Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Journal of Materials Science
Published in: Journal of Materials Science 12/2017

17-03-2017 | Original Paper

Hyperelastic behavior of modified sepiolite/SEBS thermoplastic elastomers

Authors: D. Perrin, R. Léger, B. Otazaghine, P. Ienny

Published in: Journal of Materials Science | Issue 12/2017

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Thin elastomer films of styrene–ethylene–butylene–styrene block copolymer (SEBS) filled with sepiolite nanofibers nanocomposites were prepared by a dip-coating process. To increase the SEBS/sepiolite elastomer performances, a new strategy of surface modification of sepiolite by SEBS polymer chains has been developed. In a first part, the surface modification of sepiolite was characterized by FTIR and TGA. In a second part, the mechanical properties of the filled SEBS films were assessed. Measurements of tensile properties and tear strength were carried to evaluate the impact of the sepiolite modification. These results are discussed in taking account the filler dispersion and the quality of the SEBS/sepiolite interface. The surface modification of the sepiolite nanofibers shows an interesting improvement of the tear strength without major modifications of SEBS matrix intrinsic hyperelastic behavior.
previous article Size-dependent hydration mechanism and kinetics for reactive MgO and Al2O3 powders with respect to the calcia-free hydraulic binder systems designed for refractory castables
next article Improved luminescence properties and thermal stability of SrSi2O2N2:Eu2+ phosphor with single phase via the formation of Eu3+ on surface structure

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
Matzeu G, Pucci A, Savi S, Romanelli M, Di Francesco F (2012) A temperature sensor based on a MWCNT/SEBS nanocomposite. Sens Actuators A 178:94–99CrossRef
2.
Juárez D, Ferrand S, Fenollar O, Fombuena V, Balart R (2011) Improvement of thermal inertia of styrene–ethylene/butylene–styrene (SEBS) polymers by addition of microencapsulated phase change materials (PCMs). Eur Polym J 47(2):153–161CrossRef
3.
Shi H, Shi D, Li C, Luan S, Yin J, Li RKY (2014) Preparation of functionalized graphene/SEBS-g-MAH nanocomposites and improvement of its electrical, mechanical properties. Mater Lett 133:200–203CrossRef
4.
Buckley CP, Prisacariu C, Martin C (2010) Elasticity and inelasticity of thermoplastic polyurethane elastomers: sensitivity to chemical and physical structure. Polymer 51:3213–3224CrossRef
5.
Dorfmann A, Ogden RW (2004) A pseudo–elastic model for the Mullins effect in filled rubber. Int J Solids Struct 41:1855–1878CrossRef
6.
Ogden RW, Roxburgh DG (1999) A pseudo–elastic model for the Mullins effect in filled rubber. Proc R Soc Lond A 455:2861–2877CrossRef
7.
Mullins L (1969) Softening of rubber by deformation. Rubber Chem Technol 42:339–362CrossRef
8.
Mullins L, Tobin N (1957) Theoretical model for the elastic behavior of filler-reinforced vulcanized rubbers. Rubber Chem Technol 30:51–571
9.
Chagnon G, Verron E, Marckmann G, Gornet L (2006) Development of new constitutive equations for the Mullins effect in rubber using the network alteration theory. Int J Solids Struct 43(22–23):6817–6831CrossRef
10.
Marckmann G, Verron E, Gornet L, Chagnon G, Charrier P, Fort P (2002) Comparison of hyperelastic models for rubber-like materials. J Mech Phys Solids 50:2011–2028CrossRef
11.
Jaudouin O, Robin JJ, Perrin D, Sonnier R, Ienny P, Léger R, Lopez-Cuesta JM (2012) Incorporation of organomodified layered silicates and silica in thermoplastic elastomers in order to improve tear strength. Mater Sci Forum 714:217–227CrossRef
12.
G’Sell C, Coupard A (1997) Génie mécanique des caoutchoucs et les élastomères thermoplastiques. In: Bouchereau MN (eds) Formulation des élastomères. Apollor, INPL, LRCCP, FIRTECH
13.
Aso O, Eguiazábal JI, Nazábal J (2007) The influence of surface modification on the structure and properties of a nanosilica filled thermoplastic elastomer. Compos Sci Technol 67(13):2854–2863CrossRef
14.
Finnigan B, Martin D, Halley P, Truss R, Campbell K (2004) Morphology and properties of thermoplastic polyurethane nanocomposites incorporating hydrophilic layered silicates. Polymer 45:2249–2260CrossRef
15.
Hassan PA, Verma G, Ganguly R (2012) 1—Soft materials—properties and applications. In: Functional materials, pp 1–59
16.
17.
Haraguchi K, Ebato M, Takehisa T (2006) Polymer-clay nanocomposites exhibiting abnormal necking phenomena accompanied by extremely large reversible elongations and excellent transparency. Adv Mater 18:2250–2254CrossRef
18.
Chen-Yang YW, Lee YK, Chen YT, Wu JC (2007) High improvement in the properties of exfoliated PU/clay nanocomposites by the alternative swelling process. Polymer 48:2969–2979CrossRef
19.
Polyurethane composition having improved tear strength and process for preparation thereof Patent, US Patent (1977), 4,062,825
20.
21.
22.
Zhenjung Z, Lina Z, Yang L (2005) Effect of the addition of toluene on the structure and properties of styrene–isoprene–butadiene rubber/montmorillonite nanocomposites. Macromol Mater Eng 290(5):430–437CrossRef
23.
Deng C, Lu X, Zhou SB, Wan JX, Qu SX, Feng B, Li XH, Cheng QY (2008) Mechanism of ultrahigh elongation rate of poly(d, l-lactide)-matrix composite biomaterial containing nano-apatite fillers. Mater Lett 62(4–5):607–610CrossRef
24.
Ma Z, Huang X, Jiang P (2010) A comparative study of effects of SEBS and EPDM on the water tree resistance of cross-linked polyethylene. Polym Degrad Stab 95(9):1943–1949CrossRef
25.
Wang X, Pang S-I, Yang J-H, Yang F (2006) Structure and properties of SEBS/PP/OMMT nanocomposites. Trans Nonferrous Met Soc China 16(2):524–528CrossRef
26.
Zhan M-Q, Yang K-K, Wang Y-Z (2015) Shape-memory poly(p-dioxanone)-poly(ɛ-caprolactone)/sepiolite nanocomposites with enhanced recovery stress. Chin Chem Lett 26:1221–1224CrossRef
27.
Flexible sheets for waterproofing—determination of resistance to tearing—Part 2: plastic and rubber sheets for roof waterproofing. NF EN 12310-2 February 2001
28.
Kuang W, Facey GA, Detellier C, Casal B, Serratosa JM, Ruiz-Hitzky E (2003) Nanostructured hybrid materials formed by sequestration of pyridine molecules in the tunnels of sepiolite. Chem Mater 15:4956–4967CrossRef
29.
Tartaglione G, Tabuani D, Camino G (2008) Thermal and morphological characterization of organically modified sepiolite. Microporous Mesoporous Mater 107:161–168CrossRef
30.
del Hoyo C, Dorado C, Rodríguez-Cruz MS, Sánchez-Martín MJ (2008) Physico-chemical study of selected surfactant-clay mineral systems. J Therm Anal Calorim 94(1):227–234CrossRef
31.
Benlikaya R, Alkan M, Kaya İ (2009) Preparation and characterization of sepiolite-poly (ethyl methacrylate) and poly (2-hydroxyethyl methacrylate) nanocomposites. Polym Compos 30:1585–1594CrossRef
32.
Roya N, Bhowmick AK (2010) Novel in situ polydimethylsiloxane-sepiolite nanocomposites: structure-property relationship. Polymer 51(22):5172–5185CrossRef
33.
Maiti M, Bhowmick AK (2006) Structure and properties of some novel fluoroelastomer/clay nanocomposites with special reference to their interaction. J Polym Sci B Polym Phys 44(1):162–176CrossRef
Metadata
Title
Hyperelastic behavior of modified sepiolite/SEBS thermoplastic elastomers
Authors
D. Perrin
R. Léger
B. Otazaghine
P. Ienny
Publication date
17-03-2017
Publisher
Springer US
Published in
Journal of Materials Science / Issue 12/2017
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-0991-z

Other articles of this Issue 12/2017

Journal of Materials Science 12/2017 Go to the issue

Book Review

Kannan M. Krishnan: Fundamentals and Applications of Magnetic Materials 1st Edition

Original Paper

Toward an understanding of the effect of surface roughness on instrumented indentation results

Original Paper

n- and p-type dopants in the InSe monolayer via substitutional doping

Original Paper

High-temperature reaction of amorphous silicon with carbon on a multiwall carbon nanotube heater and temperature measurement by thermal radiation spectra

Original Paper

Vacancy-mediated ferromagnetism in Co-implanted ZnO studied using a slow positron beam

Original Paper

Metal-rich aluminum–polytetrafluoroethylene reactive composite powders prepared by mechanical milling at different temperatures

Premium Partners

    Image Credits