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Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 2/2016

01-08-2016 | Original Paper: Functional coatings, thin films and membranes (including deposition techniques)

Preparation of Zn–Al layered double hydroxide thin films intercalated with Eosin Y by hot water treatment of sol-gel derived precursor films

Authors: Kiyoharu Tadanaga, Jun-ichiro Oi, Mikio Higuchi

Published in: Journal of Sol-Gel Science and Technology | Issue 2/2016

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Abstract

Zn–Al layered double hydroxide (LDH) thin films intercalated with Eosin Y were prepared by the sol-gel method with hot water treatment. Sol-gel derived amorphous Al2O3–ZnO thin films were immersed in hot water containing Eosin Y. Extended interlayer spacing, in comparison with the Zn–Al LDH with carbonate anions, was observed after immersion in distilled water containing 5 mM Eosin Y at 100 °C for 30 min, indicating that crystals of Zn–Al LDH intercalated with Eosin Y were precipitated on the precursor film. Intercalated Eosin Y was confirmed to have high thermal durability compared with Eosin Y adsorbed on the LDH surface. A cell consisting of the heat-treated thin film of Zn–Al LDH intercalated with Eosin Y on fluorine-doped tin oxide (FTO)-coated glass, triiodide/iodide electrolyte, and Pt-loaded FTO glass was confirmed to work as a solar cell under visible light irradiation.

Graphical Abstract

Zn–Al layered double hydroxide thin films intercalated with Eosin Y were prepared by the sol-gel method with hot water treatment. Intercalated Eosin Y is confirmed to have high thermal durability.
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Metadata
Title
Preparation of Zn–Al layered double hydroxide thin films intercalated with Eosin Y by hot water treatment of sol-gel derived precursor films
Authors
Kiyoharu Tadanaga
Jun-ichiro Oi
Mikio Higuchi
Publication date
01-08-2016
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 2/2016
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-016-4001-8

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