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Cellulose

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01-02-2008

Swelling and dissolution of cellulose, Part V: cellulose derivatives fibres in aqueous systems and ionic liquids

Authors: Céline Cuissinat, Patrick Navard, Thomas Heinze

Published in: Cellulose | Issue 1/2008

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Abstract

The swelling and dissolution mechanisms of several cellulose derivatives (nitrocellulose, cyanoethylcellulose and xanthate fibres) are studied in aqueous systems (N-methylmorpholine-N-oxide—water with various contents of water, hydroxide sodium—water) and in ionic liquids. The results are compared with the five modes describing the swelling and dissolution mechanisms of cotton and wood cellulose fibres. The mechanisms observed for the cellulose derivatives are similar to the ones of cotton and wood fibres. Swelling by ballooning is also seen with cellulose derivatives, showing that this phenomenon is linked to the fibre morphology, which can be kept after undergoing a heterogeneous derivatisation.

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Cuissinat C, Navard P (2006a) Swelling and dissolution of cellulose, Part I: free floating cotton and wood fibres in N-methylmorpholine N-oxide water mixtures. Macromol Symp 244(1):1–18CrossRef

Cuissinat C, Navard P (2006b) Swelling and dissolution of cellulose, Part II: free floating cotton and wood fibres in NaOH–water–additives systems. Macromol Symp 244(1):19–30CrossRef

Cuissinat C, Navard P (2007), Swelling and dissolution of cellulose, Part III: plant fibres in aqueous systems, Cellulose doi:10.1007/s10570-007-9158-4

Cuissinat C, Navard P, Heinze T (submitted) Swelling and dissolution of cellulose, Part IV: free floating cotton and wood fibres in ionic liquids, Carbohydrate Polymer

Jardeby K, Germgard U, Kreutz B, Heinze T, Heinze U, Lennholm H (2005) The influence of fibre wall thickness on the undissolved residuals in CMC solutions. Cellulose 12:167–175CrossRef

Klemm D, Philipp B, Heinze T, Heinze U, Wagenknecht W (1998) Fundamentals and analytical methods. Comprehensive cellulose chemistry, vol 1.Wiley—VCH, Weinheim, chapter 1

Title: Swelling and dissolution of cellulose, Part V: cellulose derivatives fibres in aqueous systems and ionic liquids
Authors: Céline Cuissinat
Patrick Navard
Thomas Heinze
Publication date: 01-02-2008
Publisher: Springer Netherlands
Published in: Cellulose / Issue 1/2008
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-007-9159-3

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