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Biomass Conversion and Biorefinery
Published in: Biomass Conversion and Biorefinery 2/2018

24-08-2017 | Original Article

Methyl β-cyclodextrin as a booster for the extraction for Olea europaea leaf polyphenols with a bio-based deep eutectic solvent

Authors: Vassilis Athanasiadis, Spyros Grigorakis, Stavros Lalas, Dimitris P. Makris

Published in: Biomass Conversion and Biorefinery | Issue 2/2018

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Abstract

A novel deep eutectic solvent (DES) with optimised composition was used to evaluate the effect of methyl β-cyclodextrin (CD) on the efficiency of polyphenol extraction from Olea europaea leaves (OLLs). The process developed was based on a 23 full-factorial design and response surface methodology to assess the simultaneous effect of CD concentration (C CD), liquid-to-solid ratio (R L/S ) and temperature (T). Under optimised conditions (C CD = 9%, R L/S = 40 mL g−1, T = 51 °C), the yield in total polyphenols (Y TP) was 116.65 ± 3.60 mg gallic acid equivalents per g dry weight. This value was significantly higher than that determined for the extraction performed with 60% aqueous ethanol. The extraction kinetics also showed that the extraction rate was slowed down in the presence of CD, yet the higher extraction capacity of the DES/CD medium was confirmed. Characterisation of the extracts obtained with DES/CD and DES by means of liquid chromatography-mass spectrometry demonstrated that there was no selective extraction of any particular polyphenol, suggesting that CD acted merely as an extraction booster.
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Metadata
Title
Methyl β-cyclodextrin as a booster for the extraction for Olea europaea leaf polyphenols with a bio-based deep eutectic solvent
Authors
Vassilis Athanasiadis
Spyros Grigorakis
Stavros Lalas
Dimitris P. Makris
Publication date
24-08-2017
Publisher
Springer Berlin Heidelberg
Published in
Biomass Conversion and Biorefinery / Issue 2/2018
Print ISSN: 2190-6815
Electronic ISSN: 2190-6823
DOI
https://doi.org/10.1007/s13399-017-0283-5

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