Skip to main content
Top
Published in: Rare Metals 3/2019

04-07-2018

Temperature stability of SmCo (2:17) magnets modified by Ni–Cr two-layer coating

Authors: Saira Bibi, Jing-Min Wang, M. Faisal Rathore, Cheng-Bao Jiang

Published in: Rare Metals | Issue 3/2019

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The oxidation resistance behavior of SmCo (2:17)-type high-temperature magnets modified with Ni–Cr two-layer coating was studied. The study depicts the mass gain kinetics and magnetic properties of uncoated and Ni–Cr-modified magnets oxidized at high temperature (500 °C) in air for 200 h. The oxidation test results illustrate that the mass gain of uncoated magnet is 6.95 mg·cm−2 which is more than that (0.08 mg·cm−2) of coated magnet after 200 h. For the magnetic properties concerned, there is a great loss for uncoated magnet, while for coated magnet, magnetic properties do not change much. The study of uncoated magnet through X-ray diffraction (XRD) and electron probe microanalysis (EPMA) shows that the invasion of oxygen at high temperature leads to the loss of magnetic properties by changing the microstructure of magnet.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
[1]
go back to reference Tang W, Zhang Y, Hadjipanayis GC. Microstructure and magnetic properties of Sm(CobalFexCu0.128Zr0.02)7.0 magnets with Fe substitution. J Magn Magn Mater. 2000;221(3):268.CrossRef Tang W, Zhang Y, Hadjipanayis GC. Microstructure and magnetic properties of Sm(CobalFexCu0.128Zr0.02)7.0 magnets with Fe substitution. J Magn Magn Mater. 2000;221(3):268.CrossRef
[2]
go back to reference Guo ZH, Li W. Room-and high-temperature magnetic properties of Sm(CobalFexCu0.088Zr0.025)7.5 (x = 0–0.30) sintered magnets. Acta Metall Sin. 2002;38(8):866. Guo ZH, Li W. Room-and high-temperature magnetic properties of Sm(CobalFexCu0.088Zr0.025)7.5 (x = 0–0.30) sintered magnets. Acta Metall Sin. 2002;38(8):866.
[3]
go back to reference Richard TF, Rubertus CS. Air force applications of advanced magnetic materials. In: Proceeding of Materials Research Society Spring Conference, Vol 57. San Francisco; 1999. 481. Richard TF, Rubertus CS. Air force applications of advanced magnetic materials. In: Proceeding of Materials Research Society Spring Conference, Vol 57. San Francisco; 1999. 481.
[4]
go back to reference Richard TF, Rubertus CS. Applications of high temperature magnetic materials. IEEE Trans Magn. 2000;36(5):3373.CrossRef Richard TF, Rubertus CS. Applications of high temperature magnetic materials. IEEE Trans Magn. 2000;36(5):3373.CrossRef
[5]
go back to reference Rong CB, Zhang HW, Zhang J, Du XB, Zhang SY, Shen BG. Micromagnetic simulation of the coercivity mechanism in Sm(Co, Fe, Cu, Zr)z magnets. J Appl Phys. 2004;95(3):1351.CrossRef Rong CB, Zhang HW, Zhang J, Du XB, Zhang SY, Shen BG. Micromagnetic simulation of the coercivity mechanism in Sm(Co, Fe, Cu, Zr)z magnets. J Appl Phys. 2004;95(3):1351.CrossRef
[6]
go back to reference Yi JH, Peng YD. Review of research on 2:17 type SmCo rare earth permanent magnets. Rare Met Mater Eng. 2004;33(4):337. Yi JH, Peng YD. Review of research on 2:17 type SmCo rare earth permanent magnets. Rare Met Mater Eng. 2004;33(4):337.
[7]
go back to reference An SZ, Jiang CB. Recent progress in high temperature permanent magnetic materials. Rare Met. 2013;32(5):431.CrossRef An SZ, Jiang CB. Recent progress in high temperature permanent magnetic materials. Rare Met. 2013;32(5):431.CrossRef
[8]
go back to reference Liu LL, Jiang CB. The improved oxidation resistance of Si-doped SmCo7 nanocrystalline magnet. Appl Phys Lett. 2011;98(25):252504.CrossRef Liu LL, Jiang CB. The improved oxidation resistance of Si-doped SmCo7 nanocrystalline magnet. Appl Phys Lett. 2011;98(25):252504.CrossRef
[9]
go back to reference Liu LL, Tingyan J, Jiang CB. High-temperature resistance and magnetic properties of Si-doped Sm2Co17-type magnets at 500 °C. J Magn Magn Mater. 2012;324(14):2310.CrossRef Liu LL, Tingyan J, Jiang CB. High-temperature resistance and magnetic properties of Si-doped Sm2Co17-type magnets at 500 °C. J Magn Magn Mater. 2012;324(14):2310.CrossRef
[10]
go back to reference Guo ZH, Pan W, Li W. Sm(Co, Fe, Cu, Zr)z sintered magnets with a maximum operating of 500 C. J Magn Magn Mater. 2006;303(2):396.CrossRef Guo ZH, Pan W, Li W. Sm(Co, Fe, Cu, Zr)z sintered magnets with a maximum operating of 500 C. J Magn Magn Mater. 2006;303(2):396.CrossRef
[11]
go back to reference Liu JF, Zhang Y, Dimitrov D, Hadjipanayis GC. Microstructure and high magnetic properties of Sm(CoCuFeZr)z (z = 6.7–9.1) permanent magnets. J Appl Phys. 1999;85(5):2800.CrossRef Liu JF, Zhang Y, Dimitrov D, Hadjipanayis GC. Microstructure and high magnetic properties of Sm(CoCuFeZr)z (z = 6.7–9.1) permanent magnets. J Appl Phys. 1999;85(5):2800.CrossRef
[12]
go back to reference Chen CH, Walmer MS, Walmer MH, Liu S, Kuhl GE. Thermal stability of Sm-TM high temperature magnets at 300–550 °C. IEEE Trans Magn. 2000;36(5):3291.CrossRef Chen CH, Walmer MS, Walmer MH, Liu S, Kuhl GE. Thermal stability of Sm-TM high temperature magnets at 300–550 °C. IEEE Trans Magn. 2000;36(5):3291.CrossRef
[13]
go back to reference Chen CH, Walmer MH, Kottcamp EH, Gong W. Surface reaction and Sm depletion at 550 °C. IEEE Trans Magn. 2001;37(4):2531.CrossRef Chen CH, Walmer MH, Kottcamp EH, Gong W. Surface reaction and Sm depletion at 550 °C. IEEE Trans Magn. 2001;37(4):2531.CrossRef
[14]
go back to reference Wang X, Peng X, Zhao H, Guo ZH, Li W, Wang F. High temperature oxidation and its induced coercivity loss of a 2:17 type SmCo-based magnet. J Appl Phys. 2015;117(9):093902.CrossRef Wang X, Peng X, Zhao H, Guo ZH, Li W, Wang F. High temperature oxidation and its induced coercivity loss of a 2:17 type SmCo-based magnet. J Appl Phys. 2015;117(9):093902.CrossRef
[15]
go back to reference Liu LL, Jiang CB. Oxidation resistance and magnetic properties of SmCo7-xSix permanent magnetic alloys. J Supercond Novel Magn. 2012;25(1):131.CrossRef Liu LL, Jiang CB. Oxidation resistance and magnetic properties of SmCo7-xSix permanent magnetic alloys. J Supercond Novel Magn. 2012;25(1):131.CrossRef
[16]
go back to reference Saunders SRJ, Nicholls JR. Coatings and surface treatments for high temperature oxidation resistance. Mater Sci Technol. 1989;5(8):780.CrossRef Saunders SRJ, Nicholls JR. Coatings and surface treatments for high temperature oxidation resistance. Mater Sci Technol. 1989;5(8):780.CrossRef
[17]
go back to reference Chen CH, Walmer MH, Liu S. Thermal stability and the effectiveness of coatings for SmCo 2:17 high-temperature magnets at temperatures up to 550 °C. IEEE Trans Magn. 2004;40(4):2928.CrossRef Chen CH, Walmer MH, Liu S. Thermal stability and the effectiveness of coatings for SmCo 2:17 high-temperature magnets at temperatures up to 550 °C. IEEE Trans Magn. 2004;40(4):2928.CrossRef
[18]
go back to reference Chen CH, Huang MQ, John EF, Monnette G, Middleton J, Higgins A, Liu S. Effect of surface modification on mechanical properties and thermal stability of SmCo high temperature magnetic materials. Surf Coat Tech. 2006;201(6):3430.CrossRef Chen CH, Huang MQ, John EF, Monnette G, Middleton J, Higgins A, Liu S. Effect of surface modification on mechanical properties and thermal stability of SmCo high temperature magnetic materials. Surf Coat Tech. 2006;201(6):3430.CrossRef
[19]
go back to reference Wang QY, Zheng L, An SZ, Zhang T, Jiang CB. Thermal stability of surface modified Sm2Co17-type high temperature magnets. J Magn Magn Mater. 2013;331:245.CrossRef Wang QY, Zheng L, An SZ, Zhang T, Jiang CB. Thermal stability of surface modified Sm2Co17-type high temperature magnets. J Magn Magn Mater. 2013;331:245.CrossRef
[20]
go back to reference Pragnell WM, Evans HE, Williams AJ. Oxidation protection of Sm2Co17-based alloys. J Alloy Compd. 2012;517(15):92.CrossRef Pragnell WM, Evans HE, Williams AJ. Oxidation protection of Sm2Co17-based alloys. J Alloy Compd. 2012;517(15):92.CrossRef
[21]
go back to reference Pragnell WM, Evans HE, Williams AJ. The oxidation morphology of SmCo alloys. J Alloy Compd. 2009;487(1–2):69.CrossRef Pragnell WM, Evans HE, Williams AJ. The oxidation morphology of SmCo alloys. J Alloy Compd. 2009;487(1–2):69.CrossRef
[22]
go back to reference Dong Z, Peng X, Guo ZH, Li W, Wang F. The effect of a surface Cr film on the oxidation of SmCo-based magnetic alloy at 700 °C. Corros Sci. 2013;77:113.CrossRef Dong Z, Peng X, Guo ZH, Li W, Wang F. The effect of a surface Cr film on the oxidation of SmCo-based magnetic alloy at 700 °C. Corros Sci. 2013;77:113.CrossRef
[23]
go back to reference Li JJ, Li AH, Zhu MG, Pan W, Li W. Study on corrosion behaviors of sintered Nd–Fe–B magnets in different environment conditions. J Appl Phys. 2011;109:07A744.CrossRef Li JJ, Li AH, Zhu MG, Pan W, Li W. Study on corrosion behaviors of sintered Nd–Fe–B magnets in different environment conditions. J Appl Phys. 2011;109:07A744.CrossRef
[24]
go back to reference Liu JF, Walmer MH. Thermal stability and performance data of SmCo 2:17 high-temperature magnets on PPM focusing structures. IEEE Trans Electron Devices. 2005;52(5):899.CrossRef Liu JF, Walmer MH. Thermal stability and performance data of SmCo 2:17 high-temperature magnets on PPM focusing structures. IEEE Trans Electron Devices. 2005;52(5):899.CrossRef
[25]
go back to reference Kardelky S, Gebert A, Gutfleisch O, Hoffmann V, Schultz L. Prediction of the oxidation behavior of Sm-Co based magnets. J Magn Magn Mater. 2005;290–291(2):1226.CrossRef Kardelky S, Gebert A, Gutfleisch O, Hoffmann V, Schultz L. Prediction of the oxidation behavior of Sm-Co based magnets. J Magn Magn Mater. 2005;290–291(2):1226.CrossRef
[26]
go back to reference Kardelky S, Gebert A, Gutfleisch O, Handstein A, Wyss U, Schultz L. Corrosion behavior of Sm-Co-based permanent magnets in oxidizing environments. IEEE Trans Magn. 2004;40(4):2931.CrossRef Kardelky S, Gebert A, Gutfleisch O, Handstein A, Wyss U, Schultz L. Corrosion behavior of Sm-Co-based permanent magnets in oxidizing environments. IEEE Trans Magn. 2004;40(4):2931.CrossRef
[27]
go back to reference Yang Z, Peng X, Feng Q, Guo Z, Li W, Wang F. The mechanism of high temperature oxidation of a SmCo-based magnetic alloy. Corros Sci. 2012;61:72.CrossRef Yang Z, Peng X, Feng Q, Guo Z, Li W, Wang F. The mechanism of high temperature oxidation of a SmCo-based magnetic alloy. Corros Sci. 2012;61:72.CrossRef
[28]
go back to reference Zhao H, Peng X, Yang Z, Guo ZH, Li W, Wang F. Effect of a thin Cr2O3 film on oxidation at 600 °C of a Sm(CobalFe0.22Cu0.08Zr0.02)7.5 alloy. Surf Coat Tech. 2013;226(15):22.CrossRef Zhao H, Peng X, Yang Z, Guo ZH, Li W, Wang F. Effect of a thin Cr2O3 film on oxidation at 600 °C of a Sm(CobalFe0.22Cu0.08Zr0.02)7.5 alloy. Surf Coat Tech. 2013;226(15):22.CrossRef
[29]
go back to reference Chen CH, Huang M, Higgins A, Lee D, Liu S. Improved mechanical properties and thermal stability of Sm-Co high temperature magnets resulting from surface modifications. J Iron Steel Res Int. 2006;13(8):112.CrossRef Chen CH, Huang M, Higgins A, Lee D, Liu S. Improved mechanical properties and thermal stability of Sm-Co high temperature magnets resulting from surface modifications. J Iron Steel Res Int. 2006;13(8):112.CrossRef
[30]
go back to reference Tian JJ, Zhang SG, Que XH. Effects of oxygen and carbon on the magnetic properties and microstructure of Sm2Co17 permanent magnets. Rare Met. 2007;26(4):299.CrossRef Tian JJ, Zhang SG, Que XH. Effects of oxygen and carbon on the magnetic properties and microstructure of Sm2Co17 permanent magnets. Rare Met. 2007;26(4):299.CrossRef
[31]
go back to reference Zheng J, Lin M, Xia Q. A preparation method and effects of Al–Cr coating on NdFeB sintered magnets. J Magn Magn Mater. 2012;324(22):3966.CrossRef Zheng J, Lin M, Xia Q. A preparation method and effects of Al–Cr coating on NdFeB sintered magnets. J Magn Magn Mater. 2012;324(22):3966.CrossRef
Metadata
Title
Temperature stability of SmCo (2:17) magnets modified by Ni–Cr two-layer coating
Authors
Saira Bibi
Jing-Min Wang
M. Faisal Rathore
Cheng-Bao Jiang
Publication date
04-07-2018
Publisher
Nonferrous Metals Society of China
Published in
Rare Metals / Issue 3/2019
Print ISSN: 1001-0521
Electronic ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-018-1076-0

Other articles of this Issue 3/2019

Rare Metals 3/2019 Go to the issue

Premium Partners