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Nanoparticles: Preparation, Stabilization, and Control Over Particle Size Read chapter Read first chapter

2021 | OriginalPaper | Chapter

5. Effect of Pressure on Thermo-oxidation and Thermocatalytic Oxidation of n-C7 Asphaltenes

Authors : Oscar E. Medina, Jaime Gallego, Farid B. Cortés, Camilo A. Franco

Published in: Nanoparticles: An Emerging Technology for Oil Production and Processing Applications

Publisher: Springer International Publishing

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Abstract

This study provides mechanistic insights into the effect of pressure on n-C7 asphaltene thermo-oxidation and thermocatalytic oxidation assisted by AuPd/Ce0.62Zr0.38O2 nanocatalysts as well as the thermodynamic compensation effect using pressures between 0.084 MPa and 7.0 MPa. This study is essentially divided into four parts, including (i) the impact of pressure on the oxidation of asphaltenes extracted from a single source; (ii) the effect of the chemical nature of asphaltenes on its thermo-oxidation at different pressures, using six different asphaltenes; (iii) the effect of different nanocatalysts in the decomposition of asphaltenes; and (iv) the thermodynamic compensation effect. Kinetic analysis was done based on high-pressure thermogravimetric results, conducted under an air atmosphere at temperatures from 100°C to 800°C. The temperature was divided into four main intervals, according to the mass change and rate for mass change profiles. The atypical behavior of asphaltenes limits each region during oxidation processes. The thermal events are named oxygen chemisorption region (OC), decomposition of chemisorbed oxygen region (DCO), first (FC), and second combustion (SC). Kinetic parameters were estimated through a first-order kinetic model for the different thermal regions. The results show the importance of the pressure on the oxidation of asphaltenes, according to the OC and DCO phenomena, in which there was no evidence at low-pressure conditions. Many variables influence the oxidation of asphaltenes. The content of thioethers, carboxyl and carbonyl groups, degree of aromatization, degree of dealkylation, cluster size, and content of long and short size aliphatic chains stand out. On the other hand, nanocatalysts’ presence considerably reduces the decomposition temperature of asphaltenes, obtaining values below 200°C, never before obtained. These reductions are possible in systems evaluated at 6.0 MPa and 3.0 MPa, indicating the beneficial effect of pressure on the performance and catalytic activity of the nanocatalyst. Finally, this work also shows insights about the kinetic compensation effect of the reactions throughout the conversion of asphaltenes with and without multifunctional nanocatalysts at different pressures.

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previous chapter Nanoparticles as Catalyst for Asphaltenes and Waste Heavy Hydrocarbons Upgrading
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Metadata
Title
Effect of Pressure on Thermo-oxidation and Thermocatalytic Oxidation of n-C7 Asphaltenes
Authors
Oscar E. Medina
Jaime Gallego
Farid B. Cortés
Camilo A. Franco
Copyright Year
2021
Book
Nanoparticles: An Emerging Technology for Oil Production and Processing Applications

Print ISBN: 978-3-319-12050-8

Electronic ISBN: 978-3-319-12051-5

Copyright Year: 2021

DOI
https://doi.org/10.1007/978-3-319-12051-5_5