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Published in: Metallurgical and Materials Transactions A 8/2014

01-07-2014

Powder-Route Synthesis and Mechanical Testing of Ultrafine Grain Tungsten Alloys

Authors: Zachary C. Cordero, Emily L. Huskins, Mansoo Park, Steven Livers, Megan Frary, Brian E. Schuster, Christopher A. Schuh

Published in: Metallurgical and Materials Transactions A | Issue 8/2014

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Abstract

We report a W-rich alloy (W-7Cr-9Fe, at. pct) produced by high-energy ball milling, with alloying additions that both lower the densification temperature and retard grain growth. The alloy’s consolidation behavior and the resultant compacts’ microstructure and mechanical properties are explored. Under one condition, a 98 pct dense compact with a mean grain size of 130 nm was achieved, and exhibited a hardness of 13.5 GPa, a dynamic uniaxial yield strength of 4.14 GPa in Kolsky bar experiments, and signs of structural shear localization during deformation.

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Literature
1.
go back to reference B.E. Schuster, J.P. Ligda, Z.L. Pan, and Q. Wei: JOM, 2011, vol. 63, pp. 27–31.CrossRef B.E. Schuster, J.P. Ligda, Z.L. Pan, and Q. Wei: JOM, 2011, vol. 63, pp. 27–31.CrossRef
2.
go back to reference Q. Wei, K.T. Ramesh, B.E. Schuster, L.J. Kecskes, and R.J. Dowding: JOM, 2006, vol. 58, pp. 40–44.CrossRef Q. Wei, K.T. Ramesh, B.E. Schuster, L.J. Kecskes, and R.J. Dowding: JOM, 2006, vol. 58, pp. 40–44.CrossRef
5.
go back to reference E.S. Meieran and D.A. Thomas: Trans Met Soc AIME, 1965, vol. 233, pp. 937–43. E.S. Meieran and D.A. Thomas: Trans Met Soc AIME, 1965, vol. 233, pp. 937–43.
6.
go back to reference L.J. Kecskes, K.C. Cho, R.J. Dowding, B.E. Schuster, R.Z. Valiev, and Q. Wei: Mater. Sci. Eng. A, 2007, vol. 467, pp. 33–43.CrossRef L.J. Kecskes, K.C. Cho, R.J. Dowding, B.E. Schuster, R.Z. Valiev, and Q. Wei: Mater. Sci. Eng. A, 2007, vol. 467, pp. 33–43.CrossRef
7.
go back to reference Q. Wei, H.T. Zhang, B.E. Schuster, K.T. Ramesh, R.Z. Valiev, L.J. Kecskes, R.J. Dowding, L.S. Magness Jr., and K. Cho: Acta Mater., 2006, vol. 54, pp. 4079–89.CrossRef Q. Wei, H.T. Zhang, B.E. Schuster, K.T. Ramesh, R.Z. Valiev, L.J. Kecskes, R.J. Dowding, L.S. Magness Jr., and K. Cho: Acta Mater., 2006, vol. 54, pp. 4079–89.CrossRef
8.
go back to reference A.P. Zhilyaev and T.G. Langdon: Prog. Mater. Sci., 2008, vol. 53, pp. 893–979.CrossRef A.P. Zhilyaev and T.G. Langdon: Prog. Mater. Sci., 2008, vol. 53, pp. 893–979.CrossRef
9.
10.
go back to reference Q. Wei, L.J. Kecskes, and K.T. Ramesh: Mater. Sci. Eng. A, 2013, vol. 578, pp. 394–401.CrossRef Q. Wei, L.J. Kecskes, and K.T. Ramesh: Mater. Sci. Eng. A, 2013, vol. 578, pp. 394–401.CrossRef
11.
go back to reference Q. Wei, T. Jiao, K.T. Ramesh, E. Ma, L.J. Kecskes, L.S. Magness, R.J. Dowding, V.U. Kazykhanov, and R.Z. Valiev: Acta Mater., 2006, vol. 54, pp. 77–87. Q. Wei, T. Jiao, K.T. Ramesh, E. Ma, L.J. Kecskes, L.S. Magness, R.J. Dowding, V.U. Kazykhanov, and R.Z. Valiev: Acta Mater., 2006, vol. 54, pp. 77–87.
12.
go back to reference A.K. Srivastav and B.S. Murty: J. Alloys Compd., 2012, vol. 536, Supplement 1, pp. S41–S44.CrossRef A.K. Srivastav and B.S. Murty: J. Alloys Compd., 2012, vol. 536, Supplement 1, pp. S41–S44.CrossRef
13.
go back to reference E. Oda, K. Ameyama, and S. Yamaguchi: Mater. Sci. Forum, 2006, vol. 503-504, pp. 573–78.CrossRef E. Oda, K. Ameyama, and S. Yamaguchi: Mater. Sci. Forum, 2006, vol. 503-504, pp. 573–78.CrossRef
14.
go back to reference H. Wang, Z.Z. Fang, K.S. Hwang, H. Zhang, and D. Siddle: Int. J. Refract. Met. Hard Mater., 2010, vol. 28, pp. 312–16.CrossRef H. Wang, Z.Z. Fang, K.S. Hwang, H. Zhang, and D. Siddle: Int. J. Refract. Met. Hard Mater., 2010, vol. 28, pp. 312–16.CrossRef
15.
go back to reference R. Sarkar, P. Ghosal, M. Premkumar, A.K. Singh, K. Muraleedharan, A. Chakraborti, T.P. Bagchi, and B. Sarma: Powder Metall., 2008, vol. 51, pp. 166–70.CrossRef R. Sarkar, P. Ghosal, M. Premkumar, A.K. Singh, K. Muraleedharan, A. Chakraborti, T.P. Bagchi, and B. Sarma: Powder Metall., 2008, vol. 51, pp. 166–70.CrossRef
16.
go back to reference T.S. Srivatsan, K. Manigandan, M. Petraroli, R.M. Trejo, and T.S. Sudarshan: Adv. Powder Technol., 2013, vol. 24, pp. 190–99.CrossRef T.S. Srivatsan, K. Manigandan, M. Petraroli, R.M. Trejo, and T.S. Sudarshan: Adv. Powder Technol., 2013, vol. 24, pp. 190–99.CrossRef
17.
go back to reference B.R. Klotz, F.R. Kellogg, E.M. Klier, R.J. Dowding, and K.C. Cho: Characterization, Processing, and Consolidation of Nanoscale Tungsten Powder, Army Research Laboratory, 2009. B.R. Klotz, F.R. Kellogg, E.M. Klier, R.J. Dowding, and K.C. Cho: Characterization, Processing, and Consolidation of Nanoscale Tungsten Powder, Army Research Laboratory, 2009.
18.
go back to reference K.C. Cho, R.H. Woodman, B.R. Klotz, and R.J. Dowding: Mater. Manuf. Process., 2004, vol. 19, pp. 619–30.CrossRef K.C. Cho, R.H. Woodman, B.R. Klotz, and R.J. Dowding: Mater. Manuf. Process., 2004, vol. 19, pp. 619–30.CrossRef
19.
go back to reference O. El-Atwani, D.V. Quach, M. Efe, P.R. Cantwell, B. Heim, B. Schultz, E.A. Stach, J.R. Groza, and J.P. Allain: Mater. Sci. Eng. A, 2011, vol. 528, pp. 5670–77.CrossRef O. El-Atwani, D.V. Quach, M. Efe, P.R. Cantwell, B. Heim, B. Schultz, E.A. Stach, J.R. Groza, and J.P. Allain: Mater. Sci. Eng. A, 2011, vol. 528, pp. 5670–77.CrossRef
20.
go back to reference U.K. Vashi, R.W. Armstrong, and G.E. Zima: Metall. Trans., 1970, vol. 1, pp. 1769–71.CrossRef U.K. Vashi, R.W. Armstrong, and G.E. Zima: Metall. Trans., 1970, vol. 1, pp. 1769–71.CrossRef
21.
go back to reference C. Agte and J. Vacek: Tungsten and Molybdenum, NASA Trans., 1963. C. Agte and J. Vacek: Tungsten and Molybdenum, NASA Trans., 1963.
22.
go back to reference H.H. Tian and M. Atzmon: Philos. Mag. A, 1999, vol. 79, pp. 1769–86.CrossRef H.H. Tian and M. Atzmon: Philos. Mag. A, 1999, vol. 79, pp. 1769–86.CrossRef
23.
go back to reference ASTM Standard E562-11: Test Method for Determining Volume Fraction by Systematic Manual Point Count, vol. 03.01, Annual Book of ASTM Standards, ASTM International, Materials Park, OH, 2011. ASTM Standard E562-11: Test Method for Determining Volume Fraction by Systematic Manual Point Count, vol. 03.01, Annual Book of ASTM Standards, ASTM International, Materials Park, OH, 2011.
24.
go back to reference ASTM Standard E1245-03: Practice for Determining the Inclusion or Second-Phase Constituent Content of Metals by Automatic Image Analysis, vol. 03.01, Annual Book of ASTM Standards, ASTM International, Materials Park, OH, 2008. ASTM Standard E1245-03: Practice for Determining the Inclusion or Second-Phase Constituent Content of Metals by Automatic Image Analysis, vol. 03.01, Annual Book of ASTM Standards, ASTM International, Materials Park, OH, 2008.
25.
go back to reference ASTM Standard E112-12: Test Methods for Determining Average Grain Size, vol. 03.01, Annual Book of ASTM Standards, ASTM International, Materials Park, OH, 2012. ASTM Standard E112-12: Test Methods for Determining Average Grain Size, vol. 03.01, Annual Book of ASTM Standards, ASTM International, Materials Park, OH, 2012.
26.
go back to reference W.C. Oliver and G.M. Pharr: J. Mater. Res., 2004, vol. 19, pp. 3–20.CrossRef W.C. Oliver and G.M. Pharr: J. Mater. Res., 2004, vol. 19, pp. 3–20.CrossRef
27.
go back to reference ASM Handbook: Properties and Selection: Nonferrous Alloys and Special Purpose Materials, Vol. 2, ASM International, Metals Park, OH, 1990. ASM Handbook: Properties and Selection: Nonferrous Alloys and Special Purpose Materials, Vol. 2, ASM International, Metals Park, OH, 1990.
28.
go back to reference M.D. Uchic, D.M. Dimiduk, J.N. Florando, and W.D. Nix: Science, 2004, vol. 305, pp. 986–89.CrossRef M.D. Uchic, D.M. Dimiduk, J.N. Florando, and W.D. Nix: Science, 2004, vol. 305, pp. 986–89.CrossRef
29.
go back to reference W.W. Chen and B. Song: Split Hopkinson (Kolsky) Bar Design, Testing and Applications, Springer, New York, NY, 2011.CrossRef W.W. Chen and B. Song: Split Hopkinson (Kolsky) Bar Design, Testing and Applications, Springer, New York, NY, 2011.CrossRef
30.
go back to reference T.H. Courtney and Z. Wang: Scr. Metall. Mater., 1992, vol. 27, pp. 777–82.CrossRef T.H. Courtney and Z. Wang: Scr. Metall. Mater., 1992, vol. 27, pp. 777–82.CrossRef
31.
32.
go back to reference S. Telu, A. Patra, M. Sankaranarayana, R. Mitra, and S.K. Pabi: Int. J. Refract. Met. Hard Mater., 2013, vol. 36, pp. 191–203.CrossRef S. Telu, A. Patra, M. Sankaranarayana, R. Mitra, and S.K. Pabi: Int. J. Refract. Met. Hard Mater., 2013, vol. 36, pp. 191–203.CrossRef
33.
go back to reference M.S. El-Eskandarany, K. Sumiyama, and K. Suzuki: Acta Mater., 1997, vol. 45, pp. 1175–87.CrossRef M.S. El-Eskandarany, K. Sumiyama, and K. Suzuki: Acta Mater., 1997, vol. 45, pp. 1175–87.CrossRef
34.
go back to reference C.N.J. Wagner, E. Yang, and M.S. Boldrick: Nanostructured Mater., 1996, vol. 7, pp. 1–11.CrossRef C.N.J. Wagner, E. Yang, and M.S. Boldrick: Nanostructured Mater., 1996, vol. 7, pp. 1–11.CrossRef
35.
go back to reference H.J. Fecht, E. Hellstern, Z. Fu, and W.L. Johnson: Metall. Trans. A, 1990, vol. 21, pp. 2333–37.CrossRef H.J. Fecht, E. Hellstern, Z. Fu, and W.L. Johnson: Metall. Trans. A, 1990, vol. 21, pp. 2333–37.CrossRef
36.
go back to reference R. Malewar, K.S. Kumar, B.S. Murty, B. Sarma, and S.K. Pabi: J. Mater. Res., 2007, vol. 22, pp. 1200–06.CrossRef R. Malewar, K.S. Kumar, B.S. Murty, B. Sarma, and S.K. Pabi: J. Mater. Res., 2007, vol. 22, pp. 1200–06.CrossRef
37.
go back to reference A.O. Aning, Z. Wang, and T.H. Courtney: Acta Metall. Mater., 1993, vol. 41, pp. 165–74.CrossRef A.O. Aning, Z. Wang, and T.H. Courtney: Acta Metall. Mater., 1993, vol. 41, pp. 165–74.CrossRef
38.
go back to reference D. Oleszak and P.H. Shingu: J. Appl. Phys., 1996, vol. 79, pp. 2975–80.CrossRef D. Oleszak and P.H. Shingu: J. Appl. Phys., 1996, vol. 79, pp. 2975–80.CrossRef
39.
go back to reference D.P. Xiang, L. Ding, Y.Y. Li, J.B. Li, X.Q. Li, and C. Li: Mater. Sci. Eng. A, 2012, vol. 551, pp. 95–99.CrossRef D.P. Xiang, L. Ding, Y.Y. Li, J.B. Li, X.Q. Li, and C. Li: Mater. Sci. Eng. A, 2012, vol. 551, pp. 95–99.CrossRef
40.
go back to reference U. Herr and K. Samwer: Nanostructured Mater., 1992, vol. 1, pp. 515–21.CrossRef U. Herr and K. Samwer: Nanostructured Mater., 1992, vol. 1, pp. 515–21.CrossRef
41.
go back to reference J.O. Andersson, T. Helander, L. Höglund, P. Shi, and B. Sundman: CALPHAD, 2002, vol. 26, pp. 273–312.CrossRef J.O. Andersson, T. Helander, L. Höglund, P. Shi, and B. Sundman: CALPHAD, 2002, vol. 26, pp. 273–312.CrossRef
42.
go back to reference T. Chookajorn, H.A. Murdoch, and C.A. Schuh: Science, 2012, vol. 337, pp. 951–54.CrossRef T. Chookajorn, H.A. Murdoch, and C.A. Schuh: Science, 2012, vol. 337, pp. 951–54.CrossRef
43.
go back to reference D. Peckner: The Strengthening of Metals, Reinhold, New York, 1964, pp. 93–139. D. Peckner: The Strengthening of Metals, Reinhold, New York, 1964, pp. 93–139.
44.
go back to reference R.W. Hertzberg: Deformation and Fracture Mechanics of Engineering Materials, 3rd ed., Wiley, New York, NY, 1996, pp. 8. R.W. Hertzberg: Deformation and Fracture Mechanics of Engineering Materials, 3rd ed., Wiley, New York, NY, 1996, pp. 8.
45.
go back to reference C.S. Barrett and T.B. Massalski: Structure of Metals, 3rd ed., McGraw-Hill, New York, NY, 1966, pp. 626–31. C.S. Barrett and T.B. Massalski: Structure of Metals, 3rd ed., McGraw-Hill, New York, NY, 1966, pp. 626–31.
46.
go back to reference T.J. Rupert, J.C. Trenkle, and C.A. Schuh: Acta Mater., 2011, vol. 59, pp. 1619–31.CrossRef T.J. Rupert, J.C. Trenkle, and C.A. Schuh: Acta Mater., 2011, vol. 59, pp. 1619–31.CrossRef
47.
go back to reference H.C. Lee and J. Gurland: Mater. Sci. Eng., 1978, vol. 33, pp. 125–33.CrossRef H.C. Lee and J. Gurland: Mater. Sci. Eng., 1978, vol. 33, pp. 125–33.CrossRef
48.
go back to reference E. Underwood: Quantitative Stereology, Addison-Wesley Publishing Co., Reading, MA, 1970, pp. 99-103. E. Underwood: Quantitative Stereology, Addison-Wesley Publishing Co., Reading, MA, 1970, pp. 99-103.
49.
go back to reference Z. Fan, A. P. Miodownik, and P. Tsakiropoulos: Mater. Sci. Technol., 1993, vol. 9, pp. 1094–1100.CrossRef Z. Fan, A. P. Miodownik, and P. Tsakiropoulos: Mater. Sci. Technol., 1993, vol. 9, pp. 1094–1100.CrossRef
50.
go back to reference H. Zhang, B.E. Schuster, Q. Wei, and K.T. Ramesh: Scr. Mater., 2006, vol. 54, pp. 181–86.CrossRef H. Zhang, B.E. Schuster, Q. Wei, and K.T. Ramesh: Scr. Mater., 2006, vol. 54, pp. 181–86.CrossRef
51.
go back to reference B. Butler, E. Klier, D. Casem, A. Dwivedi, M. Gallagher, and J. Hays: Demonstration of Shear Localization in Ultrafine Grained Tungsten Alloys via Powder Metallurgy Processing Route, Army Research Laboratory, 2012. B. Butler, E. Klier, D. Casem, A. Dwivedi, M. Gallagher, and J. Hays: Demonstration of Shear Localization in Ultrafine Grained Tungsten Alloys via Powder Metallurgy Processing Route, Army Research Laboratory, 2012.
52.
go back to reference A.M. Lennon and K.T. Ramesh: Mater. Sci. Eng. A, 2000, vol. 276, pp. 9–21.CrossRef A.M. Lennon and K.T. Ramesh: Mater. Sci. Eng. A, 2000, vol. 276, pp. 9–21.CrossRef
53.
go back to reference Q. Wei, K.T. Ramesh, E. Ma, L.J. Kesckes, R.J. Dowding, V.U. Kazykhanov, and R.Z. Valiev: Appl. Phys. Lett., 2005, vol. 86, pp. 101907–101909.CrossRef Q. Wei, K.T. Ramesh, E. Ma, L.J. Kesckes, R.J. Dowding, V.U. Kazykhanov, and R.Z. Valiev: Appl. Phys. Lett., 2005, vol. 86, pp. 101907–101909.CrossRef
54.
go back to reference D. Jia, K.T. Ramesh, and E. Ma: Acta Mater., 2003, vol. 51, pp. 3495–3509.CrossRef D. Jia, K.T. Ramesh, and E. Ma: Acta Mater., 2003, vol. 51, pp. 3495–3509.CrossRef
55.
go back to reference J.P. Ligda, B.E. Schuster, and Q. Wei: Scr. Mater., 2012, vol. 67, pp. 253–56.CrossRef J.P. Ligda, B.E. Schuster, and Q. Wei: Scr. Mater., 2012, vol. 67, pp. 253–56.CrossRef
56.
go back to reference J.E. Carsley, A. Fisher, W.W. Milligan, and E.C. Aifantis: Metall. Mater. Trans. A, 1998, vol. 29, pp. 2261–71.CrossRef J.E. Carsley, A. Fisher, W.W. Milligan, and E.C. Aifantis: Metall. Mater. Trans. A, 1998, vol. 29, pp. 2261–71.CrossRef
57.
go back to reference S.P. Joshi and K.T. Ramesh: Acta Mater., 2008, vol. 56, pp. 282–91.CrossRef S.P. Joshi and K.T. Ramesh: Acta Mater., 2008, vol. 56, pp. 282–91.CrossRef
58.
go back to reference S.P. Joshi and K.T. Ramesh: Mater. Sci. Eng. A, 2008, vol. 493, pp. 65–70.CrossRef S.P. Joshi and K.T. Ramesh: Mater. Sci. Eng. A, 2008, vol. 493, pp. 65–70.CrossRef
Metadata
Title
Powder-Route Synthesis and Mechanical Testing of Ultrafine Grain Tungsten Alloys
Authors
Zachary C. Cordero
Emily L. Huskins
Mansoo Park
Steven Livers
Megan Frary
Brian E. Schuster
Christopher A. Schuh
Publication date
01-07-2014
Publisher
Springer US
Published in
Metallurgical and Materials Transactions A / Issue 8/2014
Print ISSN: 1073-5623
Electronic ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-014-2286-1

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