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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 7/2015

01.07.2015

Temperature effect on electrochemical properties of Ti4O7 electrodes prepared by spark plasma sintering

verfasst von: Jinwen Ye, Guangrui Wang, Xiaolei Li, Ying Liu, Ruijie Zhu

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 7/2015

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Abstract

In this paper, Magnéli phase Ti4O7 powders were successfully synthesized and used to fabricate high quality Ti4O7 electrodes by the spark plasma sintering (SPS) technique. The micro-structure, conductivity and electrochemical properties of the Ti4O7 electrode were investigated respectively. Furthermore, temperature’s effect on the electrochemical properties of Ti4O7 working electrode was studied by the cyclic voltammetry measurements under strong sulfuric acid and alkaline conditions at different temperature to simulate actual operating temperature in various electrolyte such as in lead–acid or zinc–air batteries. The results showed that Ti4O7 electrodes prepared by SPS without doping of adhesives had high conductivity, favorable electrochemical activities in function of temperature and electrochemical stability under strong sulfuric acid and alkaline conditions. It would be feasible candidate to bipolar lead–acid battery and used as air cathodes in zinc–air batteries.
Vorheriger Artikel Electronic control of magnonic and spintronic devices
Nächster Artikel High temperature optical absorption investigation into the electronic transitions in sol–gel derived C12A7 thin films

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Metadaten
Titel
Temperature effect on electrochemical properties of Ti4O7 electrodes prepared by spark plasma sintering
verfasst von
Jinwen Ye
Guangrui Wang
Xiaolei Li
Ying Liu
Ruijie Zhu
Publikationsdatum
01.07.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 7/2015
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-015-2838-1

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