Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Cellulose
Published in: Cellulose 5/2013

01-10-2013 | Original Paper

Tri-component bio-composite materials prepared using an eco-friendly processing route

Authors: Rasike De Silva, Xungai Wang, Nolene Byrne

Published in: Cellulose | Issue 5/2013

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

We report on the blending of three natural polymers, raw cotton, silk and wool, using ionic liquids as the dissolving media. We find that with increased content of wool and silk the thermal degradation temperature of the new bio films increases. This is due to an increase in the hydrogen bond network between the blended polymers. We also investigated the role of the coagulating solvent by coagulating the bio films using water, methanol or isopropanol. Again, we find the coagulating solvent impacts the final properties of the bio films with water shown to coagulated films with the best material properties.
previous article Effect of tempo and periodate-chlorite oxidized nanofibrils on ground calcium carbonate flocculation and retention in sheet forming and on the physical properties of sheets
next article Adsorption of silver on cellobiose and cellulose studied with MIES, UPS, XPS and AFM

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now
Literature
Belgacem MN, Gandini A (2008) Monomers, polymers and composites from renewable resources. Elsevier, Oxford
Cao Y, Wu J, Zhang J, Li H, Zhang Y, He J (2009) Room temperature ionic liquids (RTILs): a new and versatile platform for cellulose processing and derivatization. Chem Eng J 147(1):13–21CrossRef
Carr MC (1995) Chemistry of the textiles industry. In: Rasike (ed) Book mine, vol 18, Mage ridenawa, vol 52, 11th edn. Blackie Academic & Professional, Glasgow, pp 35-70
Du C, Jin J, Li Y, Kong X, Wei K, Yao J (2009) Novel silk fibroin/hydroxyapatite composite films: structure and properties. Mater Sci Eng C 29(1):62–68CrossRef
Fengel D (1992) Characterization of cellulose by deconvoluting the OH valency range in FTIR spectra. Holzforschung-Int J Biol, Chem, Phys Technol Wood 46(4):283–288
Fink HP, Weigel P, Purz HJ, Ganster J (2001) Structure formation of regenerated cellulose materials from NMMO-solutions. Prog Polym Sci 26(9):1473–1524CrossRef
Gibril ME, Yue Z (2012) Current status of applications of ionic liquids for cellulose dissolution and modifications: review. Int J Eng Sci 4(7):3556–3571
Goujon N, Rajkhowa R, Wang X, Byrne N (2012) Effect of solvent on ionic liquid dissolved regenerated Antheraea assamensis silk fibroin. J Appl Polym Sci 128(6):4411–4416CrossRef
Griffiths P, De Haseth JA (2007) Fourier transform infrared spectrometry, vol 171, 2nd edn. Wiley-Interscience, New JerseyCrossRef
Hameed N, Guo Q (2010) Blend films of natural wool and cellulose prepared from an ionic liquid. Cellulose 17(4):803–813CrossRef
Handbook of Fiber Chemistry (2006) Vol 16. International Fibre Science and Technology Series, 3 edn. CRC Press, Boca Raton
Heinze T, Koschella A (2005) Solvents applied in the field of cellulose chemistry: a mini review. Polimeros 15(2):84–90CrossRef
Hu X, Cebe P, Weiss AS, Omenetto F, Kaplan DL (2012) Protein-based composite materials. Mater Today 15(5):208–215CrossRef
Isci A, Demirer G (2007) Biogas production potential from cotton wastes. Renewable Energy 32(5):750–757CrossRef
Kadokawa J-I, Hirohama K, Mine S, Kato T, Yamamoto K (2012) Facile preparation of chitin/cellulose composite films using ionic liquids. J Polym Environ 20(1):37–42CrossRef
Jin H-J, Park J, Valluzzi R, Cebe P, Kaplan DL (2004) Biomaterial films of Bombyx Mori silk fibroin with poly (ethylene oxide). Biomacromolecules 5(3):711–717CrossRef
Kaplan D, Adams WW, Farmer B, Viney C (1994) Silk polymers, vol 544. ACS, Washington, DC
Köhler S, Heinze T (2007) New solvents for cellulose: dimethyl sulfoxide/ammonium fluorides. Macromol Biosci 7(3):307–314CrossRef
Kokorin A (2011) Ionic liquids: theory, properties, new approaches. InTech, RijekaCrossRef
Kondo T, Sawatari C (1996) A Fourier transform infra-red spectroscopic analysis of the character of hydrogen bonds in amorphous cellulose. Polymer 37(3):393–399CrossRef
Kong J, Yu S (2007) Fourier transform infrared spectroscopic analysis of protein secondary structures. Acta Biochim Biophys Sin 39(8):549–559CrossRef
Kweon H, Ha HC, Um IC, Park YH (2001) Physical properties of silk fibroin/chitosan blend films. J Appl Polym Sci 80(7):928–934CrossRef
Lee SH, Miyauchi M, Dordick JS, Linhardt RJ (2010) Preparation of biopolymer-based materials using ionic liquids for the biomedical application. In: ACS symposium series ionic liquids application: pharmaceutical, therapeutics, and biotechnology. pp 115–134
Li R, Wang D (2012) Preparation of regenerated wool keratin films from wool keratin-ionic liquid solutions. J Appl Polym Sci 127(4):2648–2653CrossRef
Maia E, Peguy A, Perez S (1981) Cellulose organic solvents. I. The structures of anhydrous N-methylmorpholine N-oxide and N-methylmorpholine N-oxide monohydrate. Acta Crystallogr B 37(10):1858–1862CrossRef
Matthews JA, Wnek GE, Simpson DG, Bowlin GL (2002) Electrospinning of collagen nanofibers. Biomacromolecules 3(2):232–238CrossRef
Mohanty A, Misra M, Hinrichsen G (2000) Biofibres, biodegradable polymers and biocomposites: an overview. Macromol Mater Eng 276(1):1–24CrossRef
Mohanty A, Misra M, Drzal L (2002) Sustainable bio-composites from renewable resources: opportunities and challenges in the green materials world. J Polym Environ 10(1):19–26CrossRef
Morton Ernest W, Hearle WSJ (1993) Physical properties of textile fibres, 3rd edn. Textile Institute, Manchester
Netravali AN, Huang X, Mizuta K (2007) Advanced’green’composites. Adv Compos Mater 16(4):269–282CrossRef
Onions Wilfred J (1962) Wool. An introduction to its properties, varieties, uses and production. Ernest Benn Ltd, London
Phillips DM, Drummy LF, Conrady DG, Fox DM, Naik RR, Stone MO, Trulove PC, Hugh C, Mantz RA (2004) Dissolution and regeneration of Bombyx mori silk fibroin using ionic liquids. J Am Chem Soc 126(44):14350–14351CrossRef
Pribic R, Vanstokkum I, Chapman D, Haris P, Bloemendal M (1993) Protein secondary structure from Fourier transform infrared and/or circular dichroism spectra. Anal Biochem 214(2):366–378CrossRef
Rogers RD, Seddon KR (2003) Ionic liquids–solvents of the future? Science 302(5646):792–793CrossRef
Schwanninger M, Rodrigues J, Pereira H, Hinterstoisser B (2004) Effects of short-time vibratory ball milling on the shape of FT-IR spectra of wood and cellulose. Vib Spectrosc 36(1):23–40CrossRef
Shang S, Zhu L, Fan J (2011) Physical properties of silk fibroin/cellulose blend films regenerated from the hydrophilic ionic liquid. Carbohydr Polym 86(2):462–468CrossRef
Stefanescu C, Daly WH, Negulescu II (2012) Biocomposite films prepared from ionic liquid solutions of chitosan and cellulose. Carbohydr Polym 87(1):435–443CrossRef
Swatloski RP, Spear SK, Holbrey JD, Rogers RD (2002) Dissolution of cellose with ionic liquids. J Am Chem Soc 124(18):4974–4975CrossRef
Vitz J, Erdmenger T, Schubert US (2010) Imidazolium based ionic liquids as solvents for cellulose chemistry ACS symposium series. Oxford University Press, Oxford, pp 299–317
Wendler F, Meister F, Wawro D, Wesolowska E, Ciechanska D, Saake B, Puls J, Le Moigne N, Navard P (2010) Polysaccharide blend fibres formed from NaOH, N-methylmorpholine-N-oxide and 1-ethyl-3-methylimidazolium acetate. Fibre Text East Eur 18 (2)
Wu R-L, Wang X-L, Wang Y-Z, Bian X-C, Li F (2009) Cellulose/soy protein isolate blend films prepared via room-temperature ionic liquid. Ind Eng Chem Res 48(15):7132–7136CrossRef
Xie H, Li S, Zhang S (2005) Ionic liquids as novel solvents for the dissolution and blending of wool keratin fibers. Green Chem 7(8):606–608CrossRef
Metadata
Title
Tri-component bio-composite materials prepared using an eco-friendly processing route
Authors
Rasike De Silva
Xungai Wang
Nolene Byrne
Publication date
01-10-2013
Publisher
Springer Netherlands
Published in
Cellulose / Issue 5/2013
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-013-0014-4

Other articles of this Issue 5/2013

Cellulose 5/2013 Go to the issue

Original Paper

Effects of lignin on the ionic-liquid assisted catalytic hydrolysis of cellulose: chemical inhibition by lignin

Original Paper

Nanocomposite hydrogel from grafting of acrylamide onto HPMC using sodium montmorillonite nanoclay and removal of crystal violet dye

Original Paper

Sorption of iron(III)–alginate complexes on cellulose fibres

Original Paper

Inhibition of mild steel corrosion in HCl solution using chitosan

Original Paper

Cellulose and microcrystalline cellulose from rice straw and banana plant waste: preparation and characterization

Original Paper

Topochemical activation of pulp fibres