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Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 7/2015

01-07-2015

Temperature effect on electrochemical properties of Ti4O7 electrodes prepared by spark plasma sintering

Authors: Jinwen Ye, Guangrui Wang, Xiaolei Li, Ying Liu, Ruijie Zhu

Published in: Journal of Materials Science: Materials in Electronics | Issue 7/2015

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Abstract

In this paper, Magnéli phase Ti4O7 powders were successfully synthesized and used to fabricate high quality Ti4O7 electrodes by the spark plasma sintering (SPS) technique. The micro-structure, conductivity and electrochemical properties of the Ti4O7 electrode were investigated respectively. Furthermore, temperature’s effect on the electrochemical properties of Ti4O7 working electrode was studied by the cyclic voltammetry measurements under strong sulfuric acid and alkaline conditions at different temperature to simulate actual operating temperature in various electrolyte such as in lead–acid or zinc–air batteries. The results showed that Ti4O7 electrodes prepared by SPS without doping of adhesives had high conductivity, favorable electrochemical activities in function of temperature and electrochemical stability under strong sulfuric acid and alkaline conditions. It would be feasible candidate to bipolar lead–acid battery and used as air cathodes in zinc–air batteries.
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Metadata
Title
Temperature effect on electrochemical properties of Ti4O7 electrodes prepared by spark plasma sintering
Authors
Jinwen Ye
Guangrui Wang
Xiaolei Li
Ying Liu
Ruijie Zhu
Publication date
01-07-2015
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 7/2015
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-015-2838-1

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