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28-04-2021 | Original Research

Highly-porous uniformly-sized amidoxime-functionalized cellulose beads prepared by microfluidics with N-methylmorpholine N-oxide

Authors: Seung-Yeop Baek, Soo-Young Park

Published in: Cellulose | Issue 9/2021

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Abstract

Uniformly-sized porous cellulose beads functionalized with amidoxime groups were prepared for the first time using a microfluidic method with N-methylmorpholine N-oxide (NMMO) monohydrate as a cellulose solvent. The molten state cellulose dope in NMMO monohydrate (cell/NMMO dope) as a disperse phase and hot mineral oil as a continuous phase were used in a T-junction microfluidic chip to produce uniformly-sized cell/NMMO droplets. Coagulation of the molten state cell/NMMO droplet at high temperature and amidoxime functionalization could prepare the highly-porous spherical amidoxime-functionalized cellulose beads with a uniform fibrous open internal structure. The prepared amidoxime-functionalized cellulose beads showed excellent metal adsorption properties with a maximum adsorption capacity of ~ 80 mg g⁻¹ in the case of Cu²⁺/phthalate ions. The newly developed highly-porous cellulose beads can open many new applications with other proper functionalization at the reactive hydroxyl groups of the cellulose.

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previous article Effect of the chemical and structural characteristics of pulps of Eucalyptus and Pinus on the deconstruction of the cell wall during the production of cellulose nanofibrils

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Title: Highly-porous uniformly-sized amidoxime-functionalized cellulose beads prepared by microfluidics with N-methylmorpholine N-oxide
Authors: Seung-Yeop Baek
Soo-Young Park
Publication date: 28-04-2021
Publisher: Springer Netherlands
Published in: Cellulose / Issue 9/2021
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-03872-0

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