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Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 23/2020

11-11-2020

Development and performance of A-site rich perovskite-type material for enhanced oxygen evolution reaction in alkaline electrolyte

Authors: Tianjing Li, Wei Guo, Qingle Shi

Published in: Journal of Materials Science: Materials in Electronics | Issue 23/2020

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Abstract

A-site rich perovskites Ba2xCoMoO6 (x = 1, 1.1, 1.2, and 1.3) were synthesised by a solid-state reaction method. The as-prepared Ba2.4CoMoO6 catalyst showed good catalytic activity towards oxygen evolution reaction (OER) activity with an overpotential of 420 mV at 10 mA cm−2, which was enhanced by 100 mV compared with that of Ba2CoMoO6, with a low Tafel slope of 79 mV dec−1, an obviously enhanced electrochemical active surface area value, and sharply improved mass and specific activities. The enhanced OER activity even surpassed the precious metal oxide IrO2 and perovskite benchmark Ba0.5Sr0.5Co0.8Fe0.2O3-δ activities.
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Appendix
Available only for authorised users
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Metadata
Title
Development and performance of A-site rich perovskite-type material for enhanced oxygen evolution reaction in alkaline electrolyte
Authors
Tianjing Li
Wei Guo
Qingle Shi
Publication date
11-11-2020
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 23/2020
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-04639-2

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