Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Arabian Journal for Science and Engineering
Published in: Arabian Journal for Science and Engineering 8/2021

30-03-2021 | Research Article-Mechanical Engineering

Thermodynamic Parameters and Adsorption Mechanism of Corrosion Inhibition in Mild Steel Using Jatropha Leaf Extract in Hydrochloric Acid

Authors: S. C. Ikpeseni, G. O. Odu, H. I. Owamah, P. U. Onochie, D. C. Ukala

Published in: Arabian Journal for Science and Engineering | Issue 8/2021

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Corrosion inhibition performance, thermodynamic parameters and adsorption mechanism of jatropha leaf extract in 2 M HCl solution have been investigated. Inhibition efficiency and corrosion rate were evaluated using gravimetric method, based on ASTM G-31 standards. Activation energy, entropy and enthalpy changes were determined using relevant thermodynamic equations. The mechanism of adsorption was studied using six different adsorption isotherm models. Results obtained show that corrosion rate increased with increase in temperature and decreased with increase in concentration of jatropha leaf extract beyond a maximum dosage. The activation energy of the inhibited process was higher than that of the uninhibited process. The enthalpy and entropy changes obtained were positive and negative, respectively. While the constant of adsorption was positive, Gibb’s free energy change of adsorption was negative with values less than 20KJ/mol. Data obtained fit into Langmuir, Frumkim, El-Awady, Freundlich, Flory Huggins and Tempkin isotherm adsorption models. It was observed that Tempkin model had the best fit and as such was used to evaluate the adsorption constant and Gibb’s free energy change of adsorption. The study found that the adsorption of jatropha leaf extract, on the surface of mild steel, is feasible, spontaneous and follows physical adsorption mechanism.
previous article Assessment of Tool Wear and Surface Integrity in Ductile Cutting Using a Developed Tool
next article Analysis of Weight loss in Reciprocating Wear Test of Cylinder Liner and Piston Ring Coated with Molybdenum

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
Alaneme, K.K.; Olusegun, S.J.; Adelowo, O.T.: Corrosion inhibition and adsorption mechanism studies of Hunteria unmbellata seed husk extracts on mild steel immersed in acidic solutions. Alex. Eng. J. 55, 673–681 (2016)CrossRef
2.
Fiori-Bimbi, M.V.; Alvareez, P.E.; Vaca, H.; Gervasi, C.A.: Corrosion inhibition of mild steel in HCl solution by pectin. Corros. Sci. 92(2015), 192–199 (2015)CrossRef
3.
Haque, J.; Srivastava, V.; Verma, C.; Quraishi, M.A.: Experimental and Quantum Chemical Analysis of 2-amino-3-((4-((S)-2-amaino-2-carboxyethyl)-1H-imidazol-2-yl)thio) Propionic Acid as New and Green Corrosion Inhibitor for Mild Steel in 1M HCl Solution. J. Molecul. Liquids 225, 10074 (20162016)
4.
Akinbulumo, O.A.; Odejobi, O.J.; Odekanle, E.L.: Thermodynamic and adsorption study of the corrosion inhibition of mild steel by Euphorbia Heterophylla L extract. Results Mater. 5(2020), 100074 (2020)CrossRef
5.
Singh, S.A.; Quraishi, V.K.; M.A. : Effect of fruit extracts of some environmentally benign green corrosion inhibitors on corrosion of mild steel in hydrochloric acid solution. J. Mater. Environ. Sci. 3, 163–174 (2010)
6.
Hassan, K.H.; Khadom, A.A.; Kurshed, N.H.: Citrus Aurantium leaves extracts as a sustainable Corrosion inhibitor of mild steel in sulfuric acid. SAJCE 22(2016), 1–5 (2016)
7.
Meshelia, A.D.; Aji, I.S.; Yawas, D.S.: Comparative analysis of jatropha curcas and neem leaves extracts as corrosion inhibitors on mild steel. Univ. Maiduguri Faculty Eng Seminar Series 8(2017), 106–113 (2017)
8.
Olawale, O.; Oyawale, F.A.; Adediran, A.A.; Obafemi, A.S.: Corrosion Inhibition of Mild Steel in Sea Water using Jatropha Stem. Eftimie Murg Resita 13(1), 228–238 (2016)
9.
Nair, R.N.: Green corrosion inhibitors for mild steel in acid medium. IJMTER 4(12), 216–221 (2017)
10.
Zhang, F.; Ju, P.; Pan, M.; Zhang, D.; Huang, Y.; Li, G.; Li, X.: Self-healing mechanism in smart protective coatings: a review. Corros. Sci. 144(2018), 74–88 (2018)CrossRef
11.
Fergachi, O.; Benhiba, F.; Mohamed, R.; Touir, R.; Ouakki, M.; Galai, M.; Lakhrissi, B.; Oudda, H.; Touhami, M.E.: Experimental and Theoretical Study of Corrosion Inhibition of Mild Steel in 1.0M HCl Medium by 2(-4chlorophenyl-1H-benzo[d]imidazole)-1-yl)phenyl) Methane. Mater. Res. 21(6), 20171038 (2018)CrossRef
12.
Haldhar, R.; Prasad, D.; Bhardwaj, N.: Extraction and experimental studies of Citrus Aurantifolia as economical and green corrosion inhibitor for mild steel in acidic media. J. Adhes. Sci. Technol. 33(11), 1169–1183 (2019)CrossRef
13.
Igbinaduwa, P.O.; Usifoh, C.O.; Ugwu, C.C.: Phytochemical analysis and toxicological evaluation of the methanolic extract of Jatropha tanjorensis leaf. J. Pharmacy Bioresour. 8(2), 86–91 (2011)
14.
N. M’hiri, D. Veys-Renaux, E. Rocca, I. Ioannou, N. M. Boudhrioua, M. Ghoul, : Corrosion inhibition of carbon steel in acidic medium by orange peel extract and its main antioxidant compounds. Corros. Sci. 102(2016), 55–62 (2016)
15.
Solomon, M.M.; Umoren, S.A.; Udosoro, I.I.; Udoh, A.P.: Inhibitive and adsorption behaviour of carboxymethyl cellulose on mild steel corrosion in sulphuric acid solution. Corrosion Sci. 52, 1317–1325 (2010)CrossRef
16.
Tsoeunyane, M.G.; Makhatha, M.E.; Arotiba, O.A.: Corrosion inhibition of mild steel by poly(butylene succinate)-L-histidine extended with 1,6-diisocynatohexane polymer composite in 1 M HCl, Int. J. Corr. 2019 (2019). https://​doi.​org/​10.​1155/​2019/​7406409. Article ID 7406409, 12 pages.
17.
Dagdag, O.; Safi, Z.; Hsiesou, R.; Erramli, H.; El-Bouchti, M.; Wazzan, N.; Guo, L.; Verma, C.; Ebenso, E.E.; El-Harfi, A.: Epoxy pre-polymers as new and effective materials for corrosion inhibition of carbon steel in acidic medium: computational and experimental studies. Sci. Rep. 9(1), 1–14 (2019)CrossRef
18.
Owamah, H. I.; Izinyon, O. C.; Asiagwu, A. K.: Sorption model and kinetic assessment of ultramarine blue removal using modified cassava peels biomass. J. Civil Environ Eng, 2(121) (2012).
19.
Chauhan, L.R.; Gunasekaran, G.: Corrosion inhibition of mild steel by plant extract in dilute HCl medium. Corrosion Sci. 9, 1143–1161 (2006)
20.
Asiagwu, A.K.; Owamah, H.I.; Otutu, J.O.: Kinetic model for the sorption of Cu (II) and Zn (II) using Lady Fern (Athyrium-Filix Femina) leaf waste biomass from aqueous solution. Chem. Process. Eng. 3, 1–12 (2012)
21.
Alaneme, K.K.; Olusegun, S.J.: Corrosion inhibition performance of lignin extract of sunflower (Tithonia Diversifolia) on medium carbon low alloy steel immersed in HCl solution. Leonardo J. Sci. 20, 59–70 (2012)
22.
Ebenso, E.E.; Alamu, H.; Umoren, S.A.; Obot, I.B.; Inhibition of mild steel corrosion in sulphuric acid using alizarin yellow dye and synergistic iodide additive, Int. J. Electrochem. Sci. 3(12), 1325–1339 (2008)
23.
24.
Rose, K.; Kim, B.S.; Rajagopal, K.; Arumugam, S.; Devarayan, K.: Surface protection of steel in acid medium by Tabernaemontana divaricata extract: physicochemical evidence for adsorption of inhibitor. J. Mol. Liq. 214, 111–116 (2016)CrossRef
25.
26.
Bashir, S.; Singh, G.; Kumar, A.: Shatavari (Asparagus racemosus) as green corrosion inhibitor of aluminium in acidic medium. J. Mater. Environ. Sci. 8, 4284 (2017)
27.
28.
29.
Noor, E.A.: Temperature effects on the corrosion inhibition of mild steel in acidic solutions by aqueous extract of fenugreek Leaves. Int. J. Electrochem. Sci. 3(2007), 996–1017 (2007)
30.
Sudhish, K.S.; Eno, E.E.: Corrosion inhibition adsorption behavior and thermodynamic properties of streptomycin on mild steel in hydrochloric acid medium. Int. J. Electrochem. Sci. 2011, 3277–3291 (2011)
31.
Olusegun, S.J.; Adeiza, B.A.; Ikeke, K.I.; Bodunrin, M.O.: Jatropha Curcas leaves extract as corrosion inhibitor for mild steel in 1M Hydrochloric Acid. J. Emerg. Trends Eng. Appl. Sci. (JETEAS) 4(1), 138–143 (2013)
32.
Khadom, A.A.; Abd, A.N.; Ahmed, N.A.: Xanthium strumarium leaves extracts as a friendly corrosion inhibitor of low carbon steel in hydrochloric acid: Kinetics and mathematical studies. S. Afr. J. Chem. Eng. 25(2018), 13–21 (2018)
33.
Shahmoradi, A.R.; Talebibahmanbigloo, N.; Javidparvar, A.A.; Bahlakehd, G.; Ramezanzadeh, B.: Studying the adsorption/inhibition impact of the cellulose and lignin compounds extracted fromagricultural waste on the mild steel corrosion in HCl solution. J. Mol. Liq. 304(2020), 112751 (2020)CrossRef
34.
Hamdy, A.; El-Gendy, N.S.: Thermodynamic, adsorption and electrochemical studies for corrosion inhibition of carbon steel by henna extract in acid medium. Egypt. J. Pet. 2013(22), 17–25 (2013)CrossRef
35.
36.
37.
38.
39.
Subektia, N.; Soedarsonoa, J.W.; Rustandia, A.; Arlana, A.S.: Corrosion Inhibition by a Caesalpinia Sappan L Modified Imidazoline for Carbon Steel API 5L Grade X60 in HCl 1M Environment 15th International Conference on Quality in Research (QiR 2017).
40.
Kamal, C.; Sethuraman, M.G.: Spirulina platensis—a novel green inhibitor for acid corrosion of mild steel. Arab. J. Chem. 2012(5), 155–161 (2012)CrossRef
41.
Gupta, A.; Naraniwal, M.; Kothari, V.: Modern extraction methods for preparation of bioactive active plant extract. Int. J. Appl. Nat. Sci. (IJANS) 1(1), 8–9 (2012)
Metadata
Title
Thermodynamic Parameters and Adsorption Mechanism of Corrosion Inhibition in Mild Steel Using Jatropha Leaf Extract in Hydrochloric Acid
Authors
S. C. Ikpeseni
G. O. Odu
H. I. Owamah
P. U. Onochie
D. C. Ukala
Publication date
30-03-2021
Publisher
Springer Berlin Heidelberg
Published in
Arabian Journal for Science and Engineering / Issue 8/2021
Print ISSN: 2193-567X
Electronic ISSN: 2191-4281
DOI
https://doi.org/10.1007/s13369-021-05488-9

Other articles of this Issue 8/2021

Arabian Journal for Science and Engineering 8/2021 Go to the issue

Research Article-Mechanical Engineering

Influence of Surfactants on the Tribological Behavior of Nanoparticle Additives Under Boundary Lubrication Conditions

Research Article-Mechanical Engineering

Mechanical and Corrosion Properties of Low-Carbon Steel Processed by Cryorolling: Effect of Different Initial Microstructures

Research Article-Mechanical Engineering

Evaluation of Vital Factors Effecting 4S CI Engine with Altered IT Using Calophyllum Inophyllum Blends with H2 Enrichment

Research Article-Mechanical Engineering

Psychophysics Experiment to Check the Temperature Impacts Over Human Fingertips for the Application of Textural Applications in Haptics Technology

Research Article-Mechanical Engineering

Multi-objective Soft Computing Approaches to Evaluate the Performance of Abrasive Water Jet drilling Parameters on Die Steel

Research Article-Mechanical Engineering

Aerodynamic Performance Optimization of Multiple Slat Airfoil based on Multi-Objective Genetic Algorithm

Premium Partners

    Image Credits