Skip to main content
Top
Published in: European Journal of Wood and Wood Products 5/2018

07-06-2018 | Original

The potential of phenol–formaldehyde as plasticizing agent for moulding applications of wood veneer: two-dimensional and three-dimensional moulding

Authors: Tom Franke, Nadine Herold, Beate Buchelt, Alexander Pfriem

Published in: European Journal of Wood and Wood Products | Issue 5/2018

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Two phenol–formaldehyde resols, namely a low and a medium molecular weight phenol–formaldehyde, were investigated for their applicability as plasticizers in moulding of European beech veneer (Fagus sylvatica L.). Therefore, beech veneers specimens were impregnated with both phenol–formaldehyde resol types in various concentrations. Subsequently, two-dimensional mouldability of the veneer was tested in a three-point-bending test along and perpendicular to the grain. Additionally, three-dimensional moulding of the phenol–formaldehyde impregnated veneer was tested throughout a modified Erichsen cupping test, where the veneer is pressed through a circular shaped coining die. The obtained results indicate a significantly improved mouldability of the treated beech veneers compared to untreated, water-saturated control specimens. Even at low phenol–formaldehyde concentrations plasticizing effects were detected in longitudinal direction and perpendicular to the grain. These findings are substantiated by results from three-dimensional moulding. Furthermore, the low molecular weight phenol–formaldehyde treated veneers displayed a higher mouldability than medium molecular weight phenol–formaldehyde specimens at similar phenol–formaldehyde concentration.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
go back to reference Beery WH, Ifu G, McLain TE (1983) Quantitative wood anatomy—relating anatomy to transverse tensile strength. Wood Fiber Sci 15(4):395–407 Beery WH, Ifu G, McLain TE (1983) Quantitative wood anatomy—relating anatomy to transverse tensile strength. Wood Fiber Sci 15(4):395–407
go back to reference Biziks V, Bicke S, Militz H (2015) Penetration of phenol formaldehyde (PF) resin into beech wood studied by light microscopy. In: Annual Meeting of International Research group on Wood Protection, Vina del Mar, Chile. IRG/WP 15-20558 Biziks V, Bicke S, Militz H (2015) Penetration of phenol formaldehyde (PF) resin into beech wood studied by light microscopy. In: Annual Meeting of International Research group on Wood Protection, Vina del Mar, Chile. IRG/WP 15-20558
go back to reference Buchelt B, Wagenführ A (2008) The mechanical behaviour of veneer subjected to bending and tensile loads. Holz Roh Werkst 66:289–294CrossRef Buchelt B, Wagenführ A (2008) The mechanical behaviour of veneer subjected to bending and tensile loads. Holz Roh Werkst 66:289–294CrossRef
go back to reference Davidson RW, Baumgardt WG (1970) Plasticizing wood with ammonia—a progress report. For Prod J 20(3):1925 Davidson RW, Baumgardt WG (1970) Plasticizing wood with ammonia—a progress report. For Prod J 20(3):1925
go back to reference DIN 50101, issue 1979-09 (withdrawn) Testing of metals; Erichsen cupping test on sheet and strip metal having a width of ≥ 90 mm; Thickness range: 0.2 to 2 mm. German Institute for Standardization DIN 50101, issue 1979-09 (withdrawn) Testing of metals; Erichsen cupping test on sheet and strip metal having a width of ≥ 90 mm; Thickness range: 0.2 to 2 mm. German Institute for Standardization
go back to reference DIN 52186-06 (1978) Testing of wood; bending test (in German). German Institute for Standardization DIN 52186-06 (1978) Testing of wood; bending test (in German). German Institute for Standardization
go back to reference Fekiac J, Zemiar J, Gaff M, Gabirik J, Gasparik M, Marusak R (2015) 3D-moldability of veneers plasticized with water and ammonia. BioResources 10(1):866–876 Fekiac J, Zemiar J, Gaff M, Gabirik J, Gasparik M, Marusak R (2015) 3D-moldability of veneers plasticized with water and ammonia. BioResources 10(1):866–876
go back to reference Franke T, Mund A, Lenz C, Herold N, Pfriem A (2017) Microscopic and macroscopic swelling and dimensional stability of beech wood impregnated with phenol-formaldehyde. Pro Ligno 13(4):373–378 Franke T, Mund A, Lenz C, Herold N, Pfriem A (2017) Microscopic and macroscopic swelling and dimensional stability of beech wood impregnated with phenol-formaldehyde. Pro Ligno 13(4):373–378
go back to reference Furuno T, Imamura Y, Kajita H (2004) The modification of wood by treatment with low molecular weight phenol-formaldehyde resin: a properties enhancement with neutralized phenolic-resin and resin penetration into wood cell walls. Wood Sci Technol 37:349–361CrossRef Furuno T, Imamura Y, Kajita H (2004) The modification of wood by treatment with low molecular weight phenol-formaldehyde resin: a properties enhancement with neutralized phenolic-resin and resin penetration into wood cell walls. Wood Sci Technol 37:349–361CrossRef
go back to reference Gabrielli CP, Kamke FA (2010) Phenol-formaldehyde impregnation of densified wood for improved dimensional stability. Wood Sci Technol 44:95–104CrossRef Gabrielli CP, Kamke FA (2010) Phenol-formaldehyde impregnation of densified wood for improved dimensional stability. Wood Sci Technol 44:95–104CrossRef
go back to reference Gasparik M, Barcik S (2013) Impact of plasticization by microwave heating on the total deformation of beech wood. BioResources 8(4):62976308CrossRef Gasparik M, Barcik S (2013) Impact of plasticization by microwave heating on the total deformation of beech wood. BioResources 8(4):62976308CrossRef
go back to reference Gasson P (1987) Some implications of anatomical variations in the wood of pedunculate oak (Quercus robur L.), including comparisons with common beech (Fagus sylvatica L.). IAWA Bull 8(2):149–166CrossRef Gasson P (1987) Some implications of anatomical variations in the wood of pedunculate oak (Quercus robur L.), including comparisons with common beech (Fagus sylvatica L.). IAWA Bull 8(2):149–166CrossRef
go back to reference Herold N, Pfriem A (2013) Impregnation of veneer with furfuryl alcohol for an improved plasticization and moulding. Eur J Wood Prod 71(2):281–282CrossRef Herold N, Pfriem A (2013) Impregnation of veneer with furfuryl alcohol for an improved plasticization and moulding. Eur J Wood Prod 71(2):281–282CrossRef
go back to reference Herold N, Pfriem A (2014) Shape retention of furfurylated and moulded wood veneer. BioResources 9(1):545 553 Herold N, Pfriem A (2014) Shape retention of furfurylated and moulded wood veneer. BioResources 9(1):545 553
go back to reference Huang Y, Fei B, Zhao R (2014) Investigations of low-molecular weight phenol formaldehyde distribution in tracheid cell walls of Chinese fir wood. BioResources 9(3):41504158CrossRef Huang Y, Fei B, Zhao R (2014) Investigations of low-molecular weight phenol formaldehyde distribution in tracheid cell walls of Chinese fir wood. BioResources 9(3):41504158CrossRef
go back to reference Huttunen J (1975) Method for plasticizing wood. US 3,894,569 Huttunen J (1975) Method for plasticizing wood. US 3,894,569
go back to reference Jebrane M, Harper D, Labbé N, Sèbea G (2011) Comparative determination of the grafting distribution and viscoelastic properties of wood blocks acetylated by vinyl acetate or acetic anhydride. Carbohydr Polym 84:1314–1320CrossRef Jebrane M, Harper D, Labbé N, Sèbea G (2011) Comparative determination of the grafting distribution and viscoelastic properties of wood blocks acetylated by vinyl acetate or acetic anhydride. Carbohydr Polym 84:1314–1320CrossRef
go back to reference Kelley SS, Rials TG, Glasser WG (1987) Relaxation behaviour of the amorphous components of wood. J Mater Sci 22:617–624CrossRef Kelley SS, Rials TG, Glasser WG (1987) Relaxation behaviour of the amorphous components of wood. J Mater Sci 22:617–624CrossRef
go back to reference Knop A, Pilato LA (1985) Phenolic resins. Chemistry, applications and performance—future directions. Springer, Berlin Knop A, Pilato LA (1985) Phenolic resins. Chemistry, applications and performance—future directions. Springer, Berlin
go back to reference Loughborough WK (1942) Process for plasticizing lignocellulosic materials. US 2,298,017 A Loughborough WK (1942) Process for plasticizing lignocellulosic materials. US 2,298,017 A
go back to reference Norimoto M, Gril J (1989) Wood bending using microwave heating. J Microwave Power EE 24(4):203–212 Norimoto M, Gril J (1989) Wood bending using microwave heating. J Microwave Power EE 24(4):203–212
go back to reference Pfriem A, Dietrich T, Buchelt B (2012) Furfuryl alcohol impregnation for improved plasticization and fixation during densification of wood. Holzforschung 66:215–218CrossRef Pfriem A, Dietrich T, Buchelt B (2012) Furfuryl alcohol impregnation for improved plasticization and fixation during densification of wood. Holzforschung 66:215–218CrossRef
go back to reference Pizzi A (2003) Phenolic resins. In: Pizzi A, Mittal KL (eds) Handbook of adhesive technology, 2nd edn. Taylor & Francis, New York Pizzi A (2003) Phenolic resins. In: Pizzi A, Mittal KL (eds) Handbook of adhesive technology, 2nd edn. Taylor & Francis, New York
go back to reference Sass U, Eckstein D (1995) The variability of vessel size in beech (Fagus sylvatica L.) and its ecophysiological interpretation. Trees 9:247252CrossRef Sass U, Eckstein D (1995) The variability of vessel size in beech (Fagus sylvatica L.) and its ecophysiological interpretation. Trees 9:247252CrossRef
go back to reference Schuerch C (1963) Plasticizing wood with liquid ammonia. Ind Eng Chem 55(10):39CrossRef Schuerch C (1963) Plasticizing wood with liquid ammonia. Ind Eng Chem 55(10):39CrossRef
go back to reference Shams MI, Yano H (2011) Compressive deformation of phenol formaldehyde (PF) resin-impregnated wood related to the molecular weight of resin. Wood Sci Technol 45:73–81CrossRef Shams MI, Yano H (2011) Compressive deformation of phenol formaldehyde (PF) resin-impregnated wood related to the molecular weight of resin. Wood Sci Technol 45:73–81CrossRef
go back to reference Shams MI, Yano H, Endou K (2004) Compressive deformation of wood with low molecular weight phenol formaldehyde (PF) resin I: effects of pressing and pressure holding. J Wood Sci 50:337–342 Shams MI, Yano H, Endou K (2004) Compressive deformation of wood with low molecular weight phenol formaldehyde (PF) resin I: effects of pressing and pressure holding. J Wood Sci 50:337–342
go back to reference Sontag LA, Norton J (1935) Phenolic resin adhesives in the plywood industry. Ind Eng Chem 277(10):11141119 Sontag LA, Norton J (1935) Phenolic resin adhesives in the plywood industry. Ind Eng Chem 277(10):11141119
go back to reference Stamm AJ, Seborg RM (1942) Resin treated wood (Impreg) Forest Products Laboratory. Report 1380 (Revised 1962) Stamm AJ, Seborg RM (1942) Resin treated wood (Impreg) Forest Products Laboratory. Report 1380 (Revised 1962)
go back to reference Stamm AJ, Seborg RM (1955) Resin-treated, laminated compressed wood (Compreg). Forest Products Laboratory. Report 1381 (Revised 1960) Stamm AJ, Seborg RM (1955) Resin-treated, laminated compressed wood (Compreg). Forest Products Laboratory. Report 1381 (Revised 1960)
go back to reference Wagenführ A, Buchelt B, Pfriem A (2006) Material behaviour of veneer during multidimensional moulding. Holz Roh Werkst 64:83–89CrossRef Wagenführ A, Buchelt B, Pfriem A (2006) Material behaviour of veneer during multidimensional moulding. Holz Roh Werkst 64:83–89CrossRef
Metadata
Title
The potential of phenol–formaldehyde as plasticizing agent for moulding applications of wood veneer: two-dimensional and three-dimensional moulding
Authors
Tom Franke
Nadine Herold
Beate Buchelt
Alexander Pfriem
Publication date
07-06-2018
Publisher
Springer Berlin Heidelberg
Published in
European Journal of Wood and Wood Products / Issue 5/2018
Print ISSN: 0018-3768
Electronic ISSN: 1436-736X
DOI
https://doi.org/10.1007/s00107-018-1320-1

Other articles of this Issue 5/2018

European Journal of Wood and Wood Products 5/2018 Go to the issue