mater. Chem. Phys. 117, 294 (2009)CrossRef
30.
A.G. Pandolfo, G.J. Wilson, T.D. Huynh, A.F. Hollenkamp, The influence of conductive additives and inter-particle voids in carbon EDLC electrodes. Fuel Cells 10, 856 (2010)CrossRef
31.
J. Qiao, T. Okada, H. Ono, High molecular weight PVA-modified PVA/PAMPS protonconducting membranes with increased stability and their application in DMFCs. Solid State Ionics 180, 1318–1323 (2009)CrossRef
32.
E.K. Niu, R. Sichel, D. Hoch, H.Tennent Moy,, High power electrochemical capacitors based on carbon nanotube electrodes. Appl. Phys. Lett. 70, 1480 (1997)CrossRef
33.
S. Murali, D.R. Dreyer, P. Valle-Vigón, M.D. Stoller, Y. Zhu, C. Morales, A.B. Fuertes, C.W. Bielawski, R.S. Ruoff, Mesoporous carbon capsules as electrode materials in electrochemical double layer capacitors. Phys. Chem. Chem. Phys. 13, 2652 (2011)CrossRef
34.
Y. Lu, D.F. Wang, T. Li, X.Q. Zhao, Y.L. Cao, H.X. Yang, Y.Y. Duan, Poly(vinyl alcohol)/ poly(acrylic acid) hydrogel coatings for improving electrode-neural tissue interface. Biomaterials 30 (2009) 4143–4151.CrossRef
35.
Y.J. Kim, Y.A. Kim, T. Chino, H. Suezaki, M. Endo, M.S. Dresselhaus, Chemically modified multiwalled carbon nanotubes as an additive for supercapacitors. Small 2, 339 (2006)CrossRef
36.
C. Portet, P.L. Taberna, P. Simon, C. Laberty-Robert, Modification of Al current collector surface by sol–gel deposit for carbon–carbon supercapacitor applications. Electrochim. Acta 49, 905 (2004)CrossRef
37.
Y.-S. Ye, J. Rick, B.-J. Hwang, Ionic liquid polymer electrolytes. J. Mater. Chem. A 1, 2719–2743 (2013)CrossRef
38.
C.-W. Liew, S. Ramesh, A.K. Arof, Investigation of ionic liquid-based poly(vinyl alcohol) proton conductor for electrochemical double-layer capacitor. High Perform. Polym. 26, 632–636 (2014)CrossRef
39.
S. Ishimoto, Y. Asakwa, M. Shinya, K. Naoi, Degradation responses of activatedcarbon-based EDLCs for higher voltage operation and their factors. J. Electrochem. Soc. 156, A563 (2009)CrossRef
40.
M. Hahn, A. Wursing, R. Gallay, P. Novak, R. Kotz, Gas evolution in activated carbon/propylene carbonate based double-layer capacitors. Electrochem. Commun. 7, 925 (2005)CrossRef
41.
K.S. Kim, S.Y. Park, S. Choi, H. Lee, Ionic liquid–polymer gel electrolytes based on morpholinium salt and PVdF(HFP) copolymer. J. Power Sources 155, 385–390 (2006)CrossRef
42.
X. Kang, Nonaqueous liquid electrolytes for lithium-based rechargeable batteries. Chem. Rev. 104, 4303–4417 (2004)CrossRef
43.
P.L. Taberna, C. Portet, P. Simon, Electrode surface treatment and electrochemical impedance spectroscopy study on carbon/carbon supercapacitors, Appl. Phys. A 82, 639 (2006)CrossRef
44.
A. Burke, R&D considerations for the performance and application of electrochemical capacitors, Electrochim. Acta 53, 1083 (2007)CrossRef
45.
S. Ye, L. Zhu, I.-K. Kim, S.-H. Yang, W.-C. Oh, Characterization of expanded graphene nanosheet as additional material and improved performances for electric double layer capacitors. J. Ind. Eng. Chem. 43, 53–60 (2016)CrossRef
Metadata
Title
CVD grown graphene/CNT composite as additive material to improve the performance of electric double layer capacitors (EDLCs)
Authors
Shu Ye
Ick-Jun Kim
Sun-hye Yang
Jae-won Lee
Won-Chun Oh
Publication date
03-02-2017
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 9/2017
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-6349-0

Other articles of this Issue 9/2017

Journal of Materials Science: Materials in Electronics 9/2017 Go to the issue

OriginalPaper

Investigation of the critical properties near room temperature in La0.7Ca0.2Ba0.1MnO3 manganite

OriginalPaper

Electromagnetic and microwave absorption properties of flaky FeCrAl particles

OriginalPaper

Morphological development of CdSe0.6Te0.4 nanostructures by simple preparative parameters in electrochemical method and their subsequent influence on photoelectrochemical cell

OriginalPaper

Preparation and characterizations of active carbon/barium ferrite/polypyrrole composites

OriginalPaper

Preferred location for conducting filament formation in thin-film nano-ionic electrolyte: study of microstructure by atom-probe tomography

OriginalPaper

Design of a flexure composite with large flexoelectricity