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Published in:
Synthesis and Molecular Structures of Endohedral Fullerenes Read chapter Read first chapter

2017 | OriginalPaper | Chapter

4. Ions of Endometallofullerenes in the Gas Phase

Author : Olga V. Boltalina

Published in: Endohedral Fullerenes: Electron Transfer and Spin

Publisher: Springer International Publishing

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Abstract

This chapter describes the studies of the endometallofullerene (EMF) ions in the gas phase by various mass spectrometric methods. Historically, mass spectrometry was the first method to indicate the possible existence of EMFs, which happened several years before the discovery of their bulk arc-discharge synthesis. The studies of the ions of EMFs in the gas phase often preceded studies by other techniques that require substantial quantities of EMFs and provided a lot of information on their electronic properties and reactivity. In this chapter, particular attention is devoted to the gas-phase reactions of EMF ions with small molecules, and to the studies of the electron affinity of EMFs.

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previous chapter Non-Chromatographic Separation of Endohedral Metallofullerenes by Utilizing Their Redox Properties
next chapter Photoexcitation in Donor–Acceptor Dyads Based on Endohedral Fullerenes and Their Applications in Organic Photovoltaics
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Metadata
Title
Ions of Endometallofullerenes in the Gas Phase
Author
Olga V. Boltalina
Copyright Year
2017
Book
Endohedral Fullerenes: Electron Transfer and Spin

Print ISBN: 978-3-319-47047-4

Electronic ISBN: 978-3-319-47049-8

Copyright Year: 2017

DOI
https://doi.org/10.1007/978-3-319-47049-8_4

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