Skip to main content
Top
Published in: Cellulose 1/2008

01-02-2008

Extraction of cellulose and preparation of nanocellulose from sisal fibers

Authors: Juan I. Morán, Vera A. Alvarez, Viviana P. Cyras, Analia Vázquez

Published in: Cellulose | Issue 1/2008

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

In this work a study on the feasibility of extracting cellulose from sisal fiber, by means of two different procedures was carried out. These processes included usual chemical procedures such as acid hydrolysis, chlorination, alkaline extraction, and bleaching. The final products were characterized by means of Thermogravimetric Analysis (TGA), Infrared Spectroscopy (FTIR), X-Ray Diffraction (XRD), Differential Scanning Calorimetry (DSC) and Scanning Electronic Microscopy (SEM). The extraction procedures that were used led to purified cellulose. Advantages and disadvantages of both procedures were also analyzed. Finally, nanocellulose was produced by the acid hydrolysis of obtained cellulose and characterized by Atomic Force Microscopy (AFM).

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literature
go back to reference Alvarez VA, Vazquez A (2006) Influence of fiber chemical modification procedure on the mechanical properties and water absorption of MaterBi/Sisal fiber composites. Compos Part A: Appl S 37(10):1672–1680CrossRef Alvarez VA, Vazquez A (2006) Influence of fiber chemical modification procedure on the mechanical properties and water absorption of MaterBi/Sisal fiber composites. Compos Part A: Appl S 37(10):1672–1680CrossRef
go back to reference Baird MS, Hamlin JD, O’Sullivan, Whiting A (2006) An insight into the mechanism of the cellulose dyeing process: molecular modelling and simulations of cellulose and its interactions with water, urea, aromatic azo-dyes and aryl ammonium compounds. Dyes Pigments, (in Press), It was not actualized Baird MS, Hamlin JD, O’Sullivan, Whiting A (2006) An insight into the mechanism of the cellulose dyeing process: molecular modelling and simulations of cellulose and its interactions with water, urea, aromatic azo-dyes and aryl ammonium compounds. Dyes Pigments, (in Press), It was not actualized
go back to reference Bhatnagar A, Sain M (2005) Processing of cellulose nanofiber-reinforced composites. J Reinf Plast Comp 24(12):1259–1269CrossRef Bhatnagar A, Sain M (2005) Processing of cellulose nanofiber-reinforced composites. J Reinf Plast Comp 24(12):1259–1269CrossRef
go back to reference Benziman M, Haigler CH, Brown RMJ, White AR, Cooper KM (1980) Cellulose biogenesis: polymerization and crystallization are coupled processes in Acetobacter xylinum. National Academy of Science, USA, p 4 Benziman M, Haigler CH, Brown RMJ, White AR, Cooper KM (1980) Cellulose biogenesis: polymerization and crystallization are coupled processes in Acetobacter xylinum. National Academy of Science, USA, p 4
go back to reference Bledzki A-K, Gassan J (1999) Composites reinforced with cellulose based fibres. Prog Polym Sci 24:221–275CrossRef Bledzki A-K, Gassan J (1999) Composites reinforced with cellulose based fibres. Prog Polym Sci 24:221–275CrossRef
go back to reference Chattopadhyay H, Sarkar PB (1946) A New Method for the Estimation of Cellulose. Proc Natl Inst Sci India 12(1):23–46 Chattopadhyay H, Sarkar PB (1946) A New Method for the Estimation of Cellulose. Proc Natl Inst Sci India 12(1):23–46
go back to reference Cyras VP, Vallo C, Kenny JM, Vazquez A (2004) Effect of the chemical treatment on the mechanical properties of the PCL/starch and sisal fiber composites. J Compos Mater 38(16):512–520 Cyras VP, Vallo C, Kenny JM, Vazquez A (2004) Effect of the chemical treatment on the mechanical properties of the PCL/starch and sisal fiber composites. J Compos Mater 38(16):512–520
go back to reference Deraman M, Zakaria S, Murshidi JA (2001) Estimation of crystallinity and cryistallite size of cellulose in benzylated fibres of oil palm empty fruit bunches by X-Ray Diffraction. J Appl Phys 40:311–315 Deraman M, Zakaria S, Murshidi JA (2001) Estimation of crystallinity and cryistallite size of cellulose in benzylated fibres of oil palm empty fruit bunches by X-Ray Diffraction. J Appl Phys 40:311–315
go back to reference Doraiswammy I, Chellamani P (1993) Pineapple-leaf fibers. Text Progr 24(1):1–37CrossRef Doraiswammy I, Chellamani P (1993) Pineapple-leaf fibers. Text Progr 24(1):1–37CrossRef
go back to reference García-Jaldon G, Dupeyre D, Vignon MR (1998) Fibers from semi-retted hemp bundles by steam explosion treatment. Biomass Bioenerg 14:251–260CrossRef García-Jaldon G, Dupeyre D, Vignon MR (1998) Fibers from semi-retted hemp bundles by steam explosion treatment. Biomass Bioenerg 14:251–260CrossRef
go back to reference Goodger EM (1976) Hydrocarbon fuels, production, properties and performance of liquids and gases. Macmillan, London, p 120 Goodger EM (1976) Hydrocarbon fuels, production, properties and performance of liquids and gases. Macmillan, London, p 120
go back to reference Itoh T, Brown RMJ (1984) The assembly of cellulose microfibrils in Valonia macrophysa. Planta 160:372–381CrossRef Itoh T, Brown RMJ (1984) The assembly of cellulose microfibrils in Valonia macrophysa. Planta 160:372–381CrossRef
go back to reference Lojewska J, Miskowiec P, Lojewski T, Pronienwicz LM (2005) Cellulose oxidative and hydrolytic degradation: in situ FTIR approach. Polym Degrad Stab 88:512–520CrossRef Lojewska J, Miskowiec P, Lojewski T, Pronienwicz LM (2005) Cellulose oxidative and hydrolytic degradation: in situ FTIR approach. Polym Degrad Stab 88:512–520CrossRef
go back to reference Mwaikambo LY, Ansell MP (2002) Chemical modification of hemp, sisal, jute, and kapok fibers by alkalization. J Appl Polym Sci 84:2222–2234CrossRef Mwaikambo LY, Ansell MP (2002) Chemical modification of hemp, sisal, jute, and kapok fibers by alkalization. J Appl Polym Sci 84:2222–2234CrossRef
go back to reference Nelson ML, O’Connor RT (1964) Relation of certain infrared bands to cellulose crystallinity and crystal lattice type. Part II: a new infrared ratio for estimation of crystallinity in celluloses I and II. J Appl Polym Sci 8(3):1328–1341 Nelson ML, O’Connor RT (1964) Relation of certain infrared bands to cellulose crystallinity and crystal lattice type. Part II: a new infrared ratio for estimation of crystallinity in celluloses I and II. J Appl Polym Sci 8(3):1328–1341
go back to reference Oh SY, Yoo DI, Shin Y, Seo G (2005) FTIR analysis of cellulose treated with sodium hydroxide and carbon dioxide. Carbohyd Res 340:417–428CrossRef Oh SY, Yoo DI, Shin Y, Seo G (2005) FTIR analysis of cellulose treated with sodium hydroxide and carbon dioxide. Carbohyd Res 340:417–428CrossRef
go back to reference Reddy N, Yang Y (2005) Structure and properties of high quality natural cellulose fiber from cornstalks. Polymer 46(15):5494–5500CrossRef Reddy N, Yang Y (2005) Structure and properties of high quality natural cellulose fiber from cornstalks. Polymer 46(15):5494–5500CrossRef
go back to reference Rong MZ, Zhang MQ, Lui Y, Yang GC, Zeng HM (2001) The effect of fiber treatment on the mechanical properties of unidirectional sisal-reinforced epoxi composites. Compos Sci Technol 61:1437–1447CrossRef Rong MZ, Zhang MQ, Lui Y, Yang GC, Zeng HM (2001) The effect of fiber treatment on the mechanical properties of unidirectional sisal-reinforced epoxi composites. Compos Sci Technol 61:1437–1447CrossRef
go back to reference Rowell RM, Young RA, Rowell JK (eds) (1996) Paper and composites from agro-based resources. Lewis Publishers, Boca Raton, Florida Rowell RM, Young RA, Rowell JK (eds) (1996) Paper and composites from agro-based resources. Lewis Publishers, Boca Raton, Florida
go back to reference Samir M, Alloin F, Paillet M, Dufresne A (2004) Tangling effect in fibrillated cellulose reinforced nanocomposites. Macromolecules 37:4313–4316CrossRef Samir M, Alloin F, Paillet M, Dufresne A (2004) Tangling effect in fibrillated cellulose reinforced nanocomposites. Macromolecules 37:4313–4316CrossRef
go back to reference Sarkar PB, Mazumdar AK, Pal KB (1948) The hemicelluloses of jute fibre. J Tex Inst 39(T44):44–58 Sarkar PB, Mazumdar AK, Pal KB (1948) The hemicelluloses of jute fibre. J Tex Inst 39(T44):44–58
go back to reference Hon DNS (ed) (1996) Chemical modification of lignocellulosic materials. Marcel Dekker, Inc., New York Hon DNS (ed) (1996) Chemical modification of lignocellulosic materials. Marcel Dekker, Inc., New York
go back to reference Sun RC, Sun XF (2002) Fractional and structural characterization of hemicelluloses isolated by alkali and alkaline peroxide from barley straw. Carbohyd Polym 49:415–423CrossRef Sun RC, Sun XF (2002) Fractional and structural characterization of hemicelluloses isolated by alkali and alkaline peroxide from barley straw. Carbohyd Polym 49:415–423CrossRef
go back to reference Sun XF, Sun RC, Su Y, Sun JX (2004) Comparative study of crude and purified cellulose from wheat straw. J Agric Food Chem 52:839–847CrossRef Sun XF, Sun RC, Su Y, Sun JX (2004) Comparative study of crude and purified cellulose from wheat straw. J Agric Food Chem 52:839–847CrossRef
go back to reference Vignon MR, Heux L, Malainine ME, Mahrouz M (2004) Arabinan-cellulose composite in Opuntia ficus-indica prickly pear spines Carbohyd Res 339(1):123–131 Vignon MR, Heux L, Malainine ME, Mahrouz M (2004) Arabinan-cellulose composite in Opuntia ficus-indica prickly pear spines Carbohyd Res 339(1):123–131
go back to reference Yang H, Yan R, Chen H, Dong Ho L, Zheng C (2007) Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel, (in press) Yang H, Yan R, Chen H, Dong Ho L, Zheng C (2007) Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel, (in press)
Metadata
Title
Extraction of cellulose and preparation of nanocellulose from sisal fibers
Authors
Juan I. Morán
Vera A. Alvarez
Viviana P. Cyras
Analia Vázquez
Publication date
01-02-2008
Publisher
Springer Netherlands
Published in
Cellulose / Issue 1/2008
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-007-9145-9

Other articles of this Issue 1/2008

Cellulose 1/2008 Go to the issue