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Colloid and Polymer Science

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08-02-2020 | Original Contribution

Self-healing quadruple-shape memory hydrogel based on imine, coordination, and borate bonds with tunable mechanical properties

Authors: Minying Wang, Baohang Mo, Birong Chen, Linbin Jiang, Hua Yang

Published in: Colloid and Polymer Science | Issue 3/2020

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Abstract

PAM/OSA/PVA hydrogel was prepared by simple copolymerization using acrylamide (PAM), oxidized sodium alginate (OSA), and poly (vinyl alcohol) as monomers. The hydrogel exhibited a quadruple-shape memory effect based on imine, coordination, and borate bonds. Self-healing properties of the quadruple-shape memory hydrogel were observed to evolve due to the imine and borate bonds. The hydrogel demonstrated tunable mechanical properties because of supramolecular interactions including OSA –Ca²⁺, PVA –borax, and OSA –PAM in different conditions. The new hydrogel is envisaged to increase the variety as well as broaden the design and manufacturing of shape memory hydrogels.

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Title: Self-healing quadruple-shape memory hydrogel based on imine, coordination, and borate bonds with tunable mechanical properties
Authors: Minying Wang
Baohang Mo
Birong Chen
Linbin Jiang
Hua Yang
Publication date: 08-02-2020
Publisher: Springer Berlin Heidelberg
Published in: Colloid and Polymer Science / Issue 3/2020
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-020-04613-8

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