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Cellulose
Published in: Cellulose 5/2013

01-10-2013 | Original Paper

Nanocomposite hydrogel from grafting of acrylamide onto HPMC using sodium montmorillonite nanoclay and removal of crystal violet dye

Authors: Gholam Reza Mahdavinia, Javad Hasanpour, Zeinab Rahmani, Shiva Karami, Hossein Etemadi

Published in: Cellulose | Issue 5/2013

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Abstract

Hydrogel nanocomposites were synthesized from grafting of acrylamide onto hydroxypropyl methylcellulose using methylenebisacrylamide crosslinker and sodium montmorillonite (Na-MMt) nanoclay. The effect of nanoclay content on the swelling of nanocomposites was investigated and an optimum swelling capacity was obtained at 12.7 wt% of Na-MMt. The effect of salt solutions on the swelling of nanocomposites revealed that the degree of swelling of samples depends only slightly on the salinity. The structure of nanocomposites was characterized by XRD, SEM, FTIR, and TEM techniques. The XRD and TEM results confirmed the exfoliation of Na-MMt nanoclay in nanocomposite matrix. The morphology of the nanocomposites was characterized by SEM technique and according to the results a loose surface was observed. The nanocomposite hydrogels were evaluated to remove cationic crystal violet dye from water. The investigation of the dye adsorption capacity and rate of nanocomposite hydrogels as a function of Na-MMt content revealed that the both adsorption capacity and rate is enhanced as the nanoclay content is increased in nanocomposite composition. The experimental equilibrated adsorption capacity of nanocomposites was analyzed using Freundlich and Langmuir isotherm models. The best fit to the experimental data was obtained with the Langmuir model.
previous article Effects of emulsifier on the bonding performance and freeze–thaw stability of starch-based wood adhesive
next article Effect of hydrolysis degree of hydrolyzed polyacrylamide grafted carboxymethyl cellulose on dye removal efficiency

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Metadata
Title
Nanocomposite hydrogel from grafting of acrylamide onto HPMC using sodium montmorillonite nanoclay and removal of crystal violet dye
Authors
Gholam Reza Mahdavinia
Javad Hasanpour
Zeinab Rahmani
Shiva Karami
Hossein Etemadi
Publication date
01-10-2013
Publisher
Springer Netherlands
Published in
Cellulose / Issue 5/2013
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-013-0004-6

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