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Cellulose
Published in: Cellulose 1/2018

01-12-2017 | Original Paper

Micro-patterns on nanocellulose films and paper by photo-induced thiol–yne click coupling: a facile method toward wetting with spatial resolution

Authors: Jiaqi Guo, Ilari Filpponen, Leena-Sisko Johansson, Stefan Heiβler, Lei Li, Pavel Levkin, Orlando J. Rojas

Published in: Cellulose | Issue 1/2018

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Abstract

We report a facile approach to tailor the wettability of ligno-cellulosic substrates via photo-induced thiol–yne click coupling. First, cellulosic surfaces were functionalized with 4-pentynoic acid to introduce terminal alkyne moieties for the subsequent photo-induced coupling in heterogeneous phase. Next, the (primed) surfaces were reacted with various thiol-containing molecules to systematically tailor the surface energy. Finally, the method was applied to nanocellulose films and paper to develop micro-patterned surfaces via UV lithography, endowing the substrates with thin hydrophilic channels (~ 250 μm thickness) and hydrophobic boundaries between neighboring water droplets, as small as 100 μm in width. Overall, we propose thiol-click as a facile method toward spatially-resolved wetting that enables paper-based electronics in smart labels and point-of-care bioplatforms.
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Appendix
Available only for authorised users
Literature
Chen G, Kumar J, Gregory A, Stenzel MH (2009) Efficient synthesis of dendrimers via a thiol–yne and esterification process and their potential application in the delivery of platinum anti-cancer drugs. Chem Commun 41:6291–6293CrossRef
Falconnet D, Csucs G, Grandin HM, Textor M (2006) Surface engineering approaches to micropattern surfaces for cell-based assays. Biomaterials 27:3044–3063CrossRef
Feng W, Li L, Ueda E, Li J, Heißler S, Welle A, Trapp O, Levkin PA (2014) Surface patterning via thiol–yne click chemistry: an extremely fast and versatile approach to superhydrophilic–superhydrophobic micropatterns. Adv Mater Interfaces 1:1400269CrossRef
Gau H, Herminghaus S, Lenz P, Lipowsky R (1999) Liquid morphologies on structured surfaces: from microchannels to microchips. Science 283:46–49CrossRef
Guo J, Fang W, Welle A, Feng W, Filpponen I, Rojas OJ, Levkin PA (2016) Superhydrophobic and slippery lubricant-infused flexible transparent nanocellulose films by photoinduced thiol–ene functionalization. ACS Appl Mater Interfaces 8:34115–34122CrossRef
Haginoya C, Ishibashi M, Koike K (1997) Nanostructure array fabrication with a size-controllable natural lithography. Appl Phys Lett 71:2934–2936CrossRef
Hayward R, Saville D, Aksay I (2000) Electrophoretic assembly of colloidal crystals with optically tunable micropatterns. Nature 404:56–59CrossRef
He Q, Sudibya HG, Yin Z, Wu S, Li H, Boey F, Huang W, Chen P, Zhang H (2010) Centimeter-long and large-scale micropatterns of reduced graphene oxide films: fabrication and sensing applications. ACS Nano 4:3201–3208CrossRef
Hoogenboom R (2010) Thiol–yne chemistry: a powerful tool for creating highly functional materials. Angew Chem Int Ed 49:3415–3417CrossRef
Huang J, Zhu H, Chen Y, Preston C, Rohrbach K, Cumings J, Hu L (2013) Highly transparent and flexible nanopaper transistors. ACS Nano 7:2106–2113CrossRef
Huang J, Li C, Gray DG (2014) Functionalization of cellulose nanocrystal films via “thiol–ene” click reaction. RSC Adv 4:6965–6969CrossRef
Juvonen H, Määttänen A, Laurén P, Ihalainen P, Urtti A, Yliperttula M, Peltonen J (2013) Biocompatibility of printed paper-based arrays for 2-D cell cultures. Acta Biomater 9:6704–6710CrossRef
Kargl R, Mohan T, Köstler S, Spirk S, Doliška A, Stana-Kleinschek K, Ribitsch V (2013) Functional patterning of biopolymer thin films using enzymes and lithographic methods. Adv Func Mater 23:308–315CrossRef
Kim J, Yun S, Ounaies Z (2006) Discovery of cellulose as a smart material. Macromolecules 39:4202–4206CrossRef
Klemm D, Kramer F, Moritz S, Lindström T, Ankerfors M, Gray D, Dorris A (2011) Nanocelluloses: a new family of nature-based materials. Angew Chem Int Ed 50:5438–5466CrossRef
Lessing J, Glavan AC, Walker SB, Keplinger C, Lewis JA, Whitesides GM (2014) Inkjet printing of conductive inks with high lateral resolution on omniphobic “RF Paper” for paper-based electronics and MEMS. Adv Mater 26:4677–4682CrossRef
Li Y, Pan M, Li Y, Huang Y, Guo Q (2013) Thiol–yne radical reaction mediated site-specific protein labeling via genetic incorporation of an alkynyl-l-lysine analogue. Org Biomol Chem 11:2624–2629CrossRef
Li L, Li J, Du X, Welle A, Grunze M, Trapp O, Levkin PA (2014) Direct UV-induced functionalization of surface hydroxy groups by thiol–ol chemistry. Angew Chem Int Ed 53:3835–3839CrossRef
Lin SY, Chow E, Hietala VV, Villeneuve PR, Joannopoulos JD (1998) Experimental demonstration of guiding and bending of electromagnetic waves in a photonic crystal. Science 282:274–276CrossRef
Nogi M, Iwamoto S, Nakagaito AN, Yano H (2009) Optically transparent nanofiber paper. Adv Mater 21:1595–1598CrossRef
Painter O, Lee RK, Scherer A, Yariv A, O’Brien JD, Dapkus PD, Kim II (1999) Two-dimensional photonic band-Gap defect mode laser. Science 284:1819–1821CrossRef
Popova AA, Schillo SM, Demir K, Ueda E, Nesterov-Mueller A, Levkin PA (2015) Droplet-array (DA) sandwich chip: a versatile platform for high-throughput cell screening based on superhydrophobic-superhydrophilic micropatterning. Adv Mater 27:5217–5222CrossRef
Popova AA, Demir K, Hartanto TG, Schmitt E, Levkin PA (2016) Droplet-microarray on superhydrophobic–superhydrophilic patterns for high-throughput live cell screenings. RSC Adv 6:38263–38276CrossRef
Siegel AC, Phillips ST, Dickey MD, Lu N, Suo Z, Whitesides GM (2010) Foldable printed circuit boards on paper substrates. Adv Func Mater 20:28–35CrossRef
Song J, Rojas OJ (2013) Approaching super-hydrophobicity from cellulosic materials: a review. Nord Pulp Paper Res J 28:216–238CrossRef
Songok J, Tuominen M, Teisala H, Haapanen J, Mäkelä J, Kuusipalo J, Toivakka M (2014) Paper-based microfluidics: fabrication technique and dynamics of capillary-driven surface flow. ACS Appl Mater Interfaces 6:20060–20066CrossRef
Teisala H, Tuominen M, Kuusipalo J (2014) Superhydrophobic coatings on cellulose-based materials: fabrication, properties, and applications. Adv Mater Interfaces 1:1–20
Tingaut P, Hauert R, Zimmermann T (2011) Highly efficient and straightforward functionalization of cellulose films with thiol–ene click chemistry. J Mater Chem 21:16066–16076CrossRef
Zeng M, Laromaine A, Feng W, Levkin PA, Roig A (2014) Origami magnetic cellulose: controlled magnetic fraction and patterning of flexible bacterial cellulose. J Mater Chem C 2:6312–6318CrossRef
Zhu H, Luo W, Ciesielski PN, Fang Z, Zhu J, Henriksson G, Himmel ME, Hu L (2016) Wood-derived materials for green electronics, biological devices, and energy applications. Chem Rev 116:9305–9374CrossRef
Metadata
Title
Micro-patterns on nanocellulose films and paper by photo-induced thiol–yne click coupling: a facile method toward wetting with spatial resolution
Authors
Jiaqi Guo
Ilari Filpponen
Leena-Sisko Johansson
Stefan Heiβler
Lei Li
Pavel Levkin
Orlando J. Rojas
Publication date
01-12-2017
Publisher
Springer Netherlands
Published in
Cellulose / Issue 1/2018
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-017-1593-2

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