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Journal of Materials Science: Materials in Electronics

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11-11-2019

Effect of Mn²⁺ as a redox additive on ternary doped polyaniline-metal nanocomposite: an efficient dielectric material

Authors: C. Anju, Shiny Palatty

Published in: Journal of Materials Science: Materials in Electronics | Issue 24/2019

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Abstract

An efficient ternary doped polyaniline-metal nanocomposite was synthesized via in situ rapid mixing chemical oxidative polymerization method. The detailed morphological and structural analysis shows the incorporation of binary transition metals (Fe & Mn) in a highly crystalline PANI matrix with a modified flaky morphology. Further dielectric and electrochemical characterizations substantiate a high dielectric constant and specific capacitance of about 613F/g with a good cyclic stability for the as synthesized PANI material.

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K. Le, M. Gao, W. Liu, J. Liu, Z. Wang, F. Wang, V. Murugadoss, S. Wu, T. Ding, Z. Guo, MOF-derived hierarchical core-shell hollow iron-cobalt sulfides nanoarrays on Ni foam with enhanced electrochemical properties for high energy density asymmetric supercapacitors. Electrochim. Acta 323, 134826 (2019). https://doi.org/10.1016/j.electacta.2019.134826 CrossRef

W. Du, X. Wang, J. Zhan, X. Sun, L. Kang, F. Jiang, X. Zhang, Q. Shao, M. Dong, H. Liu, V. Murugadoss, Z. Guo, Biological cell template synthesis of nitrogen-doped porous hollow carbon spheres/MnO₂ composites for high-performance asymmetric supercapacitors. Electrochim. Acta (2018). https://doi.org/10.1016/j.electacta.2018.11.074 CrossRef

K. Le, Z. Wang, F. Wang, Q. Wang, Q. Shao, V. Murugadas, S. Wu, W. Liu, J. Liu, Q. Gao, Z. Guo, Sandwich-like NiCo layered double hydroxides/reduced graphene oxide nanocomposite cathode for high energy density asymmetric supercapacitors. Dalton Trans. (2019). https://doi.org/10.1039/c9dt00615j CrossRef

Y. Ma, M. Ma, X. Yin, Q. Shao, N. Lu, Y. Feng, Y. Lu, Tuning polyaniline nanostructures via end group substitutions and their morphology dependent electrochemical performances. Polymer (2018). https://doi.org/10.1016/j.polymer.2018.09.051 CrossRef

Y. Ma, C. Hou, H. Zhang, Q. Zhang, H. Liu, S. Wu, Electrochimica acta three-dimensional core-shell Fe₃O₄/Polyaniline coaxial heterogeneous nanonets: preparation and high performance supercapacitor electrodes. Electrochim. Acta 315, 114–123 (2019). https://doi.org/10.1016/j.electacta.2019.05.073 CrossRef

K. Sun, J. Dong, Z. Wang, Z. Wang, G. Fan, Q. Hou, L. An, M. Dong, R. Fan, Z. Guo, Tunable negative permittivity in flexible graphene/PDMS metacomposites. J. Phys. Chem. C (2019). https://doi.org/10.1021/acs.jpcc.9b06753 CrossRef

Y. Zhang, Y. An, L. Wu, H. Chen, Z. Li, H. Dou, V. Murugadoss, J. Fan, X. Zhang, X. Mai, Z. Guo, Metal-free energy storage systems: combining batteries with capacitors based on methylene blue functionalized graphene cathode. Mater. Chem. A (2019). https://doi.org/10.1039/C9TA06734E CrossRef

Y. Zhai, J. Wang, Q. Gao, Y. Fan, C. Hou, Y. Hou, H. Liu, Q. Shao, S. Wu, L. Zhao, T. Ding, F. Dang, Z. Guo, Highly efficient cobalt nanoparticles anchored porous N-doped carbon nanosheets electrocatalysts for Li-O₂ batteries. J. Catal. 377, 534–542 (2019). https://doi.org/10.1016/j.jcat.2019.07.055 CrossRef

C. Hou, J. Wang, W. Du, J. Wang, Y. Du, C. Liu, J. Zhang, H. Hou, F. Dang, L. Zhao, Z. Guo, Molybdenum carbide heterostructures coupled with 3D holey carbon nanosheets for highly efficient and ultrastable cycling lithium-ion. J. Mater. Chem. A 7, 13460–13472 (2019). https://doi.org/10.1039/c9ta03551f CrossRef

10.

M. Liu, Z. Yang, H. Sun, C. Lai, X. Zhao, H. Peng, T. Liu, A hybrid carbon aerogel with both aligned and interconnected pores as interlayer for high-performance lithium—sulfur batteries. Nano Res. (2016). https://doi.org/10.1007/s12274-016-1244-1 CrossRef

11.

M. Liu, Y. Liu, Y. Yan, F. Wang, J. Liu, T. Liu, A highly conductive carbon-sulfur film with interconnected mesopores as advanced cathode for lithium-sulfur batteries. ChemComm (2017). https://doi.org/10.1039/C7CC04523A CrossRef

12.

J. Tian, Q. Shao, X. Dong, J. Zheng, D. Pan, X. Zhang, H. Cao, L. Hao, J. Liu, X. Mai, Z. Guo, Electrochim. Acta (2018). https://doi.org/10.1016/j.electacta.2017.12.094 CrossRef

13.

V. Murugadas, J. Lin, H. Liu, X. Mai, T. Dina, Z. Guo, S. Angaiah, Optimizing graphene content in nise/graphene nanohybrid counter electrode on boosting photovoltaic performance of dye-sensitized solar cells. Nanoscale (2019). https://doi.org/10.1039/C9NR07060E CrossRef

14.

Y. Xie, X. Sha, Electrochemical cycling stability of nickel (II) coordinated polyaniline. Synth. Met. 237, 29–39 (2018). https://doi.org/10.1016/j.synthmet.2018.01.011 CrossRef

15.

C. Hu, S. Chen, Y. Wang, X. Peng, W. Zhang, J. Chen, Excellent electrochemical performances of cabbage-like polyaniline fabricated by template synthesis. J. Power Sources 321, 94–101 (2016). https://doi.org/10.1016/j.jpowsour.2016.04.113 CrossRef

16.

H. Guan, L. Fan, H. Zhang, X. Qu, Polyaniline nanofibers obtained by interfacial polymerization for high-rate supercapacitors. Electrochim. Acta 56, 964–968 (2010). https://doi.org/10.1016/j.electacta.2010.09.078 CrossRef

17.

Y. Wang, Y. Song, Y. Xia, Characterization and applications chemical functional materials. Chem. Soc. Rev. 45, 5925–5950 (2016). https://doi.org/10.1039/C5CS00580A CrossRef

18.

M.N. Nadagouda, R.S. Varma, Green approach to bulk and template-free synthesis of thermally stable reduced polyaniline nanofibers for capacitor applications. Green Chem. 9, 632 (2007). https://doi.org/10.1039/b614633c CrossRef

19.

S.A. El-khodary, G.M. El-enany, M. El-okr, M. Ibrahim, Modified iron doped polyaniline/sulfonated carbon nanotubes for all symmetric solid-state supercapacitor. Synth. Met. 233, 41–51 (2017). https://doi.org/10.1016/j.synthmet.2017.09.002 CrossRef

20.

S. Ghosh, T. Maiyalagan, R.N. Basu, Nanostructured conducting polymers for energy applications: towards a sustainable platform. Nanoscale 8, 6921–6947 (2016). https://doi.org/10.1039/C5NR08803H CrossRef

21.

G. Ciri, Recent advances in polyaniline research: polymerization mechanisms, structural aspects, properties and applications. Synth. Met. 177, 1–47 (2013). https://doi.org/10.1016/j.synthmet.2013.06.004 CrossRef

22.

D.M. Jundale, S.T. Navale, G.D. Khuspe, D.S. Dalavi, P.S. Patil, V.B. Patil, Polyaniline-CuO hybrid nanocomposites: synthesis, structural, morphological, optical and electrical transport studies. J. Mater. Sci.: Mater. Electron. (2016). https://doi.org/10.1007/s10854-013-1280-5 CrossRef

23.

E. Hur, A. Arslan, Cobalt ion-doped polyaniline, poly(-methylaniline), and poly(-ethylaniline): electrosynthesis and characterisation using electrochemical methods in acidic solutions. Chem. Papers (2014). https://doi.org/10.2478/s11696-014-0605-z CrossRef

24.

L. Tang, F. Duan, M. Chen, Fabrication of ferric chloride doped polyaniline/multilayer super-short carbon nanotube nanocomposites for supercapacitor applications. J. Solid State Electrochem. (2016). https://doi.org/10.1007/s10008-016-3264-x CrossRef

25.

L.N. Shubha, P. Madhusudana Rao, Temperature characterization of dielectric permittivity and AC conductivity of nano copper oxide-doped polyaniline composite. J. Adv. Dielectr. 6, 1650018 (2016). https://doi.org/10.1142/s2010135x16500181 CrossRef

26.

C. Li, H. Bai, G. Shi, Conducting polymer nanomaterials: electrosynthesis and applications. Chem. Soc. Rev. (2009). https://doi.org/10.1039/b816681c CrossRef

27.

S. Saha, P. Samanta, N. Chandra, T. Kuila, A review on the heterostructure nanomaterials for supercapacitor application. J. Energy Storage 17, 181–202 (2018). https://doi.org/10.1016/j.est.2018.03.006 CrossRef

28.

N. Parveen, N. Mahato, M. Omaish, M. Hwan, Enhanced electrochemical behavior and hydrophobicity of crystalline polyaniline @ graphene nanocomposite synthesized at elevated temperature. Compos. B 87, 281–290 (2016). https://doi.org/10.1016/j.compositesb.2015.10.029 CrossRef

29.

S. Dhibar, P. Bhattacharya, G. Hatui, S. Sahoo, C.K. Das, transition metal-doped polyaniline/single-walled carbon nanotubes nanocomposites: efficient electrode material for high performance supercapacitors. ACS Sustain. Chem. Eng. (2014). https://doi.org/10.1021/sc5000072 CrossRef

30.

T. Sen, S. Mishra, N.G. Shimpi, A β Cyclodextrin based binary dopant for polyaniline: structural, thermal, electrical, and sensing performance. Mater. Sci. Eng. B 220, 13–21 (2017). https://doi.org/10.1016/j.mseb.2017.03.003 CrossRef

31.

H. Gu, X. Xu, J. Cai, S. Wei, H. Wei, H. Liu, D.P. Young, Q. Shao, S. Wu, T. Ding, Z. Guo, Controllable organic magnetoresistance in polyaniline coated poly(p-phenylene-2,6-benzobisoxazole) short fibers. ChemComm (2019). https://doi.org/10.1039/c9cc04789a CrossRef

32.

Y. Ma, Z. Zhuang, M. Ma, Y. Yang, W. Li, M. Dong, S. Wu, T. Ding, Z. Guo, Solid polyaniline dendrites consisting of high aspect ratio branches self- assembled using sodium lauryl sulfonate as soft templates: synthesis and electrochemical performance. Polymer (Guildf) 182, 121808 (2019). https://doi.org/10.1016/j.polymer.2019.121808 CrossRef

33.

Q. Hu, N. Zhou, K. Gong, H. Liu, Q. Liu, Intracellular polymer substances induced conductive polyaniline for improved methane production from anaerobic wastewater treatment. ACS Sustain. Chem. Eng. (2019). https://doi.org/10.1021/acssuschemeng.8b05847 CrossRef

34.

U. Bogdanovic, V. Vodnik, M. Mitric, S. Dimitrijevic, S.D. Skapin, V. Zunic, M. Budimir, M. Stoiljkovic, Nanomaterial with high antimicrobial efficacy copper/polyaniline nanocomposite. ACS Appl. Mater. Interfaces (2015). https://doi.org/10.1021/am507746m CrossRef

35.

D. Zhou, B. Che, X. Lu, Rapid one-pot electrodeposition of polyaniline/manganese dioxide hybrids: a facile approach to stable high-performance anodic electrochromic materials. J. Mater. Chem. C 5, 1758–1766 (2017). https://doi.org/10.1039/C6TC05216A CrossRef

36.

L. Horta-romarís, M.V. González-rodríguez, A. Lasagabáster, Thermoelectric properties and intrinsic conduction processes in DBSA and NaSIPA doped polyanilines. Synth. Met. 243, 44–50 (2018). https://doi.org/10.1016/j.synthmet.2018.06.002 CrossRef

37.

S. Cho, K. Shin, J. Jang, Enhanced electrochemical performance of highly porous supercapacitor electrodes based on solution processed polyaniline thin films. ACS Appl. Mater. Interfaces 5, 9186–9193 (2013)CrossRef

38.

A.K. Mukherjee, R. Menon, Role of mesoscopic morphology in charge transport of doped polyaniline. Pramana 58, 233–239 (2002)CrossRef

39.

D. Ghosh, S. Giri, A. Mandal, C.K. Das, Supercapacitor based on H⁺ and Ni²⁺ co-doped polyaniline–MWCNTs nanocomposite: synthesis and electrochemical characterization. RSC Adv. 3, 11676 (2013). https://doi.org/10.1039/c3ra40955d CrossRef

40.

C. Anju, S. Palatty, Ternary doped plyaniline-metal nanocomposite as high performance supercapacitive material. Electrochim. Acta 299, 626–635 (2019)CrossRef

41.

M. Vellakkat, A. Kamath, S. Raghu, S. Chapi, D. Hundekal, Dielectric constant and transport mechanism of percolated polyaniline nanoclay composites. Ind. Eng. Chem. Res. 53, 16873–16882 (2014)CrossRef

42.

J. Jeon, J.O. Neal, L. Shao, J.L. Lutkenhaus, Charge storage in polymer acid-doped polyaniline-based layer-by- layer electrodes. ACS Appl. Mater. Interfaces. 5, 10127–10136 (2013)CrossRef

43.

M.H. AbdelRehim, A.M. Youssef, H. Al-Said, T. Gamal, M. Aboaly, Polyaniline and modified titanate nanowires layerby-layer plastic electrode for flexible electronic device applications. RSC Adv. 6, 94556 (2016)CrossRef

44.

X.S. Du, C.F. Zhou, Y.W. Mai, Facile synthesis of Hierarchical polyaniline nanostructures with dendritic nanofibers as scaffolds. J. Phys. Chem. C 112, 19836–19840 (2008). https://doi.org/10.1021/jp8069404 CrossRef

45.

S. Cho, M. Kim, J.S. Lee, J. Jang, Polypropylene/polyaniline nanofiber/reduced graphene oxide nanocomposite with enhanced electrical, dielectric, and ferroelectric properties for a high energy density capacitor. ACS Appl. Mater. Interfaces 7, 22301–22314 (2015). https://doi.org/10.1021/acsami.5b05467 CrossRef

46.

J. Zhu, H. Gu, Z. Luo, N. Haldolaarachige, D.P. Young, S. Wei, Z. Guo, Carbon nanostructure-derived polyaniline metacomposites: electrical, dielectric, and giant magnetoresistive properties. Langmuir 28, 10246–10255 (2012). https://doi.org/10.1021/la302031f CrossRef

47.

K. Sun, J. Xin, Z. Wang, S. Feng, Z. Wang, R. Fan, H. Liu, Weakly negative permittivity and low frequency dispersive behavior in graphene/epoxy metacomposites. J. Mater. Sci.: Mater. Electron. (2019). https://doi.org/10.1007/s10854-019-01846-4 CrossRef

48.

X. Yao, X. Kou, J. Qiu, M.G. Moloney, Generation mechanism of negative dielectric properties of metallic oxide crystals/PANI. Composites (2016). https://doi.org/10.1021/acs.jpcc.5b12352 CrossRef

49.

K.L. Bhowmik, K. Deb, A. Bera, R.K. Nath, B. Saha, Charge transport through polyaniline incorporated electrically conducting functional paper charge transport through polyaniline incorporated electrically conducting functional paper. J. Phys. Chem. C (2016). https://doi.org/10.1021/acs.jpcc.5b08650 CrossRef

50.

C. Dhand, M. Das, M. Datta, B.D. Malhotra, Biosensors and bioelectronics recent advances in polyaniline based biosensors. Biosens. Bioelectron. 26, 2811–2821 (2011). https://doi.org/10.1016/j.bios.2010.10.017 CrossRef

51.

C.M. De León-almazan, I.A. Estrada-moreno, U. Páramo-garcía, J.L. Rivera-armenta, Polyaniline/clay nanocomposites. a comparative approach on the doping acid and the clay spacing technique. Synth. Met. 236, 61–67 (2018). https://doi.org/10.1016/j.synthmet.2018.01.006 CrossRef

52.

M. Shi, Y. Zhang, M. Bai, B. Li, Facile fabrication of polyaniline with coral-like nanostructure as electrode material for supercapacitors. Synth. Met. 233, 74–78 (2017). https://doi.org/10.1016/j.synthmet.2017.09.007 CrossRef

53.

S.K. Simotwo, C. Delre, V. Kalra, Supercapacitor electrodes based on high-purity electrospun polyaniline and polyaniline-carbon nanotube nanofibers. ACS Appl. Mater. Interfaces. (2016). https://doi.org/10.1021/acsami.6b03463 CrossRef

54.

D. Xu, Q. Xu, K. Wang, J. Chen, Z. Chen, Fabrication of Free-Standing Hierarchical Carbon Nano fi ber/Graphene Oxide/Polyaniline Films for Supercapacitors. ACS Appl. Mater. Interfaces. 6, 200–209 (2014)CrossRef

55.

W. Fan, C. Zhang, W.W. Tjiu, K.P. Pramoda, C. He, T. Liu, Graphene-wrapped polyaniline hollow spheres as novel hybrid electrode materials for supercapacitor applications. ACS Appl. Mater. Interfaces (2013). https://doi.org/10.1021/am4003827 CrossRef

56.

A.K. Thakur, A.B. Deshmukh, R. Bilash, I. Karbhal, M. Majumder, M.V. Shelke, Facile synthesis and electrochemical evaluation of PANI/CNT/MoS 2 ternary composite as an electrode material for high performance supercapacitor. Mater. Sci. Eng. B 223, 24–34 (2017). https://doi.org/10.1016/j.mseb.2017.05.001 CrossRef

57.

J. Plawan Kumar, K. Santosh Singh, G. Suresh, K. Sreekumar, B. Nirmalya, Pb2 + —N bonding chemistry: recycling of polyaniline-pb nanocrystals waste for generating high-performance supercapacitor electrodes. J. Phys. Chem. C (2015). https://doi.org/10.1021/acs.jpcc.5b11217 CrossRef

58.

A. Sajedi-moghaddam, C.C. Mayorga-martinez, D. Bous, Black phosphorus nano flakes/polyaniline hybrid material for high-performance pseudocapacitors (2017). https://doi.org/10.1021/acs.jpcc.7b06958 CrossRef

59.

L. Mieko, D. Alves, D.L. Almeida, S.S. Oishi, A.B. Couto, Constituent material in fl uence on the electrochemical performance and supercapacitance of PANI/diamond/CF composite. Mater. Sci. Eng. B 228, 249–260 (2018). https://doi.org/10.1016/j.mseb.2017.12.004 CrossRef

Title: Effect of Mn2+ as a redox additive on ternary doped polyaniline-metal nanocomposite: an efficient dielectric material
Authors: C. Anju
Shiny Palatty
Publication date: 11-11-2019
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 24/2019
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-019-02484-6

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