Skip to main content
Top
Published in: Cellulose 1/2018

10-11-2017 | Original Paper

Preparation of Eucalyptus pulp by mild condition of low-temperature, atmospheric pressure, and short-reaction-time with high-boiling-point solvent and pulp properties

Authors: Kang-Jae Kim, Sung-Bum Hong, Tae-Jin Eom

Published in: Cellulose | Issue 1/2018

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Chemical pulp was prepared by the low-temperature, atmospheric pressure, and short reaction time pulping of Eucalyptus wood chips using a high-boiling-point solvent. The pulping conditions and pulp properties were evaluated. After the digestion of the Eucalyptus chips, pulp containing 6% residual lignin was obtained in 59.6% yield. It exhibited a low shive content and a sufficiently pulped appearance. With subsequent digestion at 110 °C for 60 min, the shive content further decreased, and fiber bundles disintegrated by simple mechanical stirring. The fiber length and width of the pulp were 500–577 and 20.1–27.9 μm, respectively, and the fiber roughness was 8.8–16.8 mg/100 m. The degree of crystallization of the pulp proportionally increased with cooking temperature. The brightness of the pulp with ~ 6% residual lignin content was greater than 52% ISO, and the zero-span tensile strength and viscosity gradually increased with pulping time.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literature
go back to reference Ahn EB, Hong SB, Kim KJ, Eom TJ (2015) Micro-fibrillated cellulose preparation with enzyme beating pretreatment and effect on paper strength improvement. J Korea TAPPI 47(6):57–65 Ahn EB, Hong SB, Kim KJ, Eom TJ (2015) Micro-fibrillated cellulose preparation with enzyme beating pretreatment and effect on paper strength improvement. J Korea TAPPI 47(6):57–65
go back to reference Alaejos J, López F, Eugenio ME, Tapias R (2006) Soda-anthraquinone, kraft and organosolv pulping of holm oak trimmings. Biores Technol 97:2110–2116CrossRef Alaejos J, López F, Eugenio ME, Tapias R (2006) Soda-anthraquinone, kraft and organosolv pulping of holm oak trimmings. Biores Technol 97:2110–2116CrossRef
go back to reference Ali M, Emsley AM, Herman H, Heywood RJ (2001) Spectroscopic studies of the ageing of cellulosic paper. Polymer 42(7):2893–2900CrossRef Ali M, Emsley AM, Herman H, Heywood RJ (2001) Spectroscopic studies of the ageing of cellulosic paper. Polymer 42(7):2893–2900CrossRef
go back to reference Aziz S, Sarkanen K (1989) Organosolv pulping—a review. Tappi J 72(3):169–175 Aziz S, Sarkanen K (1989) Organosolv pulping—a review. Tappi J 72(3):169–175
go back to reference Dahlmann G, Schroeter MC (1990) The organocell process—pulping with the environment in mind. Tappi J 73(4):237–240 Dahlmann G, Schroeter MC (1990) The organocell process—pulping with the environment in mind. Tappi J 73(4):237–240
go back to reference Eom TJ, Kim KJ (2015) Process for separating Lignocellulose components by using aliphatic glycol ether. Patent #KR1015264390000 Eom TJ, Kim KJ (2015) Process for separating Lignocellulose components by using aliphatic glycol ether. Patent #KR1015264390000
go back to reference Gierer J (1985) Chemistry of delignification part 1: general concept and reactions during pulping. Wood Sci Technol 19(4):289–312 Gierer J (1985) Chemistry of delignification part 1: general concept and reactions during pulping. Wood Sci Technol 19(4):289–312
go back to reference Gustafson RR, Sleicher CA, Mckean WT, Finlayson BA (1983) Theoretical model of the Kraft pulping process. I&EC Process Des Dev 22:87–96CrossRef Gustafson RR, Sleicher CA, Mckean WT, Finlayson BA (1983) Theoretical model of the Kraft pulping process. I&EC Process Des Dev 22:87–96CrossRef
go back to reference Hong SB, Jung SE, Kim KJ, Eom TJ (2016a) Characteristics of organosolv pulping method by high boiling point solvents. Pan Pacific Conf 2016:200–201 Hong SB, Jung SE, Kim KJ, Eom TJ (2016a) Characteristics of organosolv pulping method by high boiling point solvents. Pan Pacific Conf 2016:200–201
go back to reference Hong SB, Kim KJ, Eom TJ (2016b) Delignification of pine wood meals using high boiling point solvents and acidic catalysts. J Korea TAPPI 48(6):119–126 Hong SB, Kim KJ, Eom TJ (2016b) Delignification of pine wood meals using high boiling point solvents and acidic catalysts. J Korea TAPPI 48(6):119–126
go back to reference Huang Y, Wang L, Chao Y, Nawawi DS, Akiyama T, Yokoyama T, Matsumoto Y (2012) Analysis of lignin aromatic structure in wood based on the IR spectrum. J Wood Chem Technol 32(4):294–303CrossRef Huang Y, Wang L, Chao Y, Nawawi DS, Akiyama T, Yokoyama T, Matsumoto Y (2012) Analysis of lignin aromatic structure in wood based on the IR spectrum. J Wood Chem Technol 32(4):294–303CrossRef
go back to reference International Standard Organization (ISO) (2010) Pulps-determination of limiting viscosity number in cupriethylenediamine (CED) solution. 5351:2010(E) International Standard Organization (ISO) (2010) Pulps-determination of limiting viscosity number in cupriethylenediamine (CED) solution. 5351:2010(E)
go back to reference Johansson A, Aaltonen O, Ylinen P (1987) Organosolv pulping-methods and pulp properties. Biomass 13(1):45–65CrossRef Johansson A, Aaltonen O, Ylinen P (1987) Organosolv pulping-methods and pulp properties. Biomass 13(1):45–65CrossRef
go back to reference Kajimoto J, Sano Y (2001) HBS pulping (3)—accelerated effect of RHBS on delignification. Jpn TAPPI J 55(10):114–123CrossRef Kajimoto J, Sano Y (2001) HBS pulping (3)—accelerated effect of RHBS on delignification. Jpn TAPPI J 55(10):114–123CrossRef
go back to reference Kajimoto J, Sano Y, Widodo WE, Kishimoto T, Uraki Y (2000) HBS pulping (1)—pulping of softwood. Jpn TAPPI J 54(9):88–95CrossRef Kajimoto J, Sano Y, Widodo WE, Kishimoto T, Uraki Y (2000) HBS pulping (1)—pulping of softwood. Jpn TAPPI J 54(9):88–95CrossRef
go back to reference Kim KJ, Jung JD, Jung SE, Hong SB, Eom TJ (2016) Delignification of lignocellulosic biomass with high-boiling point solvent and acidic catalyst. J Korea TAPPI 48(1):119–126 Kim KJ, Jung JD, Jung SE, Hong SB, Eom TJ (2016) Delignification of lignocellulosic biomass with high-boiling point solvent and acidic catalyst. J Korea TAPPI 48(1):119–126
go back to reference Neiva D, Fernandes L, Araújo S, Lourenço A, Gominho J, Simões R, Pereira H (2015) Chemical composition and kraft pulping potential of 12 eucalypt species. Ind Crops Prod 66:89–95CrossRef Neiva D, Fernandes L, Araújo S, Lourenço A, Gominho J, Simões R, Pereira H (2015) Chemical composition and kraft pulping potential of 12 eucalypt species. Ind Crops Prod 66:89–95CrossRef
go back to reference Roncero MB, Torres AL, Colom JF, Vidal T (2000) Effect of xylanase treatment on fibre morphology in totally chlorine free bleaching (TCF) of Eucalyptus pulp. Process Biochem 36(1–2):45–50CrossRef Roncero MB, Torres AL, Colom JF, Vidal T (2000) Effect of xylanase treatment on fibre morphology in totally chlorine free bleaching (TCF) of Eucalyptus pulp. Process Biochem 36(1–2):45–50CrossRef
go back to reference Schrems M, Liebner F, Betz N, Zeilinger M, Böhmdorfer S, Rosenau T, Potthast A (2012) Understanding the impact of supercritical carbon dioxide on the delignification mechanism during organosolv pulping: a model compound study. J Wood Chem Technol 32(3):225–234CrossRef Schrems M, Liebner F, Betz N, Zeilinger M, Böhmdorfer S, Rosenau T, Potthast A (2012) Understanding the impact of supercritical carbon dioxide on the delignification mechanism during organosolv pulping: a model compound study. J Wood Chem Technol 32(3):225–234CrossRef
go back to reference Schroeter MC (1991) Possible lignin reactions in the organocell pulping process. Tappi J 74(10):197–200 Schroeter MC (1991) Possible lignin reactions in the organocell pulping process. Tappi J 74(10):197–200
go back to reference Yousef MA, Shabaka AA, Nada AMA, AbdEl-Nour KN (1991) Physical properties and IR spectroscopy of thermally treated bagasse paper sheets. Indian J Pure Appl Phys 29:6–8 Yousef MA, Shabaka AA, Nada AMA, AbdEl-Nour KN (1991) Physical properties and IR spectroscopy of thermally treated bagasse paper sheets. Indian J Pure Appl Phys 29:6–8
go back to reference Zhao X, Li S, Wu R, Liu D (2017) Organosolv fractionating pre-treatment of lignocellulosic biomass for efficient enzymatic saccharification: chemistry, kinetics, and substrate structures. Biofuels Bioprod Biorefin 11(3):567–590CrossRef Zhao X, Li S, Wu R, Liu D (2017) Organosolv fractionating pre-treatment of lignocellulosic biomass for efficient enzymatic saccharification: chemistry, kinetics, and substrate structures. Biofuels Bioprod Biorefin 11(3):567–590CrossRef
Metadata
Title
Preparation of Eucalyptus pulp by mild condition of low-temperature, atmospheric pressure, and short-reaction-time with high-boiling-point solvent and pulp properties
Authors
Kang-Jae Kim
Sung-Bum Hong
Tae-Jin Eom
Publication date
10-11-2017
Publisher
Springer Netherlands
Published in
Cellulose / Issue 1/2018
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-017-1564-7

Other articles of this Issue 1/2018

Cellulose 1/2018 Go to the issue