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Published in: Cellulose 1/2016

07-11-2015 | Original Paper

The influences of enzymatic processing on physico-chemical and pigment dyeing characteristics of cotton fabrics

Authors: Longyun Hao, Rui Wang, Lun Wang, Kuanjun Fang, Jingquan Liu, Yajing Men

Published in: Cellulose | Issue 1/2016

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Abstract

First, a crude cellulase was used to treat cotton fabrics to investigate its influences on the physicochemical properties of cotton. The FTIR and XRD analyses both confirmed the enzymatic treatment could increase the crystallinity of cotton, especially at a higher cellulase dosage. Once treated, the number of dissociable groups (–COOH) in cotton decreased, while that of the reducing groups (–CHO) increased. Second, copper phthalocyanine (CuPc) was selected to prepare an anionic nanoscale pigment dispersion to detect its dyeability on different cotton samples. It was concluded that the enzymatic hydrolysis itself had no significant impacts on the pigment dyeing performance. However, cellulase protein still stayed on the cotton surface after treatment and produced an enhancement effect on the pigment uptake due to strong hydrophobic interactions between them. This could be verified by K/S measurement and SEM observations.

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Literature
go back to reference Adamczyk Z, Nattich M, Wasilewska M, Sadowska M (2011) Deposition of colloid particles on protein layers: fibrinogen on mica. J Colloid Interface Sci 356:454–464CrossRef Adamczyk Z, Nattich M, Wasilewska M, Sadowska M (2011) Deposition of colloid particles on protein layers: fibrinogen on mica. J Colloid Interface Sci 356:454–464CrossRef
go back to reference Adeel S, Usman M, Haider W, Saeed M, Muneer M, Ali M (2015) Dyeing of gamma irradiated cotton using Direct Yellow 12 and Direct Yellow 27: improvement in colour strength and fastness properties. Cellulose 22:2095–2105CrossRef Adeel S, Usman M, Haider W, Saeed M, Muneer M, Ali M (2015) Dyeing of gamma irradiated cotton using Direct Yellow 12 and Direct Yellow 27: improvement in colour strength and fastness properties. Cellulose 22:2095–2105CrossRef
go back to reference Akerholm M, Hinterstoisser B, Salmen L (2004) Characterization of the crystalline structure of cellulose using static and dynamic FT-IR spectroscopy. Carbohydr Res 339:569–578CrossRef Akerholm M, Hinterstoisser B, Salmen L (2004) Characterization of the crystalline structure of cellulose using static and dynamic FT-IR spectroscopy. Carbohydr Res 339:569–578CrossRef
go back to reference Andreaus J, Azevedo H, Cavaco-Paulo A (1999) Effects of temperature on the cellulose binding ability of cellulase enzymes. J Mol Catal B Enzym 7:233–239CrossRef Andreaus J, Azevedo H, Cavaco-Paulo A (1999) Effects of temperature on the cellulose binding ability of cellulase enzymes. J Mol Catal B Enzym 7:233–239CrossRef
go back to reference Cao Y, Tan H (2005) Study on crystal structures of enzyme-hydrolyzed cellulosic materials by X-ray diffraction. Enzyme Microb Technol 36:314–317CrossRef Cao Y, Tan H (2005) Study on crystal structures of enzyme-hydrolyzed cellulosic materials by X-ray diffraction. Enzyme Microb Technol 36:314–317CrossRef
go back to reference Cavaco-paulo A, Almeida L, Bishop D (1996) Effects of agitation and endoglucanase pretreatment on the hydrolysis of cotton fabrics by a total cellulase. Text Res J 5:287–294CrossRef Cavaco-paulo A, Almeida L, Bishop D (1996) Effects of agitation and endoglucanase pretreatment on the hydrolysis of cotton fabrics by a total cellulase. Text Res J 5:287–294CrossRef
go back to reference Chung C, Lee M, Choe EK (2004) Characterization of cotton fabric scouring by FT-IR ATR spectroscopy. Carbohydr Polym 58:417–420CrossRef Chung C, Lee M, Choe EK (2004) Characterization of cotton fabric scouring by FT-IR ATR spectroscopy. Carbohydr Polym 58:417–420CrossRef
go back to reference Cortez JM, Ellis J, Bishop DP (2002) Using cellulases to improve the dimensional stability of cellulosic fabrics. Text Res J 72:673–680CrossRef Cortez JM, Ellis J, Bishop DP (2002) Using cellulases to improve the dimensional stability of cellulosic fabrics. Text Res J 72:673–680CrossRef
go back to reference Csiszar E, Urbanszki K, Szakacs G (2001) Biotreatment of desized cotton fabric by commercial cellulase and xylanase enzymes. J Mol Catal B Enzym 11:1065–1072CrossRef Csiszar E, Urbanszki K, Szakacs G (2001) Biotreatment of desized cotton fabric by commercial cellulase and xylanase enzymes. J Mol Catal B Enzym 11:1065–1072CrossRef
go back to reference Dong J, Chen S, Corti DS, Franses EI, Zhao Y, Ng HT, Hanson E (2011) Effect of Triton X-100 on the stability of aqueous dispersions of copper phthalocyanine pigment nanoparticles. J Colloid Interface Sci 362:33–41CrossRef Dong J, Chen S, Corti DS, Franses EI, Zhao Y, Ng HT, Hanson E (2011) Effect of Triton X-100 on the stability of aqueous dispersions of copper phthalocyanine pigment nanoparticles. J Colloid Interface Sci 362:33–41CrossRef
go back to reference Dourado F, Mota M, Pala H, Gama FM (1999) Effect of cellulase adsorption on he surface and interfacial properties of cellulose. Cellulose 6:265–282CrossRef Dourado F, Mota M, Pala H, Gama FM (1999) Effect of cellulase adsorption on he surface and interfacial properties of cellulose. Cellulose 6:265–282CrossRef
go back to reference Driemeier C, Calligaris GA (2011) Theoretical and experimental developments for accurate determination of crystallinity of celllose I materials. J Appl Crystallogr 44:184–192CrossRef Driemeier C, Calligaris GA (2011) Theoretical and experimental developments for accurate determination of crystallinity of celllose I materials. J Appl Crystallogr 44:184–192CrossRef
go back to reference Elazzouzi-Hafraoui S, Nishiyama Y, Putaux J, Heux L, Dubreuil F, Rochas C (2008) The shape and size distribution of crystalline nanoparticles prepared by acid hydrolysis of native cellulose. Biomacromolecules 9:57–65CrossRef Elazzouzi-Hafraoui S, Nishiyama Y, Putaux J, Heux L, Dubreuil F, Rochas C (2008) The shape and size distribution of crystalline nanoparticles prepared by acid hydrolysis of native cellulose. Biomacromolecules 9:57–65CrossRef
go back to reference French AD, Santiago Cintrón M (2013) Cellulose polymorphy, crystallite size, and the Segal crystallinity index. Cellulose 20:583–588CrossRef French AD, Santiago Cintrón M (2013) Cellulose polymorphy, crystallite size, and the Segal crystallinity index. Cellulose 20:583–588CrossRef
go back to reference Gulrajani ML, Dayal A, Chakraborty M (1998) Kawabata evaluation of enzyme treated cotton knitted fabrics. Indian J Fibre Text 23:160–164 Gulrajani ML, Dayal A, Chakraborty M (1998) Kawabata evaluation of enzyme treated cotton knitted fabrics. Indian J Fibre Text 23:160–164
go back to reference Gusakov AV, Sinitsyn AP, Berlin AG, Markov AV, Ankudimova NV (2000) Surface hydrophobic amino acid residues in cellulase molecules as a structural factor responsible for their high denim-washing performance. Enzyme Microb Technol 27:664–671CrossRef Gusakov AV, Sinitsyn AP, Berlin AG, Markov AV, Ankudimova NV (2000) Surface hydrophobic amino acid residues in cellulase molecules as a structural factor responsible for their high denim-washing performance. Enzyme Microb Technol 27:664–671CrossRef
go back to reference Hao L, Cai Y, Fang K (2009) Dyeing of lyocell fabrics with pigment dispersion systems. J Disper Sci Technol 30:332–335CrossRef Hao L, Cai Y, Fang K (2009) Dyeing of lyocell fabrics with pigment dispersion systems. J Disper Sci Technol 30:332–335CrossRef
go back to reference Hao L, Cai Y, Wang R (2011) Preparation of ultrafine pigment dispersion and investigation of its adsorption performance on cationized flax substrate. Adsorpt Sci Technol 29:875–885CrossRef Hao L, Cai Y, Wang R (2011) Preparation of ultrafine pigment dispersion and investigation of its adsorption performance on cationized flax substrate. Adsorpt Sci Technol 29:875–885CrossRef
go back to reference Hao L, Wang R, Liu J, Cai Y, Liu R (2012a) Investigating the adsorption performance of nanoscale pigment on cationized cotton substrate. Powder Technol 222:176–181CrossRef Hao L, Wang R, Liu J, Cai Y, Liu R (2012a) Investigating the adsorption performance of nanoscale pigment on cationized cotton substrate. Powder Technol 222:176–181CrossRef
go back to reference Hao L, Wang R, Liu J, Liu R (2012b) The adsorptive and hydrolytic performance of cellulase on cationised cotton. Carbohydr Polym 89:171–176CrossRef Hao L, Wang R, Liu J, Liu R (2012b) The adsorptive and hydrolytic performance of cellulase on cationised cotton. Carbohydr Polym 89:171–176CrossRef
go back to reference Hao L, Wang R, Liu J, Liu R (2012c) Ultrasound-assisted adsorption of anionic nanoscale pigment on cationised cotton fabrics. Carbohydr Polym 90:1420–1427CrossRef Hao L, Wang R, Liu J, Liu R (2012c) Ultrasound-assisted adsorption of anionic nanoscale pigment on cationised cotton fabrics. Carbohydr Polym 90:1420–1427CrossRef
go back to reference Hao L et al (2014) Utilizing cellulase as a hydrogen peroxide stabilizer to combine the biopolishing and bleaching procedures of cotton cellulose in one bath. Cellulose 21:777–789CrossRef Hao L et al (2014) Utilizing cellulase as a hydrogen peroxide stabilizer to combine the biopolishing and bleaching procedures of cotton cellulose in one bath. Cellulose 21:777–789CrossRef
go back to reference Hashem M, El-Bisi M, Sharaf S, Refaie R (2010) Pre-cationization of cotton fabrics: an effective alternative tool for activation of hydrogen peroxide bleaching process. Carbohydr Polym 79:533–540CrossRef Hashem M, El-Bisi M, Sharaf S, Refaie R (2010) Pre-cationization of cotton fabrics: an effective alternative tool for activation of hydrogen peroxide bleaching process. Carbohydr Polym 79:533–540CrossRef
go back to reference Henrissat B (1994) Cellulases and their interaction with cellulose. Cellulose 1:169–196CrossRef Henrissat B (1994) Cellulases and their interaction with cellulose. Cellulose 1:169–196CrossRef
go back to reference Kang SY, Epps HH (2009) Effect of scouring and enzyme treatment on moisture regain percentage of naturally colored cottons. J Text I 100:598–606CrossRef Kang SY, Epps HH (2009) Effect of scouring and enzyme treatment on moisture regain percentage of naturally colored cottons. J Text I 100:598–606CrossRef
go back to reference Khan AA, Iqbal N, Adeel S, Azeem M, Batool F, Bhatti IA (2014) Extraction of natural dye from red calico leaves: gamma ray assisted improvements in colour strength and fastness. Dyes Pigments 103:50–54CrossRef Khan AA, Iqbal N, Adeel S, Azeem M, Batool F, Bhatti IA (2014) Extraction of natural dye from red calico leaves: gamma ray assisted improvements in colour strength and fastness. Dyes Pigments 103:50–54CrossRef
go back to reference Langan P, Nishiyama Y, Chanzy H (2001) X-ray structure of mercerized cellulose II at 1Å resolution. Biomacromolecules 2:410–416CrossRef Langan P, Nishiyama Y, Chanzy H (2001) X-ray structure of mercerized cellulose II at 1Å resolution. Biomacromolecules 2:410–416CrossRef
go back to reference Lenting HBM, Warmoeskerken MMCG (2001) Guidelines to come to minimized tensile strengh losss upon cellulase application. J Biotechnol 89:227–232CrossRef Lenting HBM, Warmoeskerken MMCG (2001) Guidelines to come to minimized tensile strengh losss upon cellulase application. J Biotechnol 89:227–232CrossRef
go back to reference Lewin M, Ettinger A (1969) Oxidation of cellulose by hydrogen peroxide. Cell Chem Technol 3:9–20 Lewin M, Ettinger A (1969) Oxidation of cellulose by hydrogen peroxide. Cell Chem Technol 3:9–20
go back to reference Li Y, Hardin IR (1997) Enzymatic scouring of cotton: effects on structure and properties. Text Chem Color 8:71–76 Li Y, Hardin IR (1997) Enzymatic scouring of cotton: effects on structure and properties. Text Chem Color 8:71–76
go back to reference Lv J, Zhou X (1999) Relationship between cellulase treatment and dyeing properties of cotton fabrics. J China Text Univ 16:32–34 Lv J, Zhou X (1999) Relationship between cellulase treatment and dyeing properties of cotton fabrics. J China Text Univ 16:32–34
go back to reference Mori R, Haga T, Takagishi T (1996) Reactive dye dyeability of cellulose fibers with cellulase treatment. J Appl Polym Sci 59:1263–1269CrossRef Mori R, Haga T, Takagishi T (1996) Reactive dye dyeability of cellulose fibers with cellulase treatment. J Appl Polym Sci 59:1263–1269CrossRef
go back to reference Nelson ML, O’Connor RT (1964) Relations of certain infrared bands to cellulose crystallinity and crystal lattic type. Part I. Spectra of lattice types I, II, III and amorphous cellulose. J Appl Polym Sci 8:1311–1324CrossRef Nelson ML, O’Connor RT (1964) Relations of certain infrared bands to cellulose crystallinity and crystal lattic type. Part I. Spectra of lattice types I, II, III and amorphous cellulose. J Appl Polym Sci 8:1311–1324CrossRef
go back to reference Nishiyama Y (2009) Structure and properties of the cellulose microfibril. J Wood Sci 55:241–249CrossRef Nishiyama Y (2009) Structure and properties of the cellulose microfibril. J Wood Sci 55:241–249CrossRef
go back to reference Nithya E, Radhai R, Rajendran R, Shalini S, Rajendran V, Jayakumar S (2011) Synergetic effect of DC air plasma and cellulase enzyme treatment on the hydrophilicity of cotton fabric. Carbohydr Polym 83:1652–1658CrossRef Nithya E, Radhai R, Rajendran R, Shalini S, Rajendran V, Jayakumar S (2011) Synergetic effect of DC air plasma and cellulase enzyme treatment on the hydrophilicity of cotton fabric. Carbohydr Polym 83:1652–1658CrossRef
go back to reference Ogeda TL, Silva IB, Fidale LC, Seoud OAE, Petri DFS (2012) Effect of cellulose physical characteristics, especially the water sorption value, on the efficiency of its hydrolysis catalyzed by free or immobilized cellulase. J Biotechnol 157:246–252CrossRef Ogeda TL, Silva IB, Fidale LC, Seoud OAE, Petri DFS (2012) Effect of cellulose physical characteristics, especially the water sorption value, on the efficiency of its hydrolysis catalyzed by free or immobilized cellulase. J Biotechnol 157:246–252CrossRef
go back to reference Pandiyaraj KN, Selvarajan V (2008) Non-thermal plasma treatment for hydrophilicity improvement of grey cotton fabrics. J Mater Process Technol 199:130–139CrossRef Pandiyaraj KN, Selvarajan V (2008) Non-thermal plasma treatment for hydrophilicity improvement of grey cotton fabrics. J Mater Process Technol 199:130–139CrossRef
go back to reference Paralikar KM, Bhatawdekar SP (1984) Hydrolysis of cotton fibres by cellulase enzymes. J Appl Polym Sci 29:2573–2580CrossRef Paralikar KM, Bhatawdekar SP (1984) Hydrolysis of cotton fibres by cellulase enzymes. J Appl Polym Sci 29:2573–2580CrossRef
go back to reference Park S, Venditti RA, Abrecht DG, Jameel H, Pawlak JJ, Lee JM (2007) Surface and pore structure modificatellulose fibers through cellulase treatment. J Appl Polym Sci 103:3833–3839CrossRef Park S, Venditti RA, Abrecht DG, Jameel H, Pawlak JJ, Lee JM (2007) Surface and pore structure modificatellulose fibers through cellulase treatment. J Appl Polym Sci 103:3833–3839CrossRef
go back to reference Park S, Baker JO, Himmel ME, Parilla PA, Johnson DK (2010) Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulase performance. Biotechnol Biofuels 3:1–10CrossRef Park S, Baker JO, Himmel ME, Parilla PA, Johnson DK (2010) Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulase performance. Biotechnol Biofuels 3:1–10CrossRef
go back to reference Paulo AC, Almeida L (1996) Effect of agitation and endoglucanase pretreatment on the hydrolysis of cotton fabrics by a total cellulase. Text Res J 66:287–294CrossRef Paulo AC, Almeida L (1996) Effect of agitation and endoglucanase pretreatment on the hydrolysis of cotton fabrics by a total cellulase. Text Res J 66:287–294CrossRef
go back to reference Rousselle MA, Howley PS (1998) Molecular weight of cotton cellulose: effect of treatment with a total cellulase. Text Res J 68:606–610CrossRef Rousselle MA, Howley PS (1998) Molecular weight of cotton cellulose: effect of treatment with a total cellulase. Text Res J 68:606–610CrossRef
go back to reference Saravanan D, Vasanthi NS, Ramachandran T (2009) A review on influential behaviour of biopolishing on dyeability and certain physico-mechanical properties of cotton fabrics. Carbohydr Polym 76:1–7CrossRef Saravanan D, Vasanthi NS, Ramachandran T (2009) A review on influential behaviour of biopolishing on dyeability and certain physico-mechanical properties of cotton fabrics. Carbohydr Polym 76:1–7CrossRef
go back to reference Segal L, Creely JJ Jr, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786–794CrossRef Segal L, Creely JJ Jr, Martin AE, Conrad CM (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786–794CrossRef
go back to reference Spinelli HJ (1998) Polymeric dispersants in ink jet technology. Adv Mater 10:1215–1218CrossRef Spinelli HJ (1998) Polymeric dispersants in ink jet technology. Adv Mater 10:1215–1218CrossRef
go back to reference Sugiyama J, Persson J, Chanzy H (1991) Combined infrared and electron diffraction study of the polymorphism of native celluloses. Macromolecules 24:2461–2466CrossRef Sugiyama J, Persson J, Chanzy H (1991) Combined infrared and electron diffraction study of the polymorphism of native celluloses. Macromolecules 24:2461–2466CrossRef
go back to reference Tsatsaroni E, Liakopoulou-Kyriakides M (1995) Effect of enzymatic treatment on the dyeing of cotton and wool fibres with natural dyes. Dyes Pigments 29:203–209CrossRef Tsatsaroni E, Liakopoulou-Kyriakides M (1995) Effect of enzymatic treatment on the dyeing of cotton and wool fibres with natural dyes. Dyes Pigments 29:203–209CrossRef
go back to reference Wada M, Okano T, Sugiyama J (1997) Sychrotron-radiaated X-ray and neutron diffraction study of native cellulose. Cellulose 4:221–232CrossRef Wada M, Okano T, Sugiyama J (1997) Sychrotron-radiaated X-ray and neutron diffraction study of native cellulose. Cellulose 4:221–232CrossRef
go back to reference Wang N, Zha A, Wang J (2008) Study on the wicking property of polyester filament yarns. Fiber Polym 9:97–100CrossRef Wang N, Zha A, Wang J (2008) Study on the wicking property of polyester filament yarns. Fiber Polym 9:97–100CrossRef
go back to reference Xie K, Hu C, Zhang X (2012) Low temperature bleaching and dyeing properties of modified cellulose fabrics with triazine derivative. Carbohydr Polym 87:1756–1762CrossRef Xie K, Hu C, Zhang X (2012) Low temperature bleaching and dyeing properties of modified cellulose fabrics with triazine derivative. Carbohydr Polym 87:1756–1762CrossRef
go back to reference Yamade M, Amano Y, Horikawa E, Nozaki K, Kanda T (2005) Mode of action of cellulase on dyed cotton with a reactive dye. Biosci Biotech Bioch 69:45–50CrossRef Yamade M, Amano Y, Horikawa E, Nozaki K, Kanda T (2005) Mode of action of cellulase on dyed cotton with a reactive dye. Biosci Biotech Bioch 69:45–50CrossRef
go back to reference Yue Y, Zhou C, French AD, Xia G, Han G, Wang Q, Wu Q (2012) Comparative properties of cellulose nano-crystals from native and mercerized cotton fibers. Cellulose 19:1173–1187CrossRef Yue Y, Zhou C, French AD, Xia G, Han G, Wang Q, Wu Q (2012) Comparative properties of cellulose nano-crystals from native and mercerized cotton fibers. Cellulose 19:1173–1187CrossRef
go back to reference Zemljic LF (2008) Carboxyl groups in pre-treated regenerated cellulose fibres. Cellulose 15:681–690CrossRef Zemljic LF (2008) Carboxyl groups in pre-treated regenerated cellulose fibres. Cellulose 15:681–690CrossRef
go back to reference Zhang M et al (2011) Highly efficient decomposition of organic dye by aqueous-solid phase transfer and in situ photocatalysis using hierarchical copper phthalocyanine hollow spheres. ACS Appl Mater Inter 3:2573–2578CrossRef Zhang M et al (2011) Highly efficient decomposition of organic dye by aqueous-solid phase transfer and in situ photocatalysis using hierarchical copper phthalocyanine hollow spheres. ACS Appl Mater Inter 3:2573–2578CrossRef
go back to reference Zolriasatein AA, Yazdanshenas ME (2014) Changes in composition, appearence, physical, and dyeing properties of jute yarn after bio-pretreatment with laccase, xylanase, cellulase, and pectinase enzymes. J Text I 105:609–619CrossRef Zolriasatein AA, Yazdanshenas ME (2014) Changes in composition, appearence, physical, and dyeing properties of jute yarn after bio-pretreatment with laccase, xylanase, cellulase, and pectinase enzymes. J Text I 105:609–619CrossRef
Metadata
Title
The influences of enzymatic processing on physico-chemical and pigment dyeing characteristics of cotton fabrics
Authors
Longyun Hao
Rui Wang
Lun Wang
Kuanjun Fang
Jingquan Liu
Yajing Men
Publication date
07-11-2015
Publisher
Springer Netherlands
Published in
Cellulose / Issue 1/2016
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-015-0804-y

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