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Journal of Coatings Technology and Research

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19-07-2021

Synthesis and properties of phosphorus-containing cardanol-based acrylates for flame-retardant UV/EB-cured coatings

Authors: Zhuoyuan Gu, Yinpeng Nan, Yue Zhang, Jiafeng Huang, Jingcheng Liu

Published in: Journal of Coatings Technology and Research | Issue 5/2021

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Abstract

In this article, two kinds of phosphorus-containing cardanol-based acrylates were designed and synthesized. Firstly, a pre-polymer (PT-HCE) with three arms was synthesized using hydroxyethyl cardanol ether (HCE) and phosphorus oxychloride (POCl₃) as raw materials. Then, the PT-HCE was acrylated to synthesize phosphate tris-hydroxyethyl cardanol epoxy acrylate resin (AEPT-HCE) and phosphate tris-hydroxyethyl cardanol photosensitive resin (APT-HCE). The structures of PT-HCE, AEPT-HCE and APT-HCE were characterized and the results showed that the photosensitive resins were successfully synthesized. In addition, AEPT-HCE and APT-HCE were used to prepare the flame-retardant UV/EB curing coatings. The properties of the coatings were tested, and the results revealed that different structures have a certain effect on T_g and tensile properties of the coatings. The cured films demonstrated excellent flame-retardant properties, showing flammability rating of V-0 in UL-94 test.

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Title: Synthesis and properties of phosphorus-containing cardanol-based acrylates for flame-retardant UV/EB-cured coatings
Authors: Zhuoyuan Gu
Yinpeng Nan
Yue Zhang
Jiafeng Huang
Jingcheng Liu
Publication date: 19-07-2021
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 5/2021
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-021-00500-1

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