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29-01-2022 | Original Paper

Preparation and improved properties (electrical, mechanical and microwave absorption) of graphene/ZnO/XNBR nanocomposites

Authors: Che-Kuan Lin, Tse-Ming Huang, Jia-Hao Liu, Jing-Wen Tu, Yun-Ting Liu, Wen-Yen Hsieh, Jia-Huang Chang, Ren-Jang Wu, Murthy Chavali

Published in: Polymer Bulletin | Issue 1/2023

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Abstract

A preparation route to fabricate high-performance graphene/rubber elastic nanocomposites was developed by combining the plasma-assisted electrical chemical exfoliation of graphite (PEG) in liquid phase with carboxylated butadiene acrylonitrile latex (XNBR). The dispersion and adhesion of PEG in the XNBR rubber matrix were considerably improved after interfacial modification due to forming the segregated 3D structure via the covalent bonding interactions between modified PGE nanosheets and XNBR particles. The stable and segregated 3D structure endowed the graphene reinforced XNBR nanocomposites with obviously enhanced electrical conductivity to the maximum of 4.67*10⁻² S/m and strengthened the multiple mechanical performances at the same time. In addition, the microwave adsorption characteristics were also better than the pure XNBR matrix when the modified PEG nanosheets were added. Finally, the morphology of the reinforced XNBR nanocomposites was analyzed by Fourier transform infrared spectra, Raman spectra, X-ray diffraction, scanning electron microscopy and transmission electron microscopy. This simple and effective strategy provides another inspiration for the preparation of high-performance graphene-filled rubber nanocomposites.

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Title: Preparation and improved properties (electrical, mechanical and microwave absorption) of graphene/ZnO/XNBR nanocomposites
Authors: Che-Kuan Lin
Tse-Ming Huang
Jia-Hao Liu
Jing-Wen Tu
Yun-Ting Liu
Wen-Yen Hsieh
Jia-Huang Chang
Ren-Jang Wu
Murthy Chavali
Publication date: 29-01-2022
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 1/2023
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-021-04057-2

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