Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Polymer Bulletin
Published in: Polymer Bulletin 1/2023

29-01-2022 | Original Paper

Mercuric (II) up-taking from industrial wastewater based on poly(aniline-co-N-(2-hydroxyethyl)aniline as new sorbent

Authors: M. M. Rabee, H. M. Abd El-Salam

Published in: Polymer Bulletin | Issue 1/2023

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The presence of Hg+2 in industrial wastewater is considered a big environmental problem. So the removal of Hg+2 is important target. Polymeric materials especially polyaniline and its derivatives have a unique properties. Poly(aniline-co-N-(2-hydroxyethyl) aniline) (P(ANI-co-NHEANI)) as a new sorbent for Hg+2 was synthesized by oxidative chemical polymerization of N-(2-hydroxyetyl) aniline)/aniline binary mixture. Polymerization was performed in aqueous HCl solutions using ammonium persulphate (APS) as oxidant under nitrogen atmosphere at 5 °C. The optimum conditions of the copolymerization based on copolymer yield were present. The obtained P(ANI-co-NHEANI) was characterized by IR, SEM, XRD and TGA to investigate both structure and morphology of the obtained copolymer. The efficiency of the prepared P(ANI-co-NHEANI) sample to remove Hg+2 from contaminated industrial wastewater was studied. The obtained data reveal that the synthesized P(ANI-co-NHEANI) has a good efficiency towards the removal of Hg+2 (90.9% which can be closed to 100% with increasing both time and dose), some adsorption models were applied. In addition, adsorption kinetic models were investigated. The fitting of the obtained data shows both chemical and physical adsorption of Hg+2. The remained Hg(II) was measured via Atomic Fluoresces Spectrophotometer.
previous article Preparation and characterization of nanocomposite membranes based on PVC/TiO2 anatase for the separation of toluene/n-heptane mixtures via pervaporation
next article Preparation and improved properties (electrical, mechanical and microwave absorption) of graphene/ZnO/XNBR nanocomposites

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
Nasar A, Mashkoor F (2019) Application of polyaniline-based adsorbents for dye removal from water and wastewater—a review. Environ Sci Pollut 26:5333–5356CrossRef
2.
Donde OO (2017) Wastewater management techniques: a review of advancement on the appropriate wastewater treatment principles for sustainability. Environ Manag Sustain Dev 6:40–58CrossRef
3.
Tariq W, Saifullah M, Anjum T, Javed M, Tayyab N, Shoukat I (2018) Removal of heavy metals from chemical industrial wastewater using agro based bio-sorbents. Acta Chem Malays (ACMY) 2(2):09–14
4.
Barakat MA (2011) New trends in removing heavy metals from industrial wastewater. Arab J Chem 4:361–377CrossRef
5.
Corns WT, Stockwell PB, Ebdon L, Hill SJ (1993) Development of an atomic fluorescence spectrometer for the hydride forming elements. J Anal At Spectrom 8:71–77CrossRef
6.
Dada AO, Olalekan AP, Olatunya AM, Dada O (2012) Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice husk. IOSR J Appl Chem 3(1):38–45CrossRef
7.
Eisazadeh H (2008) Removal of arsenic in water using polypyrrole and its composites. World Appl Sci J 3(1):10–13
8.
Mon M, Lloret F, Ferrando-Soria J, Mart-Gastaldo C, Armentano D, Pardo E (2016) Selective and efficient removal of mercury from aqueous media with the highly flexible arms of a BioMOF. Angew Chem Int Ed 55:11167–11172CrossRef
9.
Ghaffarpour D, Ghorbani M (2015) Removal of mercury ions by polyaniline/rice husk nanocomposite from aqueous solutions. Int J Sci Res Environ Sci 3(8):0274–0283
10.
Huang S, Ma C, Liao Y, Min C, Ping Du, Jiang Y (2016) Removal of mercury(II) from aqueous solutions by adsorption on poly(1-amino-5-chloroanthraquinone) nanofibrils: equilibrium Kinetics, and Mechanism Studies. J Nanomater 2016:1–11CrossRef
11.
Morsi RE, Elsabee MZ (2015) Polyaniline nanotubes: mercury and competative heavy metals uptake. Am J Polym Sci 5(1):10–17
12.
Ansari R, Raofie F (2006) Removal of mercuric ion from aqueous solutions using sawdust coated by polyaniline. E-J Chem 3(1):35–43CrossRef
13.
Tshemesea SJ, Mlaba TT, Tichapondwa SM, Mhike W (2020) Removal of chromium (VI) from aqueous solution using exfoliated graphite/polyaniline composite. Chem Eng Trans 81:565–570
14.
Ghorbani M, Eisazadeh H, Ghoreysh AA (2012) Removal of zinc ions from aqueous solution using polyaniline nanocomposite coated on rice husk. Iran J Energy Environ 3(1):66–71CrossRef
15.
Abdolahi A, Hamzah E, Ibrahim Z, Hashim S (2012) Synthesis of uniform polyaniline nanofibers through interfacial polymerization. Materials 5:1487–1494CrossRef
16.
Lashkenari MS, Davodi B, Eisazadeh H (2011) Removal of arsenic from aqueous solution using polyaniline/rice husk nanocomposite. Korean J Chem Eng 28(7):1532–1538CrossRef
17.
18.
Kong Y, Wei J, Wang Z, Sun T, Yao C, Chen Z (2011) Heavy metals removal from solution by polyaniline/palygorskite composite. J Appl Polym Sci 122:2054–2059CrossRef
19.
German N, Ramanaviciene A, Ramanavicius A (2019) Formation of polyaniline and polypyrrole nanocomposites with embedded glucose oxidase and gold nanoparticles. Polymers 11(2):377–390CrossRef
20.
Ansari R, Feizy J, Delavar AF (2008) Removal of arsenic ions from aqueous solutions using conducting polymers. E-J Chem 5(4):853–863CrossRef
21.
Al-Daghman ANJ (2019) Optical properties of conducting polyaniline doped by H2SO4. J Sci Eng Res 6(1):50–54
22.
Abd El-Salam HM, Mohamed RA, Shokry A (2017) Preparation and characterization of novel and selective polyacrylamide-graft-poly(2-methoxyaniline) adsorbent for lead removal. Polym Bull 75:3189–3210CrossRef
23.
Belalia A, Zehhaf A, Benyoucef A (2018) Preparation of hybrid material based of PANI with SiO2 and its adsorption of phenol from aqueous solution. Polym Sci Ser B 60:816–824CrossRef
24.
Zhou Q, Wang J, Liao X, Xiao J, Fan H (2015) Removal of As(III) and As(V) from water using magnetic core-shell nanomaterial Fe3O4@polyaniline. Int J Green Technol 1:54–64CrossRef
25.
Abu Taleb Md, Kumar R, Al-Rashdib AA, Seliem MK, Barakat MA (2020) Fabrication of SiO2/CuFe2O4/polyaniline composite: a highly efficient adsorbent for heavy metals removal from aquatic environment. J Pre-proofs 13(10):7533–7543
26.
Pasela BR, Castillo AP, Simon R, Pulido MT, Mana-ay H, Roxan Abiquibil Ma, Montecillo R, Thumanu K, von Tumacder D, Taaca KL (2019) Synthesis and characterization of acetic acid-doped polyaniline and polyaniline-chitosan composite. Biomimetics 4(1):1–16CrossRef
27.
Boeva ZA, Sergeyev VG (2014) Polyaniline: synthesis properties, and application. Polym Sci Ser 56(1):153–164
28.
Molapo KM, Ndangili PM, Ajayi RF, Mbambisa G, Mailu SM, Njomo N, Masikini M, Baker P, Iwuoha EI (2012) Electronics of conjugated polymers (I): polyaniline. Int J Electrochem Sci 7:11859–11875
29.
Trchova M, Moravkova Z, Šeděnkova I, Stejskal J (2012) Spectroscopy of thin polyaniline films deposited during chemical oxidation of aniline. Chem Pap Slovak Acad Sci 66(5):415–445
30.
31.
Liao G, Lib Q, Xuc Z (2019) The chemical modification of polyaniline with enhanced properties: a review. Prog Org Coat 126:35–43CrossRef
32.
Chandrasekaran K, BalaramaKrishna MV, Karunasagar D (2010) On-line speciation of inorganic arsenic in natural waters using polyaniline (PANI) with determination by flow injection-hydride generation-inductively coupled plasma mass spectrometry at ultra-trace levels. J Anal At Spectrom 25:1348–1353CrossRef
33.
Hussi H, Gan SN, Mohamad S, Phang SW (2010) Synthesis of water-soluble polyaniline by using different types of cellulose derivatives. Polym Polym Compos 25(7):515–520
34.
Yonehara T, Komaba K, Goto H (2020) Synthesis of polyaniline in seawater. Polymers 12(2):375CrossRef
35.
Zoromba MS, Ismail MIM, Bassyouni M, Abdel-Aziz MH, Salah N, Alshahrie A, Memic A (2017) Fabrication and characterization of poly (aniline-co-o-anthranilic acid)/magnetite nanocomposites and their application in wastewater treatment. Coll Surf A Physicochem Eng Asp 520:121–130CrossRef
36.
37.
Bayramoglu G, Yakup Arica M, Bektas S (2007) Removal of Cd(II), Hg(II), and Pb(II) ions from aqueous solution using p(HEMA/Chitosan) membranes. Wiley Int Sci 106:169177
38.
Soltani H, Belmokhtar A, Zeggai FZ, Benyoucef A, Bousalem S, Bachari K (2019) Copper(II) removal from aqueous solutions by PANI-clay hybrid material: fabrication, characterization, adsorption and kinetics study. J Inorg Organometal Polym Mater 29:841–850CrossRef
39.
Zulfiqar M, Lee SY, Mafize AA, Kahar NAMA, Johari K, Rabat NE (2020) E_cient removal of Pb(II) from aqueous solutions by using oil palm bio-waste/MWCNTs reinforced PVA hydrogel composites: kinetic isotherm and thermodynamic modeling. Polymers 12(2):430–459CrossRef
40.
Agrawal S, Singh NB (2016) Removal of arsenic from aqueous solutions by an adsorbent nickel ferrite-polyaniline nanocomposite. Indian J Chem Technol 23:374–383
41.
Zia Z, Hartland A, Mucalo MR (2020) Use of low-cost biopolymers and biopolymeric composite systems for heavy metal removal from water. Int J Environ Sci Technol 17:4389–4406CrossRef
42.
Yang J, Hou B, Wang J, Tian B, Bi J, Wang Na, Li X, Huang X (2019) Nanomaterials for the removal of heavy metals from wastewater. Nanomaterials 9:424–461CrossRef
43.
Mahmud HNME, Huq AKO, Yahya R (2017) Polymer-based adsorbent for heavy metals removal from aqueous solution. Mater Sci Eng 10:1088–1757
44.
Edet UA, Ifelebuegu AO (2020) Kinetics isotherms, and thermodynamic modeling of the adsorption of phosphates from model wastewater using recycled brick waste. Processes 8:665–680CrossRef
45.
Chai LY, Wang QW, Wang YY, Li QZ, Yang ZH, Shu YD (2010) Thermodynamic study on reaction path of Hg(II) with S(II) in solution. J Cent South Univ Technol 17:289–294CrossRef
Metadata
Title
Mercuric (II) up-taking from industrial wastewater based on poly(aniline-co-N-(2-hydroxyethyl)aniline as new sorbent
Authors
M. M. Rabee
H. M. Abd El-Salam
Publication date
29-01-2022
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 1/2023
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-021-04045-6

Other articles of this Issue 1/2023

Polymer Bulletin 1/2023 Go to the issue

Original Paper

Preparation of UV-LED curable antifouling and flame retardant superhydrophobic coatings for polyethylene terephthalate surface protection

Original Paper

Effect of Cu@polythiophene yolk–shell nanofiller on the electrical, mechanical and thermal properties of poly(vinyl alcohol) thin films

Original Paper

Effect of alkali treatment on tensile strength of epoxy composite reinforced with coir fiber

Review Paper

A review on polymeric nanomaterials intervention in food industry

Original Paper

Green synthesis, characterisation and antibacterial activity studies of new multifunctional nano polymeric material, which may have multidimensional application in water purification

Original Paper

Synthesis, curing and thermal properties of the low melting point phthalonitrile resins containing glycidyl groups

Premium Partners

    Image Credits