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Polymer Bulletin
Published in: Polymer Bulletin 1/2023

27-01-2022 | Original Paper

Self-aggregate performance of hexyl alginate ester derivative synthesized via SN2 reaction for controlled release of λ-cyhalothrin

Authors: Xiuqiong Chen, Qingmei Zhu, Zhaowen Liu, Tong Zhang, Cuiyu Gong, Juan Li, Huiqiong Yan, Qiang Lin

Published in: Polymer Bulletin | Issue 1/2023

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Abstract

To change the strong hydrophilicity of alginate and make it have good amphiphilic property, thereby broadening its application as a new pesticide-controlled release system, the hexyl alginate ester derivative (HAED) was synthesized by the bimolecular nucleophilic substitution (SN2) reaction, using 1-bromohexane as the hydrophobic modifier. The structure and self-aggregate performance of the synthesized HAED were contrastively characterized. Moreover, the loading and release performance of λ-Cyhalothrin (LCH) for the HAED microcapsules prepared by the high-speed shearing method was also studied. The synthesized HAED exhibited enhanced molecular flexibility and good self-aggregate performance, which could form the stable self-aggregated spherical micelles with the average hydrodynamic diameter and zeta potential of 416 nm (PDI = 0.29) and − 39.9 mV, respectively, due to the intra- or intermolecular hydrophobic associations. Furthermore, the obtained HAED microcapsules displayed the high encapsulation efficiency and sustained-release property in comparison with the SA microcapsules for the good affinity of HAED to hydrophobic LCH that retarded the drug diffusion. On the basis of the excellent advantages of HAED, it was expected to become the ideal candidate for hydrophobic drug delivery in controlled-release pesticide formulations.
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Metadata
Title
Self-aggregate performance of hexyl alginate ester derivative synthesized via SN2 reaction for controlled release of λ-cyhalothrin
Authors
Xiuqiong Chen
Qingmei Zhu
Zhaowen Liu
Tong Zhang
Cuiyu Gong
Juan Li
Huiqiong Yan
Qiang Lin
Publication date
27-01-2022
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 1/2023
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-022-04103-7

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