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Journal of Sol-Gel Science and Technology

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05-02-2018 | Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

Selective catalytic reduction of NO_x by CO over LaMnO₃ nano perovskites prepared by microwave and ultrasound assisted sol–gel method

Authors: Seyed Ali Hosseini, Behrouz Mehri, Aligholi Niaei, Behrang Izadkhah, Consuelo Alvarez-Galvan, Jose G. Luis Fierro

Published in: Journal of Sol-Gel Science and Technology | Issue 3/2018

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Abstract

A series of LaMnO₃ perovskites as catalysts for selective reduction of NO by CO were synthesized using microwave and ultrasound assisted sol-gel method. The catalysts were characterized by BET area measurements, Scanning Electron Microscopy (SEM), X-Ray diffraction (XRD) and X-ray Photoelectron Spectroscopy (XPS) techniques. XRD results showed revealed the orthorhobic crystalline structure and with very high purity. SEM analyses proved lower particle size for ultrasound (US) assisted synthesized LaMnO₃. In addition, US assisted synthesized LaMnO₃ presented higher surface area respect to other catalysts, synthesized by the other methods. Results revealed that the ultrasound assisted synthesized catalyst determines the lowest crystallite size, the highest surface area and the highest concentration of O-vacancies and, as a consequence, the highest catalytic activity.

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Title: Selective catalytic reduction of NO x by CO over LaMnO3 nano perovskites prepared by microwave and ultrasound assisted sol–gel method
Authors: Seyed Ali Hosseini
Behrouz Mehri
Aligholi Niaei
Behrang Izadkhah
Consuelo Alvarez-Galvan
Jose G. Luis Fierro
Publication date: 05-02-2018
Publisher: Springer US
Published in: Journal of Sol-Gel Science and Technology / Issue 3/2018
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-017-4568-8

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