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Journal of Materials Science: Materials in Electronics

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09-11-2019

Modified CdS quantum dots as selective turn-on fluorescent nanosensor for detection and determination of methamphetamine

Authors: Majid Masteri-Farahani, Nazanin Mosleh

Published in: Journal of Materials Science: Materials in Electronics | Issue 24/2019

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Abstract

Surface modification of cadmium sulfide quantum dots (CdS-QDs) with anti-methamphetamine (anti-METH) antibody produced a new turn-on fluorescent nanosensor, anti-METH-CdS-QDs, for detection of methamphetamine. The anti-METH-CdS-QDs nanosensor was obtained readily via the covalent conjugation of mercaptoacetic acid capped CdS-QDs with anti-METH in the presence of N-ethyl-N′-(3-dimethylaminopropyl carbodiimide) (EDC) and Sulfo-N-hydroxysuccinimide (Sulfo-NHS) as coupling agents. The results of FT-IR and energy dispersive X-ray (EDX) spectroscopies confirmed the functionalization of CdS-QDs with anti-METH species. X-ray diffraction (XRD) and transmission electron microscopy (TEM) analyses revealed the crystal phase and microstructure of CdS-QDs in the anti-METH-CdS-QDs. The obtained anti-METH-CdS-QDs exhibited fluorescence enhancement upon addition of methamphetamine molecules which allowed the highly sensitive and selective determination of methamphetamine with detection limit of 0.006 mg/L. Further studies disclosed that this nanosensor has little interaction with other drugs such as codeine and ibuprofen. Hence, it can be utilized as simple, inexpensive, and selective nanosensor for determination of methamphetamine in low concentrations.

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Title: Modified CdS quantum dots as selective turn-on fluorescent nanosensor for detection and determination of methamphetamine
Authors: Majid Masteri-Farahani
Nazanin Mosleh
Publication date: 09-11-2019
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 24/2019
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-019-02490-8

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