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Journal of Materials Science: Materials in Electronics

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22-02-2017

Electrical and dielectric properties of polymer composite based on vanadium dioxide

Published in: Journal of Materials Science: Materials in Electronics | Issue 11/2017

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Abstract

Samples of a polymer composite based on polypropylene and vanadium dioxide VO₂ with the volume concentration from 0 to 1 were investigated. It was shown that the electrical conductivity of composites has the percolation-like character, and the current–voltage characteristics are S-shaped. In the temperature dependence of the electrical resistance of the composites samples, a sharp resistance decrease was detected at the temperature of the semiconductor–metal phase transition in VO₂, sufficient for use in critical thermistor elements. It was established that the variance of the dielectric permittivity in the range of frequencies 10⁵−10⁷ Hz can be interpreted as part of the Maxwell’s mechanism of migration polarization associated with the separation of free charge carriers in vanadium dioxide particles in the semiconducting state. It was shown that the dependence of the low-frequency dielectric permittivity on the volume concentration of the filler can be interpreted in terms of a statistical mixture model.

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Y. Cui, X. Wang, Y. Zhoua et al., Synthesis of vanadium dioxide thin films on conducting oxides and metal–insulator transition characteristics. J. Crystal Growth 338, 96–102 (2012). doi:10.1016/j.jcrysgro.2011.10.025 CrossRef

H. Kizuka, T. Yagi, J. Jia et al., Temperature dependence of thermal conductivity of VO₂ thin films across metal–insulator transition. Jap. J. Appl. Phys. 54(5), 053201 (2015). doi:10.7567/JJAP.54.053201 CrossRef

W. Bruckner, H. Opperman, W. Reihelt, J.I. Terukow, F.A. Tschudnowski, E. Wolf, Vanadiumoxide: Darstellung, Eigenschaften, Anwendung. (Akademie-Verlag, Berlin, 1983)

A.I. Ivon, V.R. Kolbunov, I.M. Chernenko, Stability of electrical properties of vanadium dioxide based ceramics. J. Eur. Ceram. Soc. 19, 1883–1888 (1999)CrossRef

J.M. Atkin, S. Berweger, E.K. Chavez, M.B. Raschke, Strain and temperature dependence of the insulating phases of VO₂ near the metal-insulator transition. Phys. Rev. B 85, 020101(R) (2012). doi:10.1103/PhysRevB.85.020101 CrossRef

С Alfred-Duplan, J. Musso, J.-R. Gavarri, C. Cesari, Variable electrical properties in composites: application to vanadium dioxide pigments in a polyethylene host. J. Sol. State Chem. 10(1), 6–14 (1994). doi:10.1006/jssc.1994.1127 CrossRef

M.K. Kerimov, M.A. Kurbanov, I.S. Sultanahmedova et al., Varistor effect in polymer-semiconductor composites. Semiconductors 44(7), 934–942 (2010). doi:10.1134/S1063782610070134 CrossRef

V.V. Turov, P.P. Gorbik, V.M. Ogenko et al., Influence of tetraethylammonium bromide on phase inhomogeneity of disperse vanadium dioxide particles in matrix of polyethylene glycol. App. Surf. Sci. 166, 492–496 (2000). doi:10.1016/S0169-4332(00)00481-5 CrossRef

Y.P. Mamunya, V.V. Davydenko, P. Pissis, E.V. Lebedev, Electrical and thermal conductivity of polymers filled with metal powders. Eur. Polymer. J. 38(9), 1887–1897 (2002). doi:10.1016/S0014-3057(02)00064-2 CrossRef

10.

J. Aneli, G. Zaikov, O Mukbaniani, Electric conductivity of polymer composites at mechanical relaxation. Chem. Chem. Technol. 5(2), 187–190 (2011)

11.

Y.Q. Tan, L.J. Fang, J.L. Xiao et al., Grafting of copolymers onto graphene by miniemulsion polymerization for conductive polymer composites: improved electrical conductivity and compatibility induced by interfacial distribution of grapheme. Polymer. Chem. 4(10), 2939–2944 (2013). doi:10.1039/C3PY00164D CrossRef

12.

H. Pang, L. Xu, D.X. Yan, Z.M. Li, Conductive polymer composites with segregated structures. Progress Polymer. Sci. 3(11), 1908–1933 (2014). doi:10.1016/j.progpolymsci.2014.07.007 CrossRef

13.

H.R. Seung, K. Seil, K. Han et al., Highly conductive polymer composites incorporated with electrochemically exfoliated graphene fillers. RSC Adv. 46(5), 36456–36460 (2015). doi:10.1039/C5RA04202J

14.

A.M. Hashimov, S.M. Hasanli, R.N. Mehdizadeh et al., Nonlinear resistor based on a polymer-ceramic composition. Tech. Phys. 52(8), 1086–1088 (2007). doi:10.1134/S1063784207080208 CrossRef

15.

AY Lyashkov, AS Tonkoshkur, Varistor composites with a positive temperature coefficient of resistance. Tech. Phys. 56(3), 427–428 (2011). doi:10.1134/S1063784211030121 CrossRef

16.

K.V. Antonova, V.R. Kolbunov, A.S. Tonkoshkur, Structure and properties of polymer composites based on vanadium dioxide. J. Polymer Res. 21(5), 1–5 (2014). doi:10.1007/s10965-014-0422-7 CrossRef

17.

A.I. Ivon, I.M. Chernenko, V.R. Kolbunov, Process for preparing of vanadium dioxide. Ukraine Patent 40041 A (UA) №99010384, 16 July 2001

18.

I.М. Afanasov, V.А. Morozov, A.V. Kepman et al., Preparation, electrical and thermal properties of new exfoliated graphite-based composites. Carbon 47(1), 263–270 (2009). doi:10.1016/j.carbon.2008.10.004 CrossRef

19.

C. Garzón, H. Palza, Electrical behavior of polypropylene composites melt mixed with carbon-based particles: Effect of the kind of particle and annealing process. Compos. Sci. Tech. 99, 117–123 (2014). doi:10.1016/j.compscitech.2014.05.018 CrossRef

20.

J. Frohlich, W. Niedermeier, H.D. Luginsland, The effect of filler–filler and filler–elastomer interaction on rubber reinforcement. Compos. Part A Appl. Sci. Manuf. 36(4), 449–460 (2005). doi:10.1016/j.compositesa.2004.10.004 CrossRef

21.

A. Montazeri, R. Naghdabadi, Investigation of the interphase effects on the mechanical behavior of carbon nanotube polymer composites by multiscale modeling. J. Appl. Polymer Sci. 117(1), 361–367 (2010). doi:10.1002/app.31460

22.

S. Kirkpatrick, Percolation and conduction. Rev. Mod. Phys. 45, 574–588 (1973). doi:10.1103/RevModPhys.45.574 CrossRef

23.

B.I. Shklovskii, A.L. Efros, Electronic Properties of Doped Semiconductors. (Springer-Verlag, Berlin, 1983)

24.

B. Brunson, Hopping conductivity and charge transport in low density polyethylene. Utah State University: all Graduate Theses and Dissertations. Paper 562, 2010

25.

A.S. Tonkoshkur, A.Y. Lyashkov, A.V. Degtyaryov, Size effects in electrical properties of carbon-polypropylene composites. Ukr. J. Phys. 61(11), 1108–1016 (2016)CrossRef

26.

C.N. Berglund, H.J. Guggenheim, Electronic properties of VO₂ near the semiconductor-metal transition. Phys. Rev. 185(3), 1022–1033 (1969). doi:10.1103/PhysRev.185.1022 CrossRef

27.

V.R. Kolbunov, A.I. Ivon, I.M. Chernenko, Conductivity of VO₂-based ceramics. J. Mater. Sci. 17, 57–62 (2006). doi:10.1007/s10854-005-5142-7

28.

S.S. Dukhin, V.N. Shilov, Dielectric Phenomena and the Double Layer in Disperse Systems and Polyelectrolytes, (Übersetzt aus dem Russischen von D. Ledermann; Herausgeber: P. Greenberg), J. (Wiley and Sons, New York, 1974)

29.

G. Bànhegyi, Numerical analysis of complex dielectric mixture formulae. Colloid Polymer Sci. 266(1), 11–28 (1988). doi:10.1007/BF01451527 CrossRef

30.

E.P. Moore, Polypropylene Handbook. Polymerization, Characterization, Properties, Processing, Applications. (Hanser Publishers, New York, 1996)

31.

S.-G. Shin, I.-K. Kwo, Effect of temperature on the dielectric properties of carbon black-filled polyethylene matrix composites below the percolation threshold. Electron. Mater. Lett. 7(3), 249–254 (2011). doi:10.1007/s13391-011-0913-1 CrossRef

32.

I.A. Morozov, A.L. Svistkov, G. Heinrich, B. Lauke, Structure of the carbon-black-particles framework in filled elastomer materials. Polymer Sci. Series A. 49(3), 292–299 (2007). doi:10.1134/S0965545X07030091 CrossRef

33.

A.V. Degtyar’ov, A.S. Tonkoshkur, Electric conductivity of PTCR polyethylene-graphite composites. Ukr. J. Phys. 52(9), 863–867 (2007)

Title: Electrical and dielectric properties of polymer composite based on vanadium dioxide
Publication date: 22-02-2017
Published in: Journal of Materials Science: Materials in Electronics / Issue 11/2017
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-017-6547-9

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