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Cellulose
Published in: Cellulose 12/2018

28-09-2018 | Original Paper

Diallyl dimethyl ammonium chloride-grafted cellulose filter membrane via ATRP for selective removal of anionic dye

Authors: Shengchang Lu, Zuwu Tang, Wenyan Li, Xinhua Ouyang, Shilin Cao, Lihui Chen, Liulian Huang, Hui Wu, Yonghao Ni

Published in: Cellulose | Issue 12/2018

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Abstract

In this paper, poly(diallyl dimethyl ammonium chloride) (PDADMAC)-grated cellulose filter membranes (cellulose-g-PDADMAC) were fabricated via atom transfer radical polymerization (ATRP) for selective removal of anionic dye from wastewater. Gel permeation chromatography (GPC), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectroscopy (FTIR) showed that PDADMAC was grafted onto the filter membrane surface via a controllable living polymerization. The resultant cellulose-g-PDADMAC membranes exhibit selective removal for anionic methyl orange (MO) through rapid and facile filtration using model MO/rhodamine B (RB) mixture, due to the electrostatic interaction between quaternary ammonium groups of membrane and the sulfonic groups of MO. The decolorization ratio of MO remains higher than 95% when the graft ratio is 13.3% even after 6 cycles. Cellulose-g-PDADMAC also shows effective antimicrobial activities against S. aureus and E. coli. The modified filter membranes are promising for the potential application in wastewater purification.

Graphical abstract

PDADMAC-grated cellulose filter membranes with good recyclability and high antimicrobial activity were fabricated via atom transfer radical polymerization for selective removal of anionic dye from wastewater.
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Appendix
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Metadata
Title
Diallyl dimethyl ammonium chloride-grafted cellulose filter membrane via ATRP for selective removal of anionic dye
Authors
Shengchang Lu
Zuwu Tang
Wenyan Li
Xinhua Ouyang
Shilin Cao
Lihui Chen
Liulian Huang
Hui Wu
Yonghao Ni
Publication date
28-09-2018
Publisher
Springer Netherlands
Published in
Cellulose / Issue 12/2018
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-018-2052-4

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