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Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 3/2009

01-03-2009 | Original Paper

IR and NMR time-resolved studies on the hydrolysis and condensation of methacryloxyalkylsilanes

Authors: Urska Lavrencic Stangar, Alessandro Sassi, Alfonso Venzo, Andrea Zattin, Boštjan Japelj, Boris Orel, Silvia Gross

Published in: Journal of Sol-Gel Science and Technology | Issue 3/2009

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Abstract

The sol–gel reactions of the two methacrylate-modified silanes methacryloxymethyltriethoxysilane (MAMTES) and methacryloxypropyltrimethoxysilane (MAPTMS) were followed by using two independent time-resolved spectroscopic methods, viz., IR ATR and NMR with the aim to optimise their pre-hydrolysis times and consequently their use as precursors for hybrid materials. Time resolved measurements were carried out on the two systems under sol–gel conditions. Whereas the hydrolysis of both siloxanes is very fast, condensation proceeds gradually and is not completely finished within 5 h.
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Metadata
Title
IR and NMR time-resolved studies on the hydrolysis and condensation of methacryloxyalkylsilanes
Authors
Urska Lavrencic Stangar
Alessandro Sassi
Alfonso Venzo
Andrea Zattin
Boštjan Japelj
Boris Orel
Silvia Gross
Publication date
01-03-2009
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 3/2009
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-008-1882-1

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