Top

Journal of Polymer Research

Published in:

01-04-2021 | ORIGINAL PAPER

Physicochemical characterization of SnO₂ grafted Poly p-phenylenediamine hybrid Nanocomposites and their enhanced antibacterial properties

Authors: Shyamal Baruah, Bharat Nayak, Amrit Puzari

Published in: Journal of Polymer Research | Issue 4/2021

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Work presented here demonstrates successful synthesis and characterization of SnO₂ nanoparticle grafted poly p-phenylenediamine/SnO₂ nanocomposites. Synthesis of the nanocomposites were accomplished by In situ oxidative polymerization technique using H₂O₂ as an oxidant. SnO₂ nanoparticles were synthesised by sol–gel technique. XRD analysis confirms the amorphous to semi crystalline morphology of the composites. FT-IR spectroscopy results also confirms the incorporation of the metal oxides nanoparticles into the polymer matrix. TGA also confirms that the materials possess appreciable thermal stability. From I-V measurement, it was revealed that conductivity of the nanocomposites falls in the semiconductor region. Therefore, the nanocomposites are expected to have application in the field of optoelectronics. In addition, the polymer and the nanocomposites possess potential antibacterial properties against Gram-positive and Gram-negative bacteria such as E. coli and Bacillus subtilis. The nanocomposites were showing better activity compared to the polymer. The materials developed thus can be used for fabrication of materials with antibacterial properties.

previous article Covalent triazine based polymer with high nitrogen levels for removal of copper‎‎ (II) ions ‎from aqueous solutions

next article Preparation and physical properties of transparent foldable poly(methyl methacrylate) based materials using reactive poly(vinyl butyral)

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

Alya KI, Younisb O, Mahrossd MH, Orabie EA, Hakimd MA, Tsutsumic O, Mohameda MG, Sayed MM (2019) Conducting copolymers nanocomposite coatings with aggregationcontrolled luminescence and efficient corrosion inhibition properties. Prog Org Coat. 135:525–535. https://doi.org/10.1016/j.porgcoat.2019.06.001.

Aly KI, Younis O, Mahross MH, Tsutsumi O, Mohamed MG, Sayed MM (2018) Novel conducting polymeric nanocomposites embedded with nanoclay: synthesis, photoluminescence, and corrosion protection performance. Polym J. https://doi.org/10.1038/s41428-018-0119-6.

Gangopadhyay R, De A (2000) Conducting Polymer Nanocomposites: A Brief Overview. Chem Mater 12:608–622. https://doi.org/10.1021/cm990537f.CrossRef

Emamy H, Kumar SK, Starr FW (2020) Structural Properties of Bound Layer in Polymer-Nanoparticle Composites. Macromolecules 53:7845–7850. https://doi.org/10.1021/acs.macromol.0c01465.CrossRef

Vargas-Reus MA, Memarzadeh K, Huang J, Ren GG, Allaker RP (2012) Antimicrobial activity of nanoparticulate metal oxides against peri-implantitis pathogens. Int J Antimicrob Agents 40:135–139. https://doi.org/10.1016/j.ijantimicag.2012.04.012.CrossRefPubMed

Ali A, Andriyana A (2020) Properties of multifunctional composite materials based on nanomaterials: a review. RSC Adv 10:16390–16403. https://doi.org/10.1039/C9RA10594H.CrossRef

Atisme TB, Yu CY, Tseng EN, Chen YC, Hsu PK, Chen SY (2019) Interface Interactions in Conjugated Polymer Composite with Metal Oxide Nanoparticles. Nanomaterials (Basel) 9:1534. https://doi.org/10.3390/nano9111534.CrossRef

Khan I, Saeed K, Khan I (2019) Nanoparticles: Properties, applications and toxicities. Arab J Chem 12:908–931. https://doi.org/10.1016/j.arabjc.2017.05.011.CrossRef

Ansari MO, Khan MM, Ansari SA, Cho MH (2015) DC electrical conductivity retention and electrical compensation of polyaniline by TiO₂ at higher loading percentages in polyaniline@TiO₂ nanocomposites. Electron Mater Lett 11:559–564. https://doi.org/10.1007/s13391-015-5073-2.CrossRef

10.

Sharma A, Vyas R, Jain PK, Jain VK (2012) Optical Properties of in-situ Chemically Synthesized PANI-TiO₂ Nanocomposites. J Nano Electron Phy 11:2012–2015. https://doi.org/10.21272/jnep.11(2).02012.CrossRef

11.

Umare SS, Shambharkar B, Ningthoujam RS (2010) Synthesis and characterization of polyaniline–Fe₃O₄ nanocomposite: Electrical conductivity, magnetic, electrochemical studies. Synth Met 160:1815–1821. https://doi.org/10.1016/j.synthmet.2010.06.015.CrossRef

12.

P. Agilan N ( 2018) Rajendran, In-vitro bioactivity and electrochemical behavior of polyaniline encapsulated titania nanotube arrays for biomedical applications. Appl Surf Sci. 439:66–74. https://doi.org/10.1016/j.apsusc.2017.12.258.

13.

Wen B, Waterhouse GIN, Jia MY, Jiang X, Zhang ZM, Yu L (2019) The feasibility of polyaniline-TiO₂ coatings for photocathodic antifouling: antibacterial effect. Synth Met 257:116175. https://doi.org/10.1016/j.synthmet.2019.116175.CrossRef

14.

Mosanenzadeh SG, Karamikamkar S, Saadatnia Z, Park CB, Naguib HE (2020) PPDA-PMDA polyimide aerogels with tailored nanostructure assembly for air filtering applications. Sep Pur Tech 250:117279. https://doi.org/10.1016/j.seppur.2020.117279.CrossRef

15.

Gu M, Duan J, Mao Q, Zhang S, Jiagen LV (2019) Direct chemiluminescent sensing of para-Phenylenediamine over its isomers and analogues via luminol diazotization. Sensors and Actuators B: Chemical 287:173–179. https://doi.org/10.1016/j.snb.2019.02.040.CrossRef

16.

Baro M, Jaidev, Ramaprabhu S (2020) Conductive and nitrogen-enriched porous carbon nanostructure derived from poly (para-phenylenediamine) for energy conversion and storage applications. Appl Sur Sci. 503:144069 https://doi.org/10.1016/j.apsusc.2019.144069.

17.

Shanmugham C, Nallaiyan R (2015) Corrosion resistance of poly p-phenylenediamine conducting polymer coated 316L SS bipolar plates for Proton Exchange Membrane Fuel Cells. Prog Org Coat. 89:42–49 https://doi.org/10.1016/j.porgcoat.2015.07.0232015.07.023.

18.

Khosrozadeh A, Darabi MA, Wang Q, Xing M (2017) Polyaniline nanoflowers grown on vibration-isolator-mimetic polyurethane nanofibers for flexible supercapacitors with prolonged cycle life. J Mater Chem A 5:7933–7943. https://doi.org/10.1039/C7TA00591A.CrossRef

19.

De Gennes PG (1980) Conformations of polymers attached to an interface Macromolecules 13(1980):1069–1075. https://doi.org/10.1021/ma60077a009.CrossRef

20.

Jaidev, Ramaprabhu S (2012) Poly(p-phenylenediamine)/graphene nanocomposites for supercapacitor applications. J Mater Chem. 22:18775–18783 https://doi.org/10.1039/C2JM33627H.

21.

Hatamzadeh M, Jaymand M (2014) Synthesis of conductive polyaniline-modified polymers via a combination of nitroxide-mediated polymerization and “click chemistry.” RSC Adv 4:28653–28663. https://doi.org/10.1039/C4RA00864B.CrossRef

22.

Hou Y, Feng J, Wang Y, Li L (2016) Enhanced antibacterial activity of Ag-doped ZnO/polyaniline nanocomposites. J Mater Sci Mater Electron. 27:6615–6622 https://doi.org/10.1007/s10854-016-4669-0.

23.

Rai J, Randhawa GK, Kaur M (2013) Recent advances in antibacterial drugs. Int J Appl Basic Med Res 3:3–10. https://doi.org/10.4103/2229-516X.112229.CrossRefPubMedPubMedCentral

24.

Coban HB (2020) Organic acids as antimicrobial food agents: applications and microbial productions. Biopro Biosyst Eng 43:569–591. https://doi.org/10.1007/s00449-019-02256.CrossRef

25.

Verdier T, Coutand M, Bertron A, Roques CG (2014) Antibacterial Activity of TiO₂ Photocatalyst Alone or in Coatings on E. coli: The Influence of Methodological Aspects. Coatings. 4:670–686. https://doi.org/10.3390/coatings4030670

26.

Maruthapandi M, Saravanan A, Luong JHT, Gedanken A (2020) Antimicrobial Properties of Polyaniline and Polypyrrole Decorated with Zinc-Doped Copper Oxide Microparticles. Polymers 12:1286. https://doi.org/10.3390/polym12061286.CrossRefPubMedCentral

27.

Bogdanović U, Vodnik V, Mitrić M, Dimitrijević S, Škapin SD, Žunič V, Budimir M, Stoiljković M (2015) Nanomaterial with High Antimicrobial Efficacy—Copper/Polyaniline Nanocomposite. ACS Appl Mater Interfaces 7:1955–1966. https://doi.org/10.1021/am507746m.CrossRefPubMed

28.

Bhagwat AD, Sawant SS, Ankamwar BG, Mahajan CM (2015) Synthesis of Nanostructured Tin Oxide (SnO₂) Powders and Thin Films by Sol-gel Method. J Nano Electron Phy 7:04037

29.

Kumar S, Baruah S, Puzari A (2020) Poly (p-phenylenediamine)-based nanocomposites with metal oxide nanoparticle for optoelectronic and magneto-optic application. Polym Bull 77:441–457. https://doi.org/10.1007/s00289-019-02760-9.CrossRef

30.

Driscoll AJ, Bhat N, Karron RA, O’Brien KL, Murdoch DR (2012) Disk Diffusion Bioassays for the Detection of Antibiotic Activity in Body Fluids: Applications for the Pneumonia Etiology Research for Child Health Project. Clin Infect Dis 54:159–164. https://doi.org/10.1093/cid/cir1061.CrossRef

31.

Robertson J, Nikolaidis MG, Nieuwoudt MK, Swift S (2018) The antimicrobial action of polyaniline involves production of oxidative stress while functionalisation of polyaniline introduces additional mechanisms. Peer J 6:e5135. https://doi.org/10.7717/peerj.5135.CrossRefPubMed

32.

Schumacker PT (2006) Reactive oxygen species in cancer cells: Live by the sword, die by the sword. Cancer Cell 10:175–176. https://doi.org/10.1016/j.ccr.2006.08.015.CrossRefPubMed

33.

Lam PL, Wong RSM, Lam KH, Hung LK, Wong MM, Yung LH, Ho YW, Wong WY, Hau DKP, Gambari R, Chui CH (2020) The role of reactive oxygen species in the biological activity of antimicrobial agents: An updated mini review. Chem Biol Interact. 320:109023 https://doi.org/10.1016/j.cbi.2020.109023.

34.

Kurutas EB (2016) The importance of antioxidants which play the role in cellular response against oxidative/nitrosative stress: current state. Nutr J. 15:71 https://doi.org/10.1186/s12937-016-0186-5.

35.

Chen CK, Huang SC (2016) Preparation of Reductant-Responsive N-Maleoyl-Functional Chitosan/Poly(vinyl alcohol) Nanofibers for Drug Delivery. Mol Pharm 13:4152–4167. https://doi.org/10.1021/acs.molpharmaceut.6b00758.CrossRefPubMed

36.

Chen CK, Lee MC, Lin ZI, Lee CA, Tung YC, Lou CW, Law WC, Chen NT, Lin KY, Lin JH (2019) Intensifying the antimicrobial activity of poly[2-(tert-butylamino)ethyl methacrylate]/polyactide composites by tailoring their chemical and physical structures. Mol Pharm 16:709–723CrossRef

37.

Chen CK, Liao MG, Wu YL, Fang ZY, Chen JA (2020) Preparation of Highly Swelling/Antibacterial Cross-Linked N-Maleoyl-Functional Chitosan/Polyethylene Oxide Nanofiber Meshes for Controlled Antibiotic Release. Mol Pharm 17:3461–3476. https://doi.org/10.1021/acs.molpharmaceut.0c00504.CrossRefPubMed

38.

Ren Y, Mei L, Gu Y, Zhao N, Wan Y, Fan R, Tong A, Chen H, Yang H, Han B, Guo G (2019) Stereocomplex Crystallite-Based Eco-Friendly Nanofiber Membranes for Removal of Cr(VI) and Antibacterial Effects. ACS Sustain Chem Eng 7:16072–16083. https://doi.org/10.1021/acssuschemeng.9b02828.CrossRef

39.

Huang C-L, Lee K-M, Liu Z-X, Lai R-Y, Chen C-K, Chen W-C, Hsu J-F (2020) Antimicrobial Activity of Electrospun Polyvinyl Alcohol Nanofibers Filled with Poly[2-(tert-butylaminoethyl) Methacrylate]-Grafted Graphene Oxide Nanosheets. Polym 12:1449. https://doi.org/10.3390/polym12071449.CrossRef

40.

Fauchère JL, Avril JL (2002). Bactériologie générale et médicale. Ellipses éditent, Paris. 365.

Title: Physicochemical characterization of SnO2 grafted Poly p-phenylenediamine hybrid Nanocomposites and their enhanced antibacterial properties
Authors: Shyamal Baruah
Bharat Nayak
Amrit Puzari
Publication date: 01-04-2021
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 4/2021
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-021-02477-2

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 4/2021

Sulfonated poly (Ester-Urethane) / ionic liquids systems: synthesis, characterization and properties

Influences of processing conditions on the glass transition of soft poly(vinyl chloride) compounds filled with calcium carbonate

Rosin-modified o-cresol novolac based vinyl ester thermosets containing methacrylated lignin model compounds: synthesis, curing and thermo-mechanical analysis

Improving the low-temperature toughness of PPR pipe by compounding with PERT

Poly(ethylene 2,6-naphthalate) blends containing a phenylphosphonic acid salts compound with a highly enhanced crystallization rate

Kinetic and mechanistic aspects during a styrene-based Pickering emulsion polymerization: Importance of the co-aid adsorption

Premium Partners