Skip to main content
Top
Published in: Cellulose 1/2008

01-02-2008

Splitting tendency of cellulosic fibers. Part 3: splitting tendency of viscose and modal fibers

Authors: Hale Bahar Öztürk, Thomas Bechtold

Published in: Cellulose | Issue 1/2008

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The splitting tendency of viscose and modal fibers in aqueous alkali solutions of LiOH, NaOH, KOH and TMAH was investigated. The viscose fibers splitted up to 5–7 fibrils, whereas modal fibers splitted up to 2–4 fibrils depending on alkali type and concentration. The fibrillar structure of lyocell enables it to split more (15–20 fibrils) than viscose and modal fibers. Splitting occurs where internal stress of fiber is high due to different alkali or void distribution inside fiber. The splitting test couldn’t be achieved for viscose and modal fibers between 1 and 5 M concentration of NaOH and TMAH solutions due to breakage of fibers during test. Above 5 M concentration, no split can be observed due to even distribution of alkali inside fiber.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Appendix
Available only for authorised users
Literature
go back to reference Abu-Rous M (2006a) Characterization of the wet-state pore structure of lyocell and other man-made cellulosic fibers by fluorescence and electron microscopy. PhD Thesis, Leopold-Franzens-University of Innsbruck Abu-Rous M (2006a) Characterization of the wet-state pore structure of lyocell and other man-made cellulosic fibers by fluorescence and electron microscopy. PhD Thesis, Leopold-Franzens-University of Innsbruck
go back to reference Abu-Rous M, Ingolic E, Schuster KC (2006b) Visualization of the fibrillar and pore morphology of cellulosic fibers applying transmission electron microscopy. Cellulose 13:411–419CrossRef Abu-Rous M, Ingolic E, Schuster KC (2006b) Visualization of the fibrillar and pore morphology of cellulosic fibers applying transmission electron microscopy. Cellulose 13:411–419CrossRef
go back to reference Armstrong RN, Varga JK, McCorsöey CC (1980) Spinnable solutions of cellulose dissolved in amine oxides. TAPPI Intl. Dissolving Pulp Conference Proceedings: 99–104 Armstrong RN, Varga JK, McCorsöey CC (1980) Spinnable solutions of cellulose dissolved in amine oxides. TAPPI Intl. Dissolving Pulp Conference Proceedings: 99–104
go back to reference Bredereck K, Gruber M, Otterbach A, Schulz F (1996) The hydrogel structure of cellulosic fibers with respect to fiber properties and textile finishing. Textilveredlung 31(9/10):194–200 Bredereck K, Gruber M, Otterbach A, Schulz F (1996) The hydrogel structure of cellulosic fibers with respect to fiber properties and textile finishing. Textilveredlung 31(9/10):194–200
go back to reference Bredereck K, Hermanutz F (2005) Man-made cellulosics. Rev Prog Color 35:59–72 Bredereck K, Hermanutz F (2005) Man-made cellulosics. Rev Prog Color 35:59–72
go back to reference Calistru E, Ciovica S (1968) Recent advances in the regenerated cellulose fiber industry. Celuloza Hirtie 17(4):137–141 Calistru E, Ciovica S (1968) Recent advances in the regenerated cellulose fiber industry. Celuloza Hirtie 17(4):137–141
go back to reference Colom X, Carillo F (2002) Crystallinity changes in lyocell and viscose-type fibers by caustric treatment. Eur Polym J 38(11):2225–2230CrossRef Colom X, Carillo F (2002) Crystallinity changes in lyocell and viscose-type fibers by caustric treatment. Eur Polym J 38(11):2225–2230CrossRef
go back to reference Cox NL (1950) US Patents 2, 535, 044; 2, 535, 045 and 2, 536, 014 Cox NL (1950) US Patents 2, 535, 044; 2, 535, 045 and 2, 536, 014
go back to reference Crawshaw J, Cameron RE (2000) A small angle X-ray scattering study of the pore structure in Tencel cellulose fibers and effects on physical treatments. Polymer 41:4691CrossRef Crawshaw J, Cameron RE (2000) A small angle X-ray scattering study of the pore structure in Tencel cellulose fibers and effects on physical treatments. Polymer 41:4691CrossRef
go back to reference Crawshaw J, Bras W, Mant GR, Cameron RE (2002) Simultaneous SAXS and WAXS investigations of changes in native cellulose fiber microstructure on swelling in aqueous sodium hydroxide. J Appl Polym Sci 83(6):1209–1218CrossRef Crawshaw J, Bras W, Mant GR, Cameron RE (2002) Simultaneous SAXS and WAXS investigations of changes in native cellulose fiber microstructure on swelling in aqueous sodium hydroxide. J Appl Polym Sci 83(6):1209–1218CrossRef
go back to reference Franks NE and Varga JK (1980) U.S. Patent 4, 196–282: April 1 Franks NE and Varga JK (1980) U.S. Patent 4, 196–282: April 1
go back to reference Götze K (1967) Chemiefasern nach dem Viskoseverfahren. Springer-Verlag. Berlin, p 354 Götze K (1967) Chemiefasern nach dem Viskoseverfahren. Springer-Verlag. Berlin, p 354
go back to reference Harms H (2002) Lenzing Lyocell: Potentiale einer neuen Fasergeneration. Lenzinger Berichte 81:27–34 Harms H (2002) Lenzing Lyocell: Potentiale einer neuen Fasergeneration. Lenzinger Berichte 81:27–34
go back to reference Harms H (2003/04) Chemiefasernaus natürlichen und synthetischen Polymeren. lecture presented at the University of Stuttgart. Germany Harms H (2003/04) Chemiefasernaus natürlichen und synthetischen Polymeren. lecture presented at the University of Stuttgart. Germany
go back to reference Jaturapiree A (2007) Porosity and transport properties in the system cellulose fiber/aqueous medium-determination and modification of porosity. PhD Thesis, Leopold-Franzens-University of Innsbruck, Austria Jaturapiree A (2007) Porosity and transport properties in the system cellulose fiber/aqueous medium-determination and modification of porosity. PhD Thesis, Leopold-Franzens-University of Innsbruck, Austria
go back to reference Klemm D, Philipp B, Heinze T, Heinze U, Wagenknecht W (1998) Comprehensive Cellulose Chemistry: Fundamentals and Analytical Methods, vol 2, Weinheim, VCH Verlag, Wiley Klemm D, Philipp B, Heinze T, Heinze U, Wagenknecht W (1998) Comprehensive Cellulose Chemistry: Fundamentals and Analytical Methods, vol 2, Weinheim, VCH Verlag, Wiley
go back to reference Krässig H, Schurz J, Steadmann RG, Schliefer K, Albrecht W (1986) Ullmann’s Encyclopedia of Industrial Chemistry, 5th edn, vol A6. VCH, Weinheim, p 375 Krässig H, Schurz J, Steadmann RG, Schliefer K, Albrecht W (1986) Ullmann’s Encyclopedia of Industrial Chemistry, 5th edn, vol A6. VCH, Weinheim, p 375
go back to reference Lenz J, Schurz J, Wrentschur E (1992) Comparative characterization of solvent spun cellulose and high wet modulus viscose fibers by their long periods. Acta Polymer 43:307–312CrossRef Lenz J, Schurz J, Wrentschur E (1992) Comparative characterization of solvent spun cellulose and high wet modulus viscose fibers by their long periods. Acta Polymer 43:307–312CrossRef
go back to reference Lenz J, Schurz J, Wrentschur E (1993) Properties and structure of solvent-spun and viscose-type fibers in the swollen state, Colloid Polym Sci 271:460–468CrossRef Lenz J, Schurz J, Wrentschur E (1993) Properties and structure of solvent-spun and viscose-type fibers in the swollen state, Colloid Polym Sci 271:460–468CrossRef
go back to reference Mortimer SA, Peguy AA (1996) The formation of structure in the spinning and coagulation of lyocell fibers. Cellulose Chem Technol 30:117–132 Mortimer SA, Peguy AA (1996) The formation of structure in the spinning and coagulation of lyocell fibers. Cellulose Chem Technol 30:117–132
go back to reference Morton WE, Hearle JWS (1997) Physical properties of textile fibers. Textile Institute, Manchester Morton WE, Hearle JWS (1997) Physical properties of textile fibers. Textile Institute, Manchester
go back to reference Moss CE, Butler MF, Müller M, Cameron RE (2002) Microfocus small-angle X-ray scattering investigation of the skin-core microstructure of lyocell cellulose fibers. J Appl Polym Sci 83(13):2799–2816CrossRef Moss CE, Butler MF, Müller M, Cameron RE (2002) Microfocus small-angle X-ray scattering investigation of the skin-core microstructure of lyocell cellulose fibers. J Appl Polym Sci 83(13):2799–2816CrossRef
go back to reference Nemec H (1994) Fibrillation of cellulosic materials-Can previous literature offer a solution? Lenzinger Berichte 9:69–72 Nemec H (1994) Fibrillation of cellulosic materials-Can previous literature offer a solution? Lenzinger Berichte 9:69–72
go back to reference Okubayashi S, Griesser UJ, Bechtold T (2005) Moisture sorption/desorption behaviour of various manmade cellulosic fibers. J Appl Polym Sci 97(4):1621–1625CrossRef Okubayashi S, Griesser UJ, Bechtold T (2005) Moisture sorption/desorption behaviour of various manmade cellulosic fibers. J Appl Polym Sci 97(4):1621–1625CrossRef
go back to reference Otterbach A (1998) Untersuchungen zur Hydrogelstruktur und Nassfibrillisationsneigung von Cellulosefasern vom Typ Lyocell, PhD Thesis, University of Stuttgart, Germany Otterbach A (1998) Untersuchungen zur Hydrogelstruktur und Nassfibrillisationsneigung von Cellulosefasern vom Typ Lyocell, PhD Thesis, University of Stuttgart, Germany
go back to reference Öztürk HB, Bechtold T (2005) Splitting tendency of cellulosic fibers. Lenzinger Berichte 84:123–130 Öztürk HB, Bechtold T (2005) Splitting tendency of cellulosic fibers. Lenzinger Berichte 84:123–130
go back to reference Öztürk HB, Okubayashi S, Bechtold T (2006a) Splitting tendency of cellulosic fibers, Part 1: the effect of shear force on mechanical stability of swollen lyocell fibers. Cellulose 13:393–402CrossRef Öztürk HB, Okubayashi S, Bechtold T (2006a) Splitting tendency of cellulosic fibers, Part 1: the effect of shear force on mechanical stability of swollen lyocell fibers. Cellulose 13:393–402CrossRef
go back to reference Öztürk HB, Okubayashi S, Bechtold T (2006b) Splitting tendency of cellulosic fibers. Part 2: effects of fiber swelling in alkali solutions. Cellulose 13:403–409CrossRef Öztürk HB, Okubayashi S, Bechtold T (2006b) Splitting tendency of cellulosic fibers. Part 2: effects of fiber swelling in alkali solutions. Cellulose 13:403–409CrossRef
go back to reference Schurz J (1994) What is new about new fibers of the lyocell type. Lenzinger Berichte 9:37–40 Schurz J (1994) What is new about new fibers of the lyocell type. Lenzinger Berichte 9:37–40
go back to reference Schuster KC, Aldred P, Villa M, Baron M, Loidl R, Biganska O, Patlazhan S, Navard P, Rüf H, Jericha E (2003) Characterising the emerging lyocell fibers structures by ultra small angle neutron scattering (USANS). Lenzinger Berichte 82:107 Schuster KC, Aldred P, Villa M, Baron M, Loidl R, Biganska O, Patlazhan S, Navard P, Rüf H, Jericha E (2003) Characterising the emerging lyocell fibers structures by ultra small angle neutron scattering (USANS). Lenzinger Berichte 82:107
go back to reference Sfiligoj-Smole M, Persin Z, Kreze T, Stana-Kleinschek K, Ribitsch V, Neumayer S (2003) X-ray study of pre-treated regenerated cellulose fibers, Mat Res Innovat 7:275–282CrossRef Sfiligoj-Smole M, Persin Z, Kreze T, Stana-Kleinschek K, Ribitsch V, Neumayer S (2003) X-ray study of pre-treated regenerated cellulose fibers, Mat Res Innovat 7:275–282CrossRef
go back to reference Warwicker JO (1966) Effect of reagents on the fine structure of cellulose Part III action of caustic soda on cotton and ramie. J Appl Polym Sci A-2 4:571–586CrossRef Warwicker JO (1966) Effect of reagents on the fine structure of cellulose Part III action of caustic soda on cotton and ramie. J Appl Polym Sci A-2 4:571–586CrossRef
go back to reference Warwicker JO (1967) Effect of chemical reagents on the fine structure of cellulose Part IV action of caustic soda on the fine structure of cotton and ramie. J Appl Polym Sci A-1 5:2579–2593CrossRef Warwicker JO (1967) Effect of chemical reagents on the fine structure of cellulose Part IV action of caustic soda on the fine structure of cotton and ramie. J Appl Polym Sci A-1 5:2579–2593CrossRef
go back to reference Warwicker JO (1969) Swelling cotton in alkalis and acids. J Appl Polym Sci 13:41–54CrossRef Warwicker JO (1969) Swelling cotton in alkalis and acids. J Appl Polym Sci 13:41–54CrossRef
go back to reference Warwicker JO, Clayton JW (1969) Reactivity of cotton after treatment in alkaline and acid swelling agents. J Appl Polym Sci 13:1037–1048CrossRef Warwicker JO, Clayton JW (1969) Reactivity of cotton after treatment in alkaline and acid swelling agents. J Appl Polym Sci 13:1037–1048CrossRef
go back to reference Zeronian SH, Cabradilla KE (1972) Action of alkali metal hydroxides on cotton. J Appl Polym Sci 16:113–128CrossRef Zeronian SH, Cabradilla KE (1972) Action of alkali metal hydroxides on cotton. J Appl Polym Sci 16:113–128CrossRef
go back to reference Zhang W, Okubayashi S, Bechtold T (2005) Fibrillation tendency of cellulosic fibers, Part 1: effects of swelling. Cellulose 12(3):267–273CrossRef Zhang W, Okubayashi S, Bechtold T (2005) Fibrillation tendency of cellulosic fibers, Part 1: effects of swelling. Cellulose 12(3):267–273CrossRef
Metadata
Title
Splitting tendency of cellulosic fibers. Part 3: splitting tendency of viscose and modal fibers
Authors
Hale Bahar Öztürk
Thomas Bechtold
Publication date
01-02-2008
Publisher
Springer Netherlands
Published in
Cellulose / Issue 1/2008
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-007-9149-5

Other articles of this Issue 1/2008

Cellulose 1/2008 Go to the issue