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Published in: Journal of Materials Science: Materials in Electronics 9/2021

06-04-2021

Performances of flexible dye‐sensitized solar cells fabricated with binder‐free nanostructure TiO2

Authors: S. C. Poh, H. Ahmad, C. H. Ting, H. T. Tung, H. K. Jun

Published in: Journal of Materials Science: Materials in Electronics | Issue 9/2021

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Abstract

Dye-sensitized solar cell (DSSC) is getting much attention in recent years due to its low-cost fabrication feature. DSSC mimics the natural photosynthesis process that converts solar energy into electricity. To be adopted in IoT devices, DSSC needs to be flexible and versatile. In this work, flexible DSSC was fabricated from binder-free TiO2 paste. The ratios of TiO2 powder to alcohol precursor were varied. The aim was to investigate the optimum amount of TiO2 powder to ethanol and the effect of different alcohol used as precursor. Hydrochloric acid was added in the TiO2 paste in order to improve the connectivity of the particles. The corresponding mechanical integrity of the as-prepared film was studied as well. From the result, the optimum conversion efficiency achieved in this work was 2.12% where the film had a ratio of TiO2 powder to ethanol of 25 wt%.

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Literature
1.
go back to reference S. Chu, A. Majumdar, Opportunities and challenges for a sustainable energy future. Nature 488, 294–303 (2012)CrossRef S. Chu, A. Majumdar, Opportunities and challenges for a sustainable energy future. Nature 488, 294–303 (2012)CrossRef
2.
go back to reference A. Aslam, U. Mehmood, M.H. Arshad, A. Ishfaq, J. Zaheer, A.U.H. Khan, M. Sufyan, Dye-sensitized solar cells (DSSCs) as a potential photovoltaic technology for the self-powered internet of things (IoTs) applications. Sol. Energy 207, 874–892 (2020)CrossRef A. Aslam, U. Mehmood, M.H. Arshad, A. Ishfaq, J. Zaheer, A.U.H. Khan, M. Sufyan, Dye-sensitized solar cells (DSSCs) as a potential photovoltaic technology for the self-powered internet of things (IoTs) applications. Sol. Energy 207, 874–892 (2020)CrossRef
3.
go back to reference D.K. Kumar, J. Kriz, N. Bernnett, B. Chen, H. Upadhayaya, K.R. Reddy, V. Sadhu, Functionalized metal oxide nanoparticles for efficient dye-sensitized solar cells (DSSCs): a review. Mater. Sci. Energy Technol. 3, 472–481 (2020) D.K. Kumar, J. Kriz, N. Bernnett, B. Chen, H. Upadhayaya, K.R. Reddy, V. Sadhu, Functionalized metal oxide nanoparticles for efficient dye-sensitized solar cells (DSSCs): a review. Mater. Sci. Energy Technol. 3, 472–481 (2020)
4.
go back to reference K. Sharma, V. Sharma, S.S. Sharma, Dye-sensitized solar cells: fundamentals and current status. Nanoscale Res. Lett. 13, 2760–2766 (2018)CrossRef K. Sharma, V. Sharma, S.S. Sharma, Dye-sensitized solar cells: fundamentals and current status. Nanoscale Res. Lett. 13, 2760–2766 (2018)CrossRef
5.
go back to reference K. Zeng, Z. Tong, L. Ma, W.-H. Zhu, W. Wu, Y. Xie, Molecular engineering strategies for fabricating efficient porphyrin-based dye-sensitized solar cells. Energy Environ. Sci. 13, 1617–1657 (2020)CrossRef K. Zeng, Z. Tong, L. Ma, W.-H. Zhu, W. Wu, Y. Xie, Molecular engineering strategies for fabricating efficient porphyrin-based dye-sensitized solar cells. Energy Environ. Sci. 13, 1617–1657 (2020)CrossRef
6.
go back to reference Y. Cao, Y. Saygili, A. Ummadisingu, J. Teuscher, J. Luo, N. Pellet, F. Giordano, S.M. Zakeerudding, J.-E. Moser, M. Freitag, A. Hagfeldt, M. Grätzel, 11% efficiency solid-state dye-sensitized solar cells with copper (II/I) hole transport materials. Nat. Commun. 8, 15390 (2017)CrossRef Y. Cao, Y. Saygili, A. Ummadisingu, J. Teuscher, J. Luo, N. Pellet, F. Giordano, S.M. Zakeerudding, J.-E. Moser, M. Freitag, A. Hagfeldt, M. Grätzel, 11% efficiency solid-state dye-sensitized solar cells with copper (II/I) hole transport materials. Nat. Commun. 8, 15390 (2017)CrossRef
7.
go back to reference Y. Ren, D. Sun, Y. Cao, H.N. Tsao, Y. Yuan, S.M. Zakeeruddin, P. Wang, M. Grätzel, A stable blue photosensitizer for color paletter of dye-sensitized solar cells reaching 12.6% efficiency. J. Am. Chem. Soc. 140, 2405–2408 (2018)CrossRef Y. Ren, D. Sun, Y. Cao, H.N. Tsao, Y. Yuan, S.M. Zakeeruddin, P. Wang, M. Grätzel, A stable blue photosensitizer for color paletter of dye-sensitized solar cells reaching 12.6% efficiency. J. Am. Chem. Soc. 140, 2405–2408 (2018)CrossRef
8.
go back to reference S. Mathew, A. Yella, P. Gao, R. Humphry-Baker, B.F.E. Curchod, N. Ashari-Astanim, I. Tavernelli, U. Rothlisberger, M.K. Nazeeruddin, M. Grätzel, Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers. Nat. Chem. 6, 242–247 (2014)CrossRef S. Mathew, A. Yella, P. Gao, R. Humphry-Baker, B.F.E. Curchod, N. Ashari-Astanim, I. Tavernelli, U. Rothlisberger, M.K. Nazeeruddin, M. Grätzel, Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers. Nat. Chem. 6, 242–247 (2014)CrossRef
9.
go back to reference M.J. Yun, M.S.I. Cha, S.H. Seo, D.Y. Lee, Highly flexible dye-sensitized solar cells produced by sewing textile electrodes on cloth. Sci. Rep. 4, 5322 (2014)CrossRef M.J. Yun, M.S.I. Cha, S.H. Seo, D.Y. Lee, Highly flexible dye-sensitized solar cells produced by sewing textile electrodes on cloth. Sci. Rep. 4, 5322 (2014)CrossRef
10.
go back to reference G. Yue, X. Liu, Y. Chen, J. Huo, H. Zheng, Improvement in the photoelectric conversion efficiency for the flexible fibrous dye-sensitized solar cells. Nanoscale Res. Lett. 13, 188 (2018)CrossRef G. Yue, X. Liu, Y. Chen, J. Huo, H. Zheng, Improvement in the photoelectric conversion efficiency for the flexible fibrous dye-sensitized solar cells. Nanoscale Res. Lett. 13, 188 (2018)CrossRef
11.
go back to reference L. Zhang, A. Konno, Development of flexible dye-sensitized solar cell based on pre-dye zinc oxide nanoparticle. Int. J. Electrochem. Sci. 13, 344–352 (2018)CrossRef L. Zhang, A. Konno, Development of flexible dye-sensitized solar cell based on pre-dye zinc oxide nanoparticle. Int. J. Electrochem. Sci. 13, 344–352 (2018)CrossRef
12.
go back to reference H. Michaels, M. Rinderle, R. Freitag, I. Benesperi, T. Edvinsson, R. Socher, A. Gagliardi, M. Freitag, Dye-sensitized solar cells under ambient light powering machine learning: towards autonomous smart sensors for internet of things. Chem. Sci. 11, 2895–2906 (2020)CrossRef H. Michaels, M. Rinderle, R. Freitag, I. Benesperi, T. Edvinsson, R. Socher, A. Gagliardi, M. Freitag, Dye-sensitized solar cells under ambient light powering machine learning: towards autonomous smart sensors for internet of things. Chem. Sci. 11, 2895–2906 (2020)CrossRef
13.
go back to reference H.C. Weerasinghe, G.V. Franks, J.D. Plessis, G.P. Simon, Y.-B. Cheng, Anomalous rheological behavior in chemically modified TiO2 colloidal pastes prepared for flexible dye-sensitized solar cells. J. Mater. Chem. 20, 9954–9961 (2010)CrossRef H.C. Weerasinghe, G.V. Franks, J.D. Plessis, G.P. Simon, Y.-B. Cheng, Anomalous rheological behavior in chemically modified TiO2 colloidal pastes prepared for flexible dye-sensitized solar cells. J. Mater. Chem. 20, 9954–9961 (2010)CrossRef
14.
go back to reference H.C. Weerasinghe, P.M. Sirimanne, G.V. Franks, G.P. Simo, Cheng Low temperature chemically sintered nano-crystalline TiO2 electrodes for flexible dye-sensitized solar cells. J. Photochem. Photobiol. A 213, 30–36 (2010)CrossRef H.C. Weerasinghe, P.M. Sirimanne, G.V. Franks, G.P. Simo, Cheng Low temperature chemically sintered nano-crystalline TiO2 electrodes for flexible dye-sensitized solar cells. J. Photochem. Photobiol. A 213, 30–36 (2010)CrossRef
15.
go back to reference B. Li, F. huang, J. Zhong, J. Xie, M. Wen, Y. Peng, Fabrication of flexible dye-sensitized solar cell modules using commercially available materials. Energy Technol. 430070, 536–542 (2016)CrossRef B. Li, F. huang, J. Zhong, J. Xie, M. Wen, Y. Peng, Fabrication of flexible dye-sensitized solar cell modules using commercially available materials. Energy Technol. 430070, 536–542 (2016)CrossRef
16.
go back to reference D. Zhang, T. Yoshida, T. Oekermann, K. Furuta, H. Minoura, Room-temperature synthesis of porous nanoparticulate TiO2 films for flexible dye-sensitized solar cells. Adv. Funct. Mater. 16, 1228–1234 (2006)CrossRef D. Zhang, T. Yoshida, T. Oekermann, K. Furuta, H. Minoura, Room-temperature synthesis of porous nanoparticulate TiO2 films for flexible dye-sensitized solar cells. Adv. Funct. Mater. 16, 1228–1234 (2006)CrossRef
17.
go back to reference W.-H. Yen, C.-C. Hsieh, C.-Y. Hung, H.-W. Wang, M.-C. Tsui, Flexible TiO2 working electrode for dye-sensitized solar cells. J. Chin. Chem. Soc. 57, 1162–1166 (2010)CrossRef W.-H. Yen, C.-C. Hsieh, C.-Y. Hung, H.-W. Wang, M.-C. Tsui, Flexible TiO2 working electrode for dye-sensitized solar cells. J. Chin. Chem. Soc. 57, 1162–1166 (2010)CrossRef
18.
go back to reference L. Muliana, J. Hidayat, P.N. Anggraini, Performance analysis of flexible DSSC with binder addition. AIP Conf. Proc. 1725, 020050 (2016)CrossRef L. Muliana, J. Hidayat, P.N. Anggraini, Performance analysis of flexible DSSC with binder addition. AIP Conf. Proc. 1725, 020050 (2016)CrossRef
19.
go back to reference W. Mekprasart, W. Jarernboon, W. Pecharapa, TiO2/CuPc hyvrid nanocomposites prepared by low-energy ball milling for dye-sensitized solar cell application. Mater. Sci. Eng. B 172, 231–236 (2010)CrossRef W. Mekprasart, W. Jarernboon, W. Pecharapa, TiO2/CuPc hyvrid nanocomposites prepared by low-energy ball milling for dye-sensitized solar cell application. Mater. Sci. Eng. B 172, 231–236 (2010)CrossRef
20.
go back to reference M. Singh, C.-H. Chiang, K.M. Boopathi, C. Hanmandlu, G. Li, C.-G. Wu, H.-C. Lin, C.-W. Chu, A novel ball milling technique for room temperature processing of TiO2 nanoparticles employed as the electron transport layer in perovskite solar cells and modules. J. Mater. Chem. A 6, 7114–7122 (2018)CrossRef M. Singh, C.-H. Chiang, K.M. Boopathi, C. Hanmandlu, G. Li, C.-G. Wu, H.-C. Lin, C.-W. Chu, A novel ball milling technique for room temperature processing of TiO2 nanoparticles employed as the electron transport layer in perovskite solar cells and modules. J. Mater. Chem. A 6, 7114–7122 (2018)CrossRef
21.
go back to reference H.H. Nguyen, G. Gyawali, T.H. Kim, S.B. Humam, S.W. Lee, Blue TiO2 polymorph: an efficient materials for dye-sensitized solar cells fabricated using a low-temperature sintering process. Prog. Nat. Sci. 28, 578–553 (2018) H.H. Nguyen, G. Gyawali, T.H. Kim, S.B. Humam, S.W. Lee, Blue TiO2 polymorph: an efficient materials for dye-sensitized solar cells fabricated using a low-temperature sintering process. Prog. Nat. Sci. 28, 578–553 (2018)
22.
go back to reference N.-G. Park, K.M. Kim, M.G. Kang, K.S. Ryu, S.H. Chang, Y.-J. Shin, Chemical sintering of nanoparticles: a methodology for low-temperature fabrication of dye-sensitized TiO2 films. Adv. Mater. 17, 2349–2353 (2005)CrossRef N.-G. Park, K.M. Kim, M.G. Kang, K.S. Ryu, S.H. Chang, Y.-J. Shin, Chemical sintering of nanoparticles: a methodology for low-temperature fabrication of dye-sensitized TiO2 films. Adv. Mater. 17, 2349–2353 (2005)CrossRef
23.
go back to reference D. Zhang, J.A. Downing, F.J. Knorr, J.L. McHale, Room-temperature preparation of nanoscrystalline TiO2 films and the influence of surface properties on dye-sensitized solar energy conversion. J. Phys. Chem. B 110, 21890–21898 (2006)CrossRef D. Zhang, J.A. Downing, F.J. Knorr, J.L. McHale, Room-temperature preparation of nanoscrystalline TiO2 films and the influence of surface properties on dye-sensitized solar energy conversion. J. Phys. Chem. B 110, 21890–21898 (2006)CrossRef
24.
go back to reference T. Miyasaka, M. Ikegami, Y. Kijitori, Photovoltaic performance of plastic dye-sensitized electrodes prepared by low-temperature binder-free coating of mesoscopic titania. J. Electrochem. Soc. 154, A455 (2007)CrossRef T. Miyasaka, M. Ikegami, Y. Kijitori, Photovoltaic performance of plastic dye-sensitized electrodes prepared by low-temperature binder-free coating of mesoscopic titania. J. Electrochem. Soc. 154, A455 (2007)CrossRef
25.
go back to reference T. Yamaguchi, N. Tobe, D. Matsumoto, H. Arakawa, Highly efficient plastic substrate dye-sensitized solar cells using a compression method for preparation of TiO2 photoelectrodes. Chem. Commun. 45, 4767–4769 (2007)CrossRef T. Yamaguchi, N. Tobe, D. Matsumoto, H. Arakawa, Highly efficient plastic substrate dye-sensitized solar cells using a compression method for preparation of TiO2 photoelectrodes. Chem. Commun. 45, 4767–4769 (2007)CrossRef
26.
go back to reference H.C. Weerasinghe, P.M. Sirimanne, G.P. Simon, Y. Cheng, Cold isostatic pressing technique for producing highly efficient flexible dye-sensitised solar cells on plastic substrates. Prog. Photovolt. 20, 321–332 (2012)CrossRef H.C. Weerasinghe, P.M. Sirimanne, G.P. Simon, Y. Cheng, Cold isostatic pressing technique for producing highly efficient flexible dye-sensitised solar cells on plastic substrates. Prog. Photovolt. 20, 321–332 (2012)CrossRef
27.
go back to reference J.H. Yune, I. Karatchevtseva, G. Triani, A study of TiO2 binder-free paste prepared for low temperature dye-sensitized solar cells. J. Mater. Res. 28, 488–496 (2012)CrossRef J.H. Yune, I. Karatchevtseva, G. Triani, A study of TiO2 binder-free paste prepared for low temperature dye-sensitized solar cells. J. Mater. Res. 28, 488–496 (2012)CrossRef
28.
go back to reference D.K. Kumar, M.-H. Hsu, A. Ivaturi, B. Chen, N. Bennett, H.M. Upadhyaya, Optimizing room temperature binder free TiO2 paste for high efficiency flexible polymer dye sensitized solar cells. Flex. Print. Electron. 4, 015007 (2019)CrossRef D.K. Kumar, M.-H. Hsu, A. Ivaturi, B. Chen, N. Bennett, H.M. Upadhyaya, Optimizing room temperature binder free TiO2 paste for high efficiency flexible polymer dye sensitized solar cells. Flex. Print. Electron. 4, 015007 (2019)CrossRef
29.
go back to reference H.H. Foong, H. Ahmad, C.H. Ting, C.Y. Ng, C.Y.H.K. Jun, Reduced graphene oxide on the performance of solid-state dye-sensitized solar cell. IOP Conf. Ser. Earth Environ Sci. 268, 012119 (2019)CrossRef H.H. Foong, H. Ahmad, C.H. Ting, C.Y. Ng, C.Y.H.K. Jun, Reduced graphene oxide on the performance of solid-state dye-sensitized solar cell. IOP Conf. Ser. Earth Environ Sci. 268, 012119 (2019)CrossRef
31.
go back to reference X.-L. He, M. Liu, G.-J. Yang, B. Fang, C.-J. Li, Unexpected efficiency enhancement of flexible dye-sensitized solar cells by repeated outward bending. RSC Adv. 5, 85174–85178 (2015)CrossRef X.-L. He, M. Liu, G.-J. Yang, B. Fang, C.-J. Li, Unexpected efficiency enhancement of flexible dye-sensitized solar cells by repeated outward bending. RSC Adv. 5, 85174–85178 (2015)CrossRef
32.
go back to reference M.N. Mustafa, Y. Sulaiman, Fully flexible dye-sensitized solar cells photoanode modified with titanium dioxide-graphene quantum dot light scattering layer. Sol. Energy 212, 332–338 (2020)CrossRef M.N. Mustafa, Y. Sulaiman, Fully flexible dye-sensitized solar cells photoanode modified with titanium dioxide-graphene quantum dot light scattering layer. Sol. Energy 212, 332–338 (2020)CrossRef
Metadata
Title
Performances of flexible dye‐sensitized solar cells fabricated with binder‐free nanostructure TiO2
Authors
S. C. Poh
H. Ahmad
C. H. Ting
H. T. Tung
H. K. Jun
Publication date
06-04-2021
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 9/2021
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-021-05833-6

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