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Cellulose

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01.08.2012 | Original Paper

Comparative properties of cellulose nano-crystals from native and mercerized cotton fibers

verfasst von: Yiying Yue, Chengjun Zhou, Alfred D. French, Guan Xia, Guangping Han, Qingwen Wang, Qinglin Wu

Erschienen in: Cellulose | Ausgabe 4/2012

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Abstract

Stable aqueous suspensions of cellulose nano-crystals (CNCs) were fabricated from both native and mercerized cotton fibers by sulfuric acid hydrolysis, followed by high-pressure homogenization. Fourier transform infrared spectrometry and wide-angle X-ray diffraction data showed that the fibers had been transformed from cellulose I (native) to cellulose II (mercerized) crystal structure, and these polymorphs were retained in the nanocrystals, giving CNC-I and CNC-II. Transmission electron microscopy showed rod-like crystal morphology for both types of crystals under the given processing conditions with CNC-II having similar width but reduced length. Freeze-dried agglomerates of CNC-II had a much higher bulk density than that of CNC-I. Thermo-gravimetric analysis showed that CNC-II had better thermal stability. The storage moduli of CNC-II suspensions at all temperatures were substantially larger than those of CNC-I suspensions at the same concentration level. CNC-II suspensions and gels were more stable in response to temperature increases. Films of CNC and Poly(ethylene oxide) were tested. Both CNC-I/PEO and CNC-II/PEO composites showed increased tensile strength and elongation at break compared to pure PEO. However, composites with CNC-II had higher strength and elongation than composites with CNC-I.

Vorheriger Artikel Cellulose solvent-based pretreatment for corn stover and avicel: concentrated phosphoric acid versus ionic liquid [BMIM]Cl

Nächster Artikel Comparing microcrystalline with spherical nanocrystalline cellulose from waste cotton fabrics

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Titel: Comparative properties of cellulose nano-crystals from native and mercerized cotton fibers
verfasst von: Yiying Yue
Chengjun Zhou
Alfred D. French
Guan Xia
Guangping Han
Qingwen Wang
Qinglin Wu
Publikationsdatum: 01.08.2012
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 4/2012
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-012-9714-4

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