Skip to main content
Top
Published in: Optical and Quantum Electronics 2/2021

01-02-2021

Investigation of thermal annealing effects on MoO3 thin film by atomic layer deposition

Author: Mustafa Demirtaş

Published in: Optical and Quantum Electronics | Issue 2/2021

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Molybdenum oxide (MoO3) thin films have been obtained by plasma-enhanced atomic layer deposition using precursors of Mo(CO)6 and O2 plasma at a reactor temperature of 160 °C. The MoO3 thin films deposited on p-type silicon substrates with thermally grown 300 nm thick SiO2 layer with different numbers of ALD growth cycles. Spectroscopic ellipsometer is used to characterize as-grown film thickness and refractive index. The as-grown films are treated at annealing temperatures at 300–600 °C. The structural properties of as-grown and annealed thin films have been characterized by optical microscopy, µRaman spectra, and atomic force microscopy.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literature
go back to reference Al-Kuhaili, M.F., Durrani, S.M.A., Bakhtiari, I.A.: Pulsed laser deposition of molybdenum oxide thin films. Appl. Phys. A Mater. Sci. Process 98, 609–615 (2010)ADSCrossRef Al-Kuhaili, M.F., Durrani, S.M.A., Bakhtiari, I.A.: Pulsed laser deposition of molybdenum oxide thin films. Appl. Phys. A Mater. Sci. Process 98, 609–615 (2010)ADSCrossRef
go back to reference Alsaif, M., Field, M.R., Murdoch, B.J., et al.: Substoichiometric two-dimensional molybdenum oxide flakes: a plasmonic gas sensing platform. Nanoscale 6, 12780–12791 (2014)ADSCrossRef Alsaif, M., Field, M.R., Murdoch, B.J., et al.: Substoichiometric two-dimensional molybdenum oxide flakes: a plasmonic gas sensing platform. Nanoscale 6, 12780–12791 (2014)ADSCrossRef
go back to reference Bertuch, A., Sundaram, G., Saly, M., et al.: Atomic layer deposition of molybdenum oxide using bis(tert-butylimido)bis(dimethylamido) molybdenum. J. Vac. Sci. Technol. A 32, 1–6 (2014)CrossRef Bertuch, A., Sundaram, G., Saly, M., et al.: Atomic layer deposition of molybdenum oxide using bis(tert-butylimido)bis(dimethylamido) molybdenum. J. Vac. Sci. Technol. A 32, 1–6 (2014)CrossRef
go back to reference Bullock, J., Cuevas, A., Allen, T., et al.: Molybdenum oxide MoOx: a versatile hole contact for silicon solar cells. Appl. Phys. Lett. 105, 1–5 (2014)CrossRef Bullock, J., Cuevas, A., Allen, T., et al.: Molybdenum oxide MoOx: a versatile hole contact for silicon solar cells. Appl. Phys. Lett. 105, 1–5 (2014)CrossRef
go back to reference Campanella, L., Pistoia, G.: MoO3: a new electrode material for nonaqueous secondary battery applications. J. Electrochem. Soc. 118, 1905–1908 (1971)ADSCrossRef Campanella, L., Pistoia, G.: MoO3: a new electrode material for nonaqueous secondary battery applications. J. Electrochem. Soc. 118, 1905–1908 (1971)ADSCrossRef
go back to reference Dayal, S., Kumar, C.S.: Development of hierarchical layered nanostructured α-MoO3 thin films using dc magnetron sputtering. Mater. Res. Exp. 3, 106405 (2016) Dayal, S., Kumar, C.S.: Development of hierarchical layered nanostructured α-MoO3 thin films using dc magnetron sputtering. Mater. Res. Exp. 3, 106405 (2016)
go back to reference Demirtas, M., Odaci, C., Shehu, Y., et al.: ALD Assisted 2D Monolayer Transition Metal Dichalcogenides and Their Applications in Optoelectronics, pp. 3034–3037. PhotonIcs & Electromagnetics Research Symposium, Rome (2019) Demirtas, M., Odaci, C., Shehu, Y., et al.: ALD Assisted 2D Monolayer Transition Metal Dichalcogenides and Their Applications in Optoelectronics, pp. 3034–3037. PhotonIcs & Electromagnetics Research Symposium, Rome (2019)
go back to reference Demirtas, M., Odaci, C., Shehu, Y., et al.: Layer and size distribution control of CVD-grown 2D MoS2 using ALD-deposited MoO3 structures as the precursor. Mater. Sci. Semicond. Process 108, 1–8 (2020)CrossRef Demirtas, M., Odaci, C., Shehu, Y., et al.: Layer and size distribution control of CVD-grown 2D MoS2 using ALD-deposited MoO3 structures as the precursor. Mater. Sci. Semicond. Process 108, 1–8 (2020)CrossRef
go back to reference Di Giulio, M., Manno, D., Micocci, G., et al.: Physical properties of molybdenum oxide thin films for NO gas detection. Phys. Status Sol. A Appl. Res. 168, 249–256 (1998)ADSCrossRef Di Giulio, M., Manno, D., Micocci, G., et al.: Physical properties of molybdenum oxide thin films for NO gas detection. Phys. Status Sol. A Appl. Res. 168, 249–256 (1998)ADSCrossRef
go back to reference Dieterle, M., Weinberg, G., Mestl, G.: Raman spectroscopy of molybdenum oxides Part I. Structural characterization of oxygen defects in MoO 3–x by DR UV/VIS, Raman spectroscopy and X-ray diffraction. Phys. Chem. Chem. Phys. 4, 812–821 (2002)CrossRef Dieterle, M., Weinberg, G., Mestl, G.: Raman spectroscopy of molybdenum oxides Part I. Structural characterization of oxygen defects in MoO 3–x by DR UV/VIS, Raman spectroscopy and X-ray diffraction. Phys. Chem. Chem. Phys. 4, 812–821 (2002)CrossRef
go back to reference Diskus, M., Nilsen, O., Fjellvag, H.: Growth of thin films of molybdenum oxide by atomic layer deposition. J. Mater. Chem. 21, 705–710 (2011)CrossRef Diskus, M., Nilsen, O., Fjellvag, H.: Growth of thin films of molybdenum oxide by atomic layer deposition. J. Mater. Chem. 21, 705–710 (2011)CrossRef
go back to reference Eda, K.: Longitudinal-transverse splitting effects in IR absorption spectra of MoO3. J. Solid State Chem. 95, 64–73 (1991)ADSCrossRef Eda, K.: Longitudinal-transverse splitting effects in IR absorption spectra of MoO3. J. Solid State Chem. 95, 64–73 (1991)ADSCrossRef
go back to reference Elumalai, N.K., Saha, A., Vijila, C., et al.: Enhancing the stability of polymer solar cells by improving the conductivity of the nanostructured MoO3 hole-transport layer. Phys. Chem. Chem. Phys. 15, 6831–6841 (2013)CrossRef Elumalai, N.K., Saha, A., Vijila, C., et al.: Enhancing the stability of polymer solar cells by improving the conductivity of the nanostructured MoO3 hole-transport layer. Phys. Chem. Chem. Phys. 15, 6831–6841 (2013)CrossRef
go back to reference Fang, Z., Yan, Z., Tan, Y., et al.: Influence of post-annealing treatment on the structure properties of ZnO films. Appl. Surf. Sci. 241, 303–308 (2005)ADSCrossRef Fang, Z., Yan, Z., Tan, Y., et al.: Influence of post-annealing treatment on the structure properties of ZnO films. Appl. Surf. Sci. 241, 303–308 (2005)ADSCrossRef
go back to reference Ferroni, M., Guidi, V., Martinelli, G., et al.: MoO3-based sputtered thin films for fast NO2 detection. Sens. Actuators B Chem. 48, 285–288 (1998)CrossRef Ferroni, M., Guidi, V., Martinelli, G., et al.: MoO3-based sputtered thin films for fast NO2 detection. Sens. Actuators B Chem. 48, 285–288 (1998)CrossRef
go back to reference Girotto, C., Voroshazi, E., Cheyns, D., et al.: Solution-processed MoO3 thin films as a hole-injection layer for organic solar cells. ACS Appl. Mater. Interfaces 3, 3244–3247 (2011)CrossRef Girotto, C., Voroshazi, E., Cheyns, D., et al.: Solution-processed MoO3 thin films as a hole-injection layer for organic solar cells. ACS Appl. Mater. Interfaces 3, 3244–3247 (2011)CrossRef
go back to reference Guerfi, A., Paynter, R.W., Dao, L.H.: Characterization and stability of electrochromic MoO3 thin-films prepared by electrodeposition. J. Electrochem. Soc. 142, 3457–3464 (1995)ADSCrossRef Guerfi, A., Paynter, R.W., Dao, L.H.: Characterization and stability of electrochromic MoO3 thin-films prepared by electrodeposition. J. Electrochem. Soc. 142, 3457–3464 (1995)ADSCrossRef
go back to reference Guo, T., Yao, M.S., Lin, Y.H., et al.: A comprehensive review on synthesis methods for transition-metal oxide nanostructures. CrystEngComm 17, 3551–3585 (2015)CrossRef Guo, T., Yao, M.S., Lin, Y.H., et al.: A comprehensive review on synthesis methods for transition-metal oxide nanostructures. CrystEngComm 17, 3551–3585 (2015)CrossRef
go back to reference He, T., Yao, J.N.: Photochromism of molybdenum oxide. J. Photochem. Photobiol. C Photochem. Rev. 4, 125–143 (2003)CrossRef He, T., Yao, J.N.: Photochromism of molybdenum oxide. J. Photochem. Photobiol. C Photochem. Rev. 4, 125–143 (2003)CrossRef
go back to reference Hogabri, A., Hajakbari, F.: Structural and optical properties of nanocrystalline α-MoO3 thin films prepared at different annealing. J. Theor. Appl. Phys. 9, 67–73 (2015)ADSCrossRef Hogabri, A., Hajakbari, F.: Structural and optical properties of nanocrystalline α-MoO3 thin films prepared at different annealing. J. Theor. Appl. Phys. 9, 67–73 (2015)ADSCrossRef
go back to reference Hu, H., Deng, C., Xu, J., et al.: Metastable h-MoO3 and stable α-MoO3 microstructures: controllable synthesis, growth mechanism and their enhanced photocatalytic activity. J. Exp. Nanosci. 10, 1336–1346 (2015)CrossRef Hu, H., Deng, C., Xu, J., et al.: Metastable h-MoO3 and stable α-MoO3 microstructures: controllable synthesis, growth mechanism and their enhanced photocatalytic activity. J. Exp. Nanosci. 10, 1336–1346 (2015)CrossRef
go back to reference Ivanova, T., Gesheva, K.A., Popkirov, G., et al.: Electrochromic properties of atmospheric CVD MoO3 and MoO3-WO3 films and their application in electrochromic devices. Mater. Sci. Eng. B Sol. State Mater. Adv. Technol. 119, 232–239 (2005)CrossRef Ivanova, T., Gesheva, K.A., Popkirov, G., et al.: Electrochromic properties of atmospheric CVD MoO3 and MoO3-WO3 films and their application in electrochromic devices. Mater. Sci. Eng. B Sol. State Mater. Adv. Technol. 119, 232–239 (2005)CrossRef
go back to reference Khandare, L., Late, D.J.: MoO3-rGO nanocomposites for electrochemical energy storage. Appl. Surf. Sci. 418, 2–8 (2017)ADSCrossRef Khandare, L., Late, D.J.: MoO3-rGO nanocomposites for electrochemical energy storage. Appl. Surf. Sci. 418, 2–8 (2017)ADSCrossRef
go back to reference Koike, K., Wada, R., Yagi, S., et al.: Characteristics of MoO3 films grown by molecular beam epitaxy. Jpn. J. Appl. Phys. 53, 1–4 (2014)CrossRef Koike, K., Wada, R., Yagi, S., et al.: Characteristics of MoO3 films grown by molecular beam epitaxy. Jpn. J. Appl. Phys. 53, 1–4 (2014)CrossRef
go back to reference Kumar, B.R., Rao, T.S.: AFM Studies on surface morphology, topography and texture of nanostructured zinc aluminum oxide thin films. Dig. J. Nanomater. Biostruct. 7, 1881–1889 (2012) Kumar, B.R., Rao, T.S.: AFM Studies on surface morphology, topography and texture of nanostructured zinc aluminum oxide thin films. Dig. J. Nanomater. Biostruct. 7, 1881–1889 (2012)
go back to reference Lee, S.H., Kim, Y.H., Deshpande, R., et al.: Reversible lithium-ion insertion in molybdenum oxide nanoparticles. Adv. Mater. 20, 3627–3632 (2008)CrossRef Lee, S.H., Kim, Y.H., Deshpande, R., et al.: Reversible lithium-ion insertion in molybdenum oxide nanoparticles. Adv. Mater. 20, 3627–3632 (2008)CrossRef
go back to reference Lin, Y., Xie, J., Wang, H., et al.: Green luminescent zinc oxide films prepared by polymer-assisted deposition with rapid thermal process. Thin Sol. Films 492, 101–104 (2005)ADSCrossRef Lin, Y., Xie, J., Wang, H., et al.: Green luminescent zinc oxide films prepared by polymer-assisted deposition with rapid thermal process. Thin Sol. Films 492, 101–104 (2005)ADSCrossRef
go back to reference Liu, D., Lei, W., Hao, J., et al.: High-pressure Raman scattering and x-ray diffraction of phase transitions in MoO 3. J. Appl. Phys. 105, 023513 (2009) Liu, D., Lei, W., Hao, J., et al.: High-pressure Raman scattering and x-ray diffraction of phase transitions in MoO 3. J. Appl. Phys. 105, 023513 (2009)
go back to reference Lucovsky, G., Tsu, D.V.: Differences between direct and remote plasma enhanced CVD. J. Non Cryst. Sol. 97–8, 265–268 (1987)ADSCrossRef Lucovsky, G., Tsu, D.V.: Differences between direct and remote plasma enhanced CVD. J. Non Cryst. Sol. 97–8, 265–268 (1987)ADSCrossRef
go back to reference Macco, B., Vos, M.F.J., Thissen, N.F.W., et al.: Low-temperature atomic layer deposition of MoOx for silicon heterojunction solar cells. Phys. Status Sol. Rapid Res. Lett. 9, 393–396 (2015)ADSCrossRef Macco, B., Vos, M.F.J., Thissen, N.F.W., et al.: Low-temperature atomic layer deposition of MoOx for silicon heterojunction solar cells. Phys. Status Sol. Rapid Res. Lett. 9, 393–396 (2015)ADSCrossRef
go back to reference Mahajan, S.S., Mujawar, S.H., Shinde, P.S., et al.: Concentration dependent structural, optical and electrochromic properties of MoO3 thin films. Int. J. Electrochem. Sci. 3, 953–960 (2008) Mahajan, S.S., Mujawar, S.H., Shinde, P.S., et al.: Concentration dependent structural, optical and electrochromic properties of MoO3 thin films. Int. J. Electrochem. Sci. 3, 953–960 (2008)
go back to reference Mattinen, M., King, P.J., Khriachtchev, L., et al.: Atomic layer deposition of crystalline molybdenum oxide thin films and phase control by post-deposition annealing. Mater. Today Chem. 9, 17–27 (2018)CrossRef Mattinen, M., King, P.J., Khriachtchev, L., et al.: Atomic layer deposition of crystalline molybdenum oxide thin films and phase control by post-deposition annealing. Mater. Today Chem. 9, 17–27 (2018)CrossRef
go back to reference Meyer, J., Hamwi, S., Kroger, M., et al.: Transition metal oxides for organic electronics: energetics. Device Phys. Appl. Adv. Mater. 24, 5408–5427 (2012) Meyer, J., Hamwi, S., Kroger, M., et al.: Transition metal oxides for organic electronics: energetics. Device Phys. Appl. Adv. Mater. 24, 5408–5427 (2012)
go back to reference Nanayakkara, C.E., Vega, A., Liu, G., et al.: Role of initial precursor chemisorption on incubation delay for molybdenum oxide atomic layer deposition. Chem. Mater. 28, 8591–8597 (2016)CrossRef Nanayakkara, C.E., Vega, A., Liu, G., et al.: Role of initial precursor chemisorption on incubation delay for molybdenum oxide atomic layer deposition. Chem. Mater. 28, 8591–8597 (2016)CrossRef
go back to reference Naresh, P., Raju, G.N., Reddy, M.S., et al.: Dielectric and spectroscopic features of ZnO-ZnF2-B2O3:MoO3 glass ceramic-a possible material for plasma display panels. J. Mater. Sci. Mater. Electron. 25, 4902–4915 (2014)CrossRef Naresh, P., Raju, G.N., Reddy, M.S., et al.: Dielectric and spectroscopic features of ZnO-ZnF2-B2O3:MoO3 glass ceramic-a possible material for plasma display panels. J. Mater. Sci. Mater. Electron. 25, 4902–4915 (2014)CrossRef
go back to reference Rahmani, M.B., Keshmiri, S.H., Yu, J., et al.: Gas sensing properties of thermally evaporated lamellar MoO3. Sens. Actuators B Chem. 145, 13–19 (2010)CrossRef Rahmani, M.B., Keshmiri, S.H., Yu, J., et al.: Gas sensing properties of thermally evaporated lamellar MoO3. Sens. Actuators B Chem. 145, 13–19 (2010)CrossRef
go back to reference Sanehira, E.M., de Villers, B.J.T., Schulz, P., et al.: Influence of electrode interfaces on the stability of perovskite solar cells: reduced degradation using MoOx/Al for hole collection. ACS Energy Lett. 1, 38–45 (2016)CrossRef Sanehira, E.M., de Villers, B.J.T., Schulz, P., et al.: Influence of electrode interfaces on the stability of perovskite solar cells: reduced degradation using MoOx/Al for hole collection. ACS Energy Lett. 1, 38–45 (2016)CrossRef
go back to reference Seguin, L., Figlarz, M., Cavagnat, R., et al.: Infrared and Raman spectra of MoO3 molybdenum trioxides and MoO3·xH2O molybdenum trioxide hydrates. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 51, 1323–1344 (1995)ADSCrossRef Seguin, L., Figlarz, M., Cavagnat, R., et al.: Infrared and Raman spectra of MoO3 molybdenum trioxides and MoO3·xH2O molybdenum trioxide hydrates. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 51, 1323–1344 (1995)ADSCrossRef
go back to reference Shakir, I., Shahid, M., Yang, H.W., et al.: Structural and electrochemical characterization of alpha-MoO3 nanorod-based electrochemical energy storage devices. Electrochim. Acta 56, 376–380 (2010)CrossRef Shakir, I., Shahid, M., Yang, H.W., et al.: Structural and electrochemical characterization of alpha-MoO3 nanorod-based electrochemical energy storage devices. Electrochim. Acta 56, 376–380 (2010)CrossRef
go back to reference Sivakumar, R., Vijayan, V., Ganesan, V., et al.: Electron beam evaporated molybdenum oxide films: a study of elemental and surface morphological properties. Smart Mater. Struct. 14, 1204–1209 (2005)ADSCrossRef Sivakumar, R., Vijayan, V., Ganesan, V., et al.: Electron beam evaporated molybdenum oxide films: a study of elemental and surface morphological properties. Smart Mater. Struct. 14, 1204–1209 (2005)ADSCrossRef
go back to reference Vos, M.F.J., Macco, B., Thissen, N.F.W., et al.: Atomic layer deposition of molybdenum oxide from ((NBu)-Bu-t)(2)(NMe2)(2)Mo and O-2 plasma. J. Vac. Sci. Technol. A 34, 1–7 (2016)CrossRef Vos, M.F.J., Macco, B., Thissen, N.F.W., et al.: Atomic layer deposition of molybdenum oxide from ((NBu)-Bu-t)(2)(NMe2)(2)Mo and O-2 plasma. J. Vac. Sci. Technol. A 34, 1–7 (2016)CrossRef
go back to reference Wang, M., Wang, J., Chen, W., et al.: Effect of preheating and annealing temperatures on quality characteristics of ZnO thin film prepared by sol–gel method. Mater. Chem. Phys. 97, 219–225 (2006)CrossRef Wang, M., Wang, J., Chen, W., et al.: Effect of preheating and annealing temperatures on quality characteristics of ZnO thin film prepared by sol–gel method. Mater. Chem. Phys. 97, 219–225 (2006)CrossRef
go back to reference Wang, F.X., Qiao, X.F., Xiong, T., et al.: The role of molybdenum oxide as anode interfacial modification in the improvement of efficiency and stability in organic light-emitting diodes. Org. Electron. 9, 985–993 (2008)CrossRef Wang, F.X., Qiao, X.F., Xiong, T., et al.: The role of molybdenum oxide as anode interfacial modification in the improvement of efficiency and stability in organic light-emitting diodes. Org. Electron. 9, 985–993 (2008)CrossRef
go back to reference Yebka, B., Julien, C., Nazri, G.: Electrochemical behavior of hydrated molybdenum oxides in rechargeable lithium batteries. Ionics 5, 236–243 (1999)CrossRef Yebka, B., Julien, C., Nazri, G.: Electrochemical behavior of hydrated molybdenum oxides in rechargeable lithium batteries. Ionics 5, 236–243 (1999)CrossRef
go back to reference Zheng, L., Xu, Y., Jin, D., et al.: Novel metastable hexagonal moo3 nanobelts: synthesis, photochromic, and electrochromic properties. Chem. Mater. 21, 5681–5690 (2009)CrossRef Zheng, L., Xu, Y., Jin, D., et al.: Novel metastable hexagonal moo3 nanobelts: synthesis, photochromic, and electrochromic properties. Chem. Mater. 21, 5681–5690 (2009)CrossRef
Metadata
Title
Investigation of thermal annealing effects on MoO3 thin film by atomic layer deposition
Author
Mustafa Demirtaş
Publication date
01-02-2021
Publisher
Springer US
Published in
Optical and Quantum Electronics / Issue 2/2021
Print ISSN: 0306-8919
Electronic ISSN: 1572-817X
DOI
https://doi.org/10.1007/s11082-020-02717-7

Other articles of this Issue 2/2021

Optical and Quantum Electronics 2/2021 Go to the issue