Skip to main content
Top
Published in: Microsystem Technologies 1/2019

18-05-2018 | Technical Paper

Fabrication and evaluation of a passive SU8-based micro direct glucose fuel cell

Authors: D. Dector, J. M. Olivares-Ramírez, V. M. Ovando-Medina, A. Sosa Dominguez, A. L. Villa, A. Duarte-Moller, N. Sabaté, J. P. Esquivel, A. Dector

Published in: Microsystem Technologies | Issue 1/2019

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

A passive micro direct glucose fuel cell (μDGFC) using SU8-current collector structures of 8 × 14 mm with a grid that allows the delivery of the reagents to the membrane-electrode assembly (MEA) by diffusion and with dimensions of ~ 200 × ~ 180 μm were fabricated by a UV-lithography technique. The SU8-current collectors were coated with Au to provide electric conductivity; a passive μDGFC was set by sandwiching an MEA between two SU8-current collectors and placed between two methacrylate pieces. The electrocatalysts consisted of commercial Au/C as anode and Pt/C as cathode. μDGFC characterization was done by measuring the polarization curves at a glucose concentration close to that found in human blood. The maximum power density achieved was ~ 0.30 mW cm−2 using 5 mM glucose as fuel and oxygen delivered from air as an oxidant. The passive micro fuel cell showed a constant current density for 30 min at a potential of 0.3 V corresponding to the maximum power density.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
go back to reference Campo AD, Greiner C (2007) SU-8: a photoresist for high-aspect-ratio and 3D submicron lithography. J Micromech Microeng 17:R81CrossRef Campo AD, Greiner C (2007) SU-8: a photoresist for high-aspect-ratio and 3D submicron lithography. J Micromech Microeng 17:R81CrossRef
go back to reference Cha H-Y, Choi H-G, Nam J-D, Lee Y, Cho SM, Lee E-S, Lee J-K, Chung C-H (2004) Fabrication of all-polymer micro-DMFCs using UV-sensitive photoresist. Electrochim Acta 50:795–799CrossRef Cha H-Y, Choi H-G, Nam J-D, Lee Y, Cho SM, Lee E-S, Lee J-K, Chung C-H (2004) Fabrication of all-polymer micro-DMFCs using UV-sensitive photoresist. Electrochim Acta 50:795–799CrossRef
go back to reference Dector A, Escalona-Villalpando RA, Dector D, Vallejo-Becerra V, Chavez-Ramírez AU, Arriaga LG, Ledesma-García J (2015) Perspective use of direct human blood as an energy source in air- breathing hybrid microfluidic fuel cells. J Power Sources 288:70–75CrossRef Dector A, Escalona-Villalpando RA, Dector D, Vallejo-Becerra V, Chavez-Ramírez AU, Arriaga LG, Ledesma-García J (2015) Perspective use of direct human blood as an energy source in air- breathing hybrid microfluidic fuel cells. J Power Sources 288:70–75CrossRef
go back to reference Dector A, Galindo-de-la-Rosa J, Amaya-Cruz DM, Ortíz-Verdín A, Guerra-Balcázar M, Olivares-Ramírez JM, Arriaga LG, Ledesma-García J (2017) Towards autonomous lateral flow assays: paper-based microfluidic fuel cell inside and HIV-test using a blood sample as fuel. Int J Hydrogen Energy 42:27979–27986CrossRef Dector A, Galindo-de-la-Rosa J, Amaya-Cruz DM, Ortíz-Verdín A, Guerra-Balcázar M, Olivares-Ramírez JM, Arriaga LG, Ledesma-García J (2017) Towards autonomous lateral flow assays: paper-based microfluidic fuel cell inside and HIV-test using a blood sample as fuel. Int J Hydrogen Energy 42:27979–27986CrossRef
go back to reference Dentinger PM, Krafcik KL, Simison KL, Janek RP, Hachman J (2002) High aspect ratio patterning with a proximity ultraviolet source. Microelectron Eng 61–62:1001–1007CrossRef Dentinger PM, Krafcik KL, Simison KL, Janek RP, Hachman J (2002) High aspect ratio patterning with a proximity ultraviolet source. Microelectron Eng 61–62:1001–1007CrossRef
go back to reference Dervisevic M, Dervisevic E, Senel M, Cevik E, Yildiz HB, Camurlu P (2017) Construction of ferrocene modified conducting polymer based amperometric urea biosensor. Enzyme Microb Technol 102:53–59CrossRef Dervisevic M, Dervisevic E, Senel M, Cevik E, Yildiz HB, Camurlu P (2017) Construction of ferrocene modified conducting polymer based amperometric urea biosensor. Enzyme Microb Technol 102:53–59CrossRef
go back to reference Esquivel JP, Senn T, Hernández-Fernández P, Santander J, Lörgen M, Rojas S, Löchel B, Cané C, Sabaté N (2010) Towards a compact SU-8 micro-direct methanol fuel cell. J Power Sources 195:8110–8115CrossRef Esquivel JP, Senn T, Hernández-Fernández P, Santander J, Lörgen M, Rojas S, Löchel B, Cané C, Sabaté N (2010) Towards a compact SU-8 micro-direct methanol fuel cell. J Power Sources 195:8110–8115CrossRef
go back to reference Esquivel JP, Del Campo FJ, Gómez de la Fuente JL, Rojas S, Sabaté N (2014) Microfluidic fuel cells on paper: meeting the power needs of next generation lateral flow devices. Energy Environ Sci 7:1744–1749CrossRef Esquivel JP, Del Campo FJ, Gómez de la Fuente JL, Rojas S, Sabaté N (2014) Microfluidic fuel cells on paper: meeting the power needs of next generation lateral flow devices. Energy Environ Sci 7:1744–1749CrossRef
go back to reference Fischer PB, Chou SY (1993) Sub-50 nm high aspect-ratio silicon pillars, ridges, and trenches fabricated using ultrahigh resolution electron beam lithography and reactive ion etching. Appl Phys Lett 62:2989–2991CrossRef Fischer PB, Chou SY (1993) Sub-50 nm high aspect-ratio silicon pillars, ridges, and trenches fabricated using ultrahigh resolution electron beam lithography and reactive ion etching. Appl Phys Lett 62:2989–2991CrossRef
go back to reference González-Guerrero MJ, Del Campo FJ, Leech D, Sabaté N (2017) Paper-based microfluidic biofuel cell operating under glucose concentrations within physiological range. Biosens Bioelectrons 90:475–480CrossRef González-Guerrero MJ, Del Campo FJ, Leech D, Sabaté N (2017) Paper-based microfluidic biofuel cell operating under glucose concentrations within physiological range. Biosens Bioelectrons 90:475–480CrossRef
go back to reference Hsieh S-S, Kuo J-K, Hwang C-F, Tsai H-H (2004) A novel design and microfabrication for a micro PEMFC. Microsyst Technol 10:121–126CrossRef Hsieh S-S, Kuo J-K, Hwang C-F, Tsai H-H (2004) A novel design and microfabrication for a micro PEMFC. Microsyst Technol 10:121–126CrossRef
go back to reference Hu W, Sarveswaran K, Lieberman M, Bernstein GH (2004) Sub-10 nm electron beam lithography using cold development of poly(methylmethacrylate). J Vac Sci Technol B 22:1711–1716CrossRef Hu W, Sarveswaran K, Lieberman M, Bernstein GH (2004) Sub-10 nm electron beam lithography using cold development of poly(methylmethacrylate). J Vac Sci Technol B 22:1711–1716CrossRef
go back to reference Jia W, Valdes-Ramirez G, Bandodkar AJ, Windmiller JR, Wang J (2013) Epidermal Biofuel Cells: energy harvesting from human perspiration. Angew Chem Int Ed 52:7233–7236CrossRef Jia W, Valdes-Ramirez G, Bandodkar AJ, Windmiller JR, Wang J (2013) Epidermal Biofuel Cells: energy harvesting from human perspiration. Angew Chem Int Ed 52:7233–7236CrossRef
go back to reference Ling Z, Lian K, Jian L (2000) Improved patterning quality of SU-8 microstructures by optimizing the exposure parameters. Proc SPIE 3999:1019–1027CrossRef Ling Z, Lian K, Jian L (2000) Improved patterning quality of SU-8 microstructures by optimizing the exposure parameters. Proc SPIE 3999:1019–1027CrossRef
go back to reference Liu G, Tian Y, Zhang X (2003) Fabrication of microchannels in negative resist. Microsyst Technol 9:461–464CrossRef Liu G, Tian Y, Zhang X (2003) Fabrication of microchannels in negative resist. Microsyst Technol 9:461–464CrossRef
go back to reference Liu G, Tian Y, Kan Y (2005) Fabrication of high-aspect-ratio microestructures using SU8 photoresist. Microsyst Technol 11:343–346CrossRef Liu G, Tian Y, Kan Y (2005) Fabrication of high-aspect-ratio microestructures using SU8 photoresist. Microsyst Technol 11:343–346CrossRef
go back to reference Pinyou P, Conzuelo F, Sliozberg K, Vivekananthan J, Contin A, Pöller S, Plumeré N, Schuhmann W (2015) Coupling of an enzymatic biofuel cell to an electrochemical cell for self-powered glucose sensing with optical readout. Bioelectrochem 106:22–27CrossRef Pinyou P, Conzuelo F, Sliozberg K, Vivekananthan J, Contin A, Pöller S, Plumeré N, Schuhmann W (2015) Coupling of an enzymatic biofuel cell to an electrochemical cell for self-powered glucose sensing with optical readout. Bioelectrochem 106:22–27CrossRef
go back to reference Stavrinidis G, Michelakis K, Kontomitrou V, Giannakakis G, Sevrisarianos M, Sevrisarianos G, Chaniotakis N, Alifragis Y, Konstantinidis G (2016) SU-8 microneedles based dry electrode for electroencephalogram. Microelectron Eng 159:114–120CrossRef Stavrinidis G, Michelakis K, Kontomitrou V, Giannakakis G, Sevrisarianos M, Sevrisarianos G, Chaniotakis N, Alifragis Y, Konstantinidis G (2016) SU-8 microneedles based dry electrode for electroencephalogram. Microelectron Eng 159:114–120CrossRef
go back to reference Torres N, Santander J, Esquivel JP, Sabaté N, Figueras E, Ivanov P, Fonseca L, Gràcia I, Cané C (2008) Performance optimization of a passive silicon-based micro-direct methanol fuel cell. Sens Actuators B 132:540–544CrossRef Torres N, Santander J, Esquivel JP, Sabaté N, Figueras E, Ivanov P, Fonseca L, Gràcia I, Cané C (2008) Performance optimization of a passive silicon-based micro-direct methanol fuel cell. Sens Actuators B 132:540–544CrossRef
go back to reference Verjulio RW, Santander J, Sabaté N, Esquivel JP, Torres-Herrero N, Habrioux A, Alonso-Vante N (2014) Fabrication and evaluation of a passive alkaline membrane micro direct methanol fuel cell. Int J Hydrogen Energy 39:5406–5413CrossRef Verjulio RW, Santander J, Sabaté N, Esquivel JP, Torres-Herrero N, Habrioux A, Alonso-Vante N (2014) Fabrication and evaluation of a passive alkaline membrane micro direct methanol fuel cell. Int J Hydrogen Energy 39:5406–5413CrossRef
go back to reference Wan J, Deng S-R, Yang R, Shu Z, Lu B-R, Xie S-Q, Chen Y, Huq E, Liu R, Qu X-P (2009) Silicon nanowire sensor for gas detection fabricated by nanoimprint on SU8/SiO2/PMMA trilayer. Microelectron Eng 86:1238–1242CrossRef Wan J, Deng S-R, Yang R, Shu Z, Lu B-R, Xie S-Q, Chen Y, Huq E, Liu R, Qu X-P (2009) Silicon nanowire sensor for gas detection fabricated by nanoimprint on SU8/SiO2/PMMA trilayer. Microelectron Eng 86:1238–1242CrossRef
go back to reference Wang X, Falk M, Ortiz R, Matsumura H, Bobacka J, Ludwig R, Bergelin M, Gorton L, Shleev S (2012) Mediatorless sugar/oxygen enzymatic fuel cells based on gold nanoparticle-modified electrodes. Biosens Bioelectron 31:219–225CrossRef Wang X, Falk M, Ortiz R, Matsumura H, Bobacka J, Ludwig R, Bergelin M, Gorton L, Shleev S (2012) Mediatorless sugar/oxygen enzymatic fuel cells based on gold nanoparticle-modified electrodes. Biosens Bioelectron 31:219–225CrossRef
go back to reference Weinmueller C, Tautschnig G, Hotz N, Poulikakos D (2010) A flexible direct methanol micro-fuel cell based on metalized, photosensitive polymer film. J Power Sources 195:3849–3857CrossRef Weinmueller C, Tautschnig G, Hotz N, Poulikakos D (2010) A flexible direct methanol micro-fuel cell based on metalized, photosensitive polymer film. J Power Sources 195:3849–3857CrossRef
go back to reference Williams JD, Wang W (2004) Study on the postbaking process and the effects on UV lithography of high aspect ratio SU-8 microstructures. J. Microlith Microfab Microsyst 3:563–568 Williams JD, Wang W (2004) Study on the postbaking process and the effects on UV lithography of high aspect ratio SU-8 microstructures. J. Microlith Microfab Microsyst 3:563–568
go back to reference Yang R, Wang W (2005) A numerical and experimental study on gap compensation and wavelength selection in UV-lithography of ultra-high aspect ratio SU-8 microstructures. Sensors Actuators B 110:279–288CrossRef Yang R, Wang W (2005) A numerical and experimental study on gap compensation and wavelength selection in UV-lithography of ultra-high aspect ratio SU-8 microstructures. Sensors Actuators B 110:279–288CrossRef
go back to reference Zhou M (2015) Recent progress on the development of biofuel cells for self-powered electrochemical biosensing and logical biosensing: a review. Electroanal 27:1786–1810CrossRef Zhou M (2015) Recent progress on the development of biofuel cells for self-powered electrochemical biosensing and logical biosensing: a review. Electroanal 27:1786–1810CrossRef
Metadata
Title
Fabrication and evaluation of a passive SU8-based micro direct glucose fuel cell
Authors
D. Dector
J. M. Olivares-Ramírez
V. M. Ovando-Medina
A. Sosa Dominguez
A. L. Villa
A. Duarte-Moller
N. Sabaté
J. P. Esquivel
A. Dector
Publication date
18-05-2018
Publisher
Springer Berlin Heidelberg
Published in
Microsystem Technologies / Issue 1/2019
Print ISSN: 0946-7076
Electronic ISSN: 1432-1858
DOI
https://doi.org/10.1007/s00542-018-3950-y

Other articles of this Issue 1/2019

Microsystem Technologies 1/2019 Go to the issue