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Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 24/2019

09-11-2019

Dispersivity ferroelectric phase transition of La-doped BaZr0.1Ti0.89Fe0.01O3 ceramics

Authors: Yun Liu, Zhanshen Zheng, Yuanliang Li, Kaibiao Xi, Yueshan Mi, Wenshuo Kang, Rujie Zhao

Published in: Journal of Materials Science: Materials in Electronics | Issue 24/2019

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Abstract

BaZr0.1Ti0.89Fe0.01O3(BZTF)was prepared by sol–gel method using Ba(CH3COO)2, ZrO(NO3)2 and [CH3(CH2)3O]4Ti as crude materials, La2O3 and Fe2O3 as doping materials, changing the amount of dopant and using different sintering temperatures. The influence of La doping on the crystal structure, micro structure and diffuse ferroelectric phase transition of the sample were investigated. XRD results showed that all samples showed a characteristic peak of a single perovskite type. The appropriate doping amount of La3+ can improve the electrical performance of the sample. With the increase in La content, the degree of lattice distortion of the sample increases, causing the Curie temperature to move toward the low temperature. At the same time, the increase in the degree of dispersion of ferroelectric phase transitions can be attributed to the growth of grains and the reduction of long-range ordered domains. When doped with 0.6 mol% La, the sample has the highest degree of dispersivity ferroelectric phase transition, and the dielectric properties is the best:(ε25℃ = 5680, tanδ = 0.044, Tc = 42℃, γ = 1.89).
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Metadata
Title
Dispersivity ferroelectric phase transition of La-doped BaZr0.1Ti0.89Fe0.01O3 ceramics
Authors
Yun Liu
Zhanshen Zheng
Yuanliang Li
Kaibiao Xi
Yueshan Mi
Wenshuo Kang
Rujie Zhao
Publication date
09-11-2019
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 24/2019
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-02508-1

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