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Colloid and Polymer Science
Published in: Colloid and Polymer Science 3/2020

24-01-2020 | Original Contribution

Fabrication of inverse core–shell and Janus-structured microspheres of blends of poly(4-butyltriphenylamine) and poly(methyl methacrylate)

Authors: Shu Kikuchi, Ryoka Shoji, Saki Yoshida, Shinji Kanehashi, Guang-Hui Ma, Kenji Ogino

Published in: Colloid and Polymer Science | Issue 3/2020

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Abstract

We here report the facile fabrication of inverse core–shell and Janus structured particles consisting of poly(4-butyltriphenylamine) (PBTPA) and poly(methyl methacrylate) (PMMA) via a solvent evaporation from solution droplets of a polymer blend dispersed in an aqueous phase. Janus structured composite particles in which the PBTPA domain was partially coated by the PMMA domain were obtained using poly(vinyl alcohol) (PVA) as a suspension stabilizer. On the other hand, when sodium dodecyl sulfate (SDS) was added as a surfactant together with PVA, “inverse core–shell” particles in which the PMMA core was covered by the PBTPA shell were formed as well as Janus particles. TEM observation showed that the PMMA core was located at the center of the sphere and PBTPA layer has uniform thickness in inverse core–shell particles. The increase of the composition of PBTPA or the concentration of SDS increased the ratio of the inverse core–shell particles to the Janus ones.
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Appendix
Available only for authorised users
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Metadata
Title
Fabrication of inverse core–shell and Janus-structured microspheres of blends of poly(4-butyltriphenylamine) and poly(methyl methacrylate)
Authors
Shu Kikuchi
Ryoka Shoji
Saki Yoshida
Shinji Kanehashi
Guang-Hui Ma
Kenji Ogino
Publication date
24-01-2020
Publisher
Springer Berlin Heidelberg
Published in
Colloid and Polymer Science / Issue 3/2020
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-020-04604-9

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