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Polymer Bulletin

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15-11-2018 | Original Paper

Functionalized polyethersulfone as PES-NH₂-metal oxide nanofilers for the detection of Y³⁺

Authors: Noof A. Alenazi, M. M. Alam, Mahmoud A. Hussein, Khalid A. Alamry, Abdullah M. Asiri, Mohammed M. Rahman

Published in: Polymer Bulletin | Issue 9/2019

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Abstract

The current study displays the synthesis, characterization as well as the performance of PES-NH₂ doped with different metal oxide nanomaterials. 5% w/w of ZnO, ZnCoFeO, Fe₂O₃, and Co₃O₄ nanofilers (NFs) were doped to the surface of PES-NH₂ to make PES-NH₂-ZnO, PES-NH₂-ZnCoFeO, PES-NH₂-Fe₂O₃-, PES-NH₂-Co₃O₄ NFs, respectively. Then, these metal oxides allowed to interact with amino functions, which were grafted on the PES backbone using two-step reactions: nitration followed by reduction. The results also showed a good thermal behavior for the doped metal oxides polymeric materials in comparison with bare PES-NH₂. The morphological structures of the PES-NH₂-metal oxide nanocomposites revealed the well-dispersed nanoparticles on the surface of PES-NH₂, in which the metal oxides nanoparticles appeared as bright small dots on the surface of polymer matrix. To execute this study, the working electrode of the proposed cation sensor was fabricated by deposition of Co₃O₄, ZnCoFeO, ZnO, and Fe₂O₃-PES-NH₂ NFs as layer of thin film coated onto a glassy carbon electrode supported with conducting binder. Based on the control experiment with PES-NH₂-ZnO, PES-NH₂-ZnCoFeO, PES-NH₂-Fe₂O₃, PES-NH₂-Co₃O₄ NFs, PES-NH₂-ZnCoFeO NFs exhibited the highest current response in the electrochemical measurement in the presence of selective analyte. A variety of Y³⁺ ionic concentrations (1.0 mM–0.1 nM) were applied as electrolyte through the assemble of Y³⁺ cationic sensor. To determine the calibration curve, the current versus the electrolyte concentration was plotted, which was found to be linear with about r² = 0.99 over the linear dynamic range (LDR) of 0.1 nM to 0.1 mM. The estimated sensitivity and detection limit are 1.1364 µAµM⁻¹ cm⁻² and 83.54 ± 4.18 pM, respectively. Therefore, the proposed Y³⁺ cation exhibited good sensitivity, wide LDR, lower limit of detection, and short time of response (10.0 s) with reproducibility with high precisions.

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Title: Functionalized polyethersulfone as PES-NH2-metal oxide nanofilers for the detection of Y3+
Authors: Noof A. Alenazi
M. M. Alam
Mahmoud A. Hussein
Khalid A. Alamry
Abdullah M. Asiri
Mohammed M. Rahman
Publication date: 15-11-2018
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 9/2019
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-018-2612-7

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