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Erschienen in: Cellulose 5/2013

01.10.2013 | Original Paper

Tri-component bio-composite materials prepared using an eco-friendly processing route

verfasst von: Rasike De Silva, Xungai Wang, Nolene Byrne

Erschienen in: Cellulose | Ausgabe 5/2013

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Abstract

We report on the blending of three natural polymers, raw cotton, silk and wool, using ionic liquids as the dissolving media. We find that with increased content of wool and silk the thermal degradation temperature of the new bio films increases. This is due to an increase in the hydrogen bond network between the blended polymers. We also investigated the role of the coagulating solvent by coagulating the bio films using water, methanol or isopropanol. Again, we find the coagulating solvent impacts the final properties of the bio films with water shown to coagulated films with the best material properties.

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Literatur
Zurück zum Zitat Belgacem MN, Gandini A (2008) Monomers, polymers and composites from renewable resources. Elsevier, Oxford Belgacem MN, Gandini A (2008) Monomers, polymers and composites from renewable resources. Elsevier, Oxford
Zurück zum Zitat Cao Y, Wu J, Zhang J, Li H, Zhang Y, He J (2009) Room temperature ionic liquids (RTILs): a new and versatile platform for cellulose processing and derivatization. Chem Eng J 147(1):13–21CrossRef Cao Y, Wu J, Zhang J, Li H, Zhang Y, He J (2009) Room temperature ionic liquids (RTILs): a new and versatile platform for cellulose processing and derivatization. Chem Eng J 147(1):13–21CrossRef
Zurück zum Zitat Carr MC (1995) Chemistry of the textiles industry. In: Rasike (ed) Book mine, vol 18, Mage ridenawa, vol 52, 11th edn. Blackie Academic & Professional, Glasgow, pp 35-70 Carr MC (1995) Chemistry of the textiles industry. In: Rasike (ed) Book mine, vol 18, Mage ridenawa, vol 52, 11th edn. Blackie Academic & Professional, Glasgow, pp 35-70
Zurück zum Zitat Du C, Jin J, Li Y, Kong X, Wei K, Yao J (2009) Novel silk fibroin/hydroxyapatite composite films: structure and properties. Mater Sci Eng C 29(1):62–68CrossRef Du C, Jin J, Li Y, Kong X, Wei K, Yao J (2009) Novel silk fibroin/hydroxyapatite composite films: structure and properties. Mater Sci Eng C 29(1):62–68CrossRef
Zurück zum Zitat Fengel D (1992) Characterization of cellulose by deconvoluting the OH valency range in FTIR spectra. Holzforschung-Int J Biol, Chem, Phys Technol Wood 46(4):283–288 Fengel D (1992) Characterization of cellulose by deconvoluting the OH valency range in FTIR spectra. Holzforschung-Int J Biol, Chem, Phys Technol Wood 46(4):283–288
Zurück zum Zitat Fink HP, Weigel P, Purz HJ, Ganster J (2001) Structure formation of regenerated cellulose materials from NMMO-solutions. Prog Polym Sci 26(9):1473–1524CrossRef Fink HP, Weigel P, Purz HJ, Ganster J (2001) Structure formation of regenerated cellulose materials from NMMO-solutions. Prog Polym Sci 26(9):1473–1524CrossRef
Zurück zum Zitat Gibril ME, Yue Z (2012) Current status of applications of ionic liquids for cellulose dissolution and modifications: review. Int J Eng Sci 4(7):3556–3571 Gibril ME, Yue Z (2012) Current status of applications of ionic liquids for cellulose dissolution and modifications: review. Int J Eng Sci 4(7):3556–3571
Zurück zum Zitat Goujon N, Rajkhowa R, Wang X, Byrne N (2012) Effect of solvent on ionic liquid dissolved regenerated Antheraea assamensis silk fibroin. J Appl Polym Sci 128(6):4411–4416CrossRef Goujon N, Rajkhowa R, Wang X, Byrne N (2012) Effect of solvent on ionic liquid dissolved regenerated Antheraea assamensis silk fibroin. J Appl Polym Sci 128(6):4411–4416CrossRef
Zurück zum Zitat Griffiths P, De Haseth JA (2007) Fourier transform infrared spectrometry, vol 171, 2nd edn. Wiley-Interscience, New JerseyCrossRef Griffiths P, De Haseth JA (2007) Fourier transform infrared spectrometry, vol 171, 2nd edn. Wiley-Interscience, New JerseyCrossRef
Zurück zum Zitat Hameed N, Guo Q (2010) Blend films of natural wool and cellulose prepared from an ionic liquid. Cellulose 17(4):803–813CrossRef Hameed N, Guo Q (2010) Blend films of natural wool and cellulose prepared from an ionic liquid. Cellulose 17(4):803–813CrossRef
Zurück zum Zitat Handbook of Fiber Chemistry (2006) Vol 16. International Fibre Science and Technology Series, 3 edn. CRC Press, Boca Raton Handbook of Fiber Chemistry (2006) Vol 16. International Fibre Science and Technology Series, 3 edn. CRC Press, Boca Raton
Zurück zum Zitat Heinze T, Koschella A (2005) Solvents applied in the field of cellulose chemistry: a mini review. Polimeros 15(2):84–90CrossRef Heinze T, Koschella A (2005) Solvents applied in the field of cellulose chemistry: a mini review. Polimeros 15(2):84–90CrossRef
Zurück zum Zitat Hu X, Cebe P, Weiss AS, Omenetto F, Kaplan DL (2012) Protein-based composite materials. Mater Today 15(5):208–215CrossRef Hu X, Cebe P, Weiss AS, Omenetto F, Kaplan DL (2012) Protein-based composite materials. Mater Today 15(5):208–215CrossRef
Zurück zum Zitat Isci A, Demirer G (2007) Biogas production potential from cotton wastes. Renewable Energy 32(5):750–757CrossRef Isci A, Demirer G (2007) Biogas production potential from cotton wastes. Renewable Energy 32(5):750–757CrossRef
Zurück zum Zitat Kadokawa J-I, Hirohama K, Mine S, Kato T, Yamamoto K (2012) Facile preparation of chitin/cellulose composite films using ionic liquids. J Polym Environ 20(1):37–42CrossRef Kadokawa J-I, Hirohama K, Mine S, Kato T, Yamamoto K (2012) Facile preparation of chitin/cellulose composite films using ionic liquids. J Polym Environ 20(1):37–42CrossRef
Zurück zum Zitat Jin H-J, Park J, Valluzzi R, Cebe P, Kaplan DL (2004) Biomaterial films of Bombyx Mori silk fibroin with poly (ethylene oxide). Biomacromolecules 5(3):711–717CrossRef Jin H-J, Park J, Valluzzi R, Cebe P, Kaplan DL (2004) Biomaterial films of Bombyx Mori silk fibroin with poly (ethylene oxide). Biomacromolecules 5(3):711–717CrossRef
Zurück zum Zitat Kaplan D, Adams WW, Farmer B, Viney C (1994) Silk polymers, vol 544. ACS, Washington, DC Kaplan D, Adams WW, Farmer B, Viney C (1994) Silk polymers, vol 544. ACS, Washington, DC
Zurück zum Zitat Köhler S, Heinze T (2007) New solvents for cellulose: dimethyl sulfoxide/ammonium fluorides. Macromol Biosci 7(3):307–314CrossRef Köhler S, Heinze T (2007) New solvents for cellulose: dimethyl sulfoxide/ammonium fluorides. Macromol Biosci 7(3):307–314CrossRef
Zurück zum Zitat Kokorin A (2011) Ionic liquids: theory, properties, new approaches. InTech, RijekaCrossRef Kokorin A (2011) Ionic liquids: theory, properties, new approaches. InTech, RijekaCrossRef
Zurück zum Zitat Kondo T, Sawatari C (1996) A Fourier transform infra-red spectroscopic analysis of the character of hydrogen bonds in amorphous cellulose. Polymer 37(3):393–399CrossRef Kondo T, Sawatari C (1996) A Fourier transform infra-red spectroscopic analysis of the character of hydrogen bonds in amorphous cellulose. Polymer 37(3):393–399CrossRef
Zurück zum Zitat Kong J, Yu S (2007) Fourier transform infrared spectroscopic analysis of protein secondary structures. Acta Biochim Biophys Sin 39(8):549–559CrossRef Kong J, Yu S (2007) Fourier transform infrared spectroscopic analysis of protein secondary structures. Acta Biochim Biophys Sin 39(8):549–559CrossRef
Zurück zum Zitat Kweon H, Ha HC, Um IC, Park YH (2001) Physical properties of silk fibroin/chitosan blend films. J Appl Polym Sci 80(7):928–934CrossRef Kweon H, Ha HC, Um IC, Park YH (2001) Physical properties of silk fibroin/chitosan blend films. J Appl Polym Sci 80(7):928–934CrossRef
Zurück zum Zitat Lee SH, Miyauchi M, Dordick JS, Linhardt RJ (2010) Preparation of biopolymer-based materials using ionic liquids for the biomedical application. In: ACS symposium series ionic liquids application: pharmaceutical, therapeutics, and biotechnology. pp 115–134 Lee SH, Miyauchi M, Dordick JS, Linhardt RJ (2010) Preparation of biopolymer-based materials using ionic liquids for the biomedical application. In: ACS symposium series ionic liquids application: pharmaceutical, therapeutics, and biotechnology. pp 115–134
Zurück zum Zitat Li R, Wang D (2012) Preparation of regenerated wool keratin films from wool keratin-ionic liquid solutions. J Appl Polym Sci 127(4):2648–2653CrossRef Li R, Wang D (2012) Preparation of regenerated wool keratin films from wool keratin-ionic liquid solutions. J Appl Polym Sci 127(4):2648–2653CrossRef
Zurück zum Zitat Maia E, Peguy A, Perez S (1981) Cellulose organic solvents. I. The structures of anhydrous N-methylmorpholine N-oxide and N-methylmorpholine N-oxide monohydrate. Acta Crystallogr B 37(10):1858–1862CrossRef Maia E, Peguy A, Perez S (1981) Cellulose organic solvents. I. The structures of anhydrous N-methylmorpholine N-oxide and N-methylmorpholine N-oxide monohydrate. Acta Crystallogr B 37(10):1858–1862CrossRef
Zurück zum Zitat Matthews JA, Wnek GE, Simpson DG, Bowlin GL (2002) Electrospinning of collagen nanofibers. Biomacromolecules 3(2):232–238CrossRef Matthews JA, Wnek GE, Simpson DG, Bowlin GL (2002) Electrospinning of collagen nanofibers. Biomacromolecules 3(2):232–238CrossRef
Zurück zum Zitat Mohanty A, Misra M, Hinrichsen G (2000) Biofibres, biodegradable polymers and biocomposites: an overview. Macromol Mater Eng 276(1):1–24CrossRef Mohanty A, Misra M, Hinrichsen G (2000) Biofibres, biodegradable polymers and biocomposites: an overview. Macromol Mater Eng 276(1):1–24CrossRef
Zurück zum Zitat Mohanty A, Misra M, Drzal L (2002) Sustainable bio-composites from renewable resources: opportunities and challenges in the green materials world. J Polym Environ 10(1):19–26CrossRef Mohanty A, Misra M, Drzal L (2002) Sustainable bio-composites from renewable resources: opportunities and challenges in the green materials world. J Polym Environ 10(1):19–26CrossRef
Zurück zum Zitat Morton Ernest W, Hearle WSJ (1993) Physical properties of textile fibres, 3rd edn. Textile Institute, Manchester Morton Ernest W, Hearle WSJ (1993) Physical properties of textile fibres, 3rd edn. Textile Institute, Manchester
Zurück zum Zitat Netravali AN, Huang X, Mizuta K (2007) Advanced’green’composites. Adv Compos Mater 16(4):269–282CrossRef Netravali AN, Huang X, Mizuta K (2007) Advanced’green’composites. Adv Compos Mater 16(4):269–282CrossRef
Zurück zum Zitat Onions Wilfred J (1962) Wool. An introduction to its properties, varieties, uses and production. Ernest Benn Ltd, London Onions Wilfred J (1962) Wool. An introduction to its properties, varieties, uses and production. Ernest Benn Ltd, London
Zurück zum Zitat Phillips DM, Drummy LF, Conrady DG, Fox DM, Naik RR, Stone MO, Trulove PC, Hugh C, Mantz RA (2004) Dissolution and regeneration of Bombyx mori silk fibroin using ionic liquids. J Am Chem Soc 126(44):14350–14351CrossRef Phillips DM, Drummy LF, Conrady DG, Fox DM, Naik RR, Stone MO, Trulove PC, Hugh C, Mantz RA (2004) Dissolution and regeneration of Bombyx mori silk fibroin using ionic liquids. J Am Chem Soc 126(44):14350–14351CrossRef
Zurück zum Zitat Pribic R, Vanstokkum I, Chapman D, Haris P, Bloemendal M (1993) Protein secondary structure from Fourier transform infrared and/or circular dichroism spectra. Anal Biochem 214(2):366–378CrossRef Pribic R, Vanstokkum I, Chapman D, Haris P, Bloemendal M (1993) Protein secondary structure from Fourier transform infrared and/or circular dichroism spectra. Anal Biochem 214(2):366–378CrossRef
Zurück zum Zitat Rogers RD, Seddon KR (2003) Ionic liquids–solvents of the future? Science 302(5646):792–793CrossRef Rogers RD, Seddon KR (2003) Ionic liquids–solvents of the future? Science 302(5646):792–793CrossRef
Zurück zum Zitat Schwanninger M, Rodrigues J, Pereira H, Hinterstoisser B (2004) Effects of short-time vibratory ball milling on the shape of FT-IR spectra of wood and cellulose. Vib Spectrosc 36(1):23–40CrossRef Schwanninger M, Rodrigues J, Pereira H, Hinterstoisser B (2004) Effects of short-time vibratory ball milling on the shape of FT-IR spectra of wood and cellulose. Vib Spectrosc 36(1):23–40CrossRef
Zurück zum Zitat Shang S, Zhu L, Fan J (2011) Physical properties of silk fibroin/cellulose blend films regenerated from the hydrophilic ionic liquid. Carbohydr Polym 86(2):462–468CrossRef Shang S, Zhu L, Fan J (2011) Physical properties of silk fibroin/cellulose blend films regenerated from the hydrophilic ionic liquid. Carbohydr Polym 86(2):462–468CrossRef
Zurück zum Zitat Stefanescu C, Daly WH, Negulescu II (2012) Biocomposite films prepared from ionic liquid solutions of chitosan and cellulose. Carbohydr Polym 87(1):435–443CrossRef Stefanescu C, Daly WH, Negulescu II (2012) Biocomposite films prepared from ionic liquid solutions of chitosan and cellulose. Carbohydr Polym 87(1):435–443CrossRef
Zurück zum Zitat Swatloski RP, Spear SK, Holbrey JD, Rogers RD (2002) Dissolution of cellose with ionic liquids. J Am Chem Soc 124(18):4974–4975CrossRef Swatloski RP, Spear SK, Holbrey JD, Rogers RD (2002) Dissolution of cellose with ionic liquids. J Am Chem Soc 124(18):4974–4975CrossRef
Zurück zum Zitat Vitz J, Erdmenger T, Schubert US (2010) Imidazolium based ionic liquids as solvents for cellulose chemistry ACS symposium series. Oxford University Press, Oxford, pp 299–317 Vitz J, Erdmenger T, Schubert US (2010) Imidazolium based ionic liquids as solvents for cellulose chemistry ACS symposium series. Oxford University Press, Oxford, pp 299–317
Zurück zum Zitat Welton T (2011) Ionic liquids in green chemistry. Green Chem 13(2):225CrossRef Welton T (2011) Ionic liquids in green chemistry. Green Chem 13(2):225CrossRef
Zurück zum Zitat Wendler F, Meister F, Wawro D, Wesolowska E, Ciechanska D, Saake B, Puls J, Le Moigne N, Navard P (2010) Polysaccharide blend fibres formed from NaOH, N-methylmorpholine-N-oxide and 1-ethyl-3-methylimidazolium acetate. Fibre Text East Eur 18 (2) Wendler F, Meister F, Wawro D, Wesolowska E, Ciechanska D, Saake B, Puls J, Le Moigne N, Navard P (2010) Polysaccharide blend fibres formed from NaOH, N-methylmorpholine-N-oxide and 1-ethyl-3-methylimidazolium acetate. Fibre Text East Eur 18 (2)
Zurück zum Zitat Wu R-L, Wang X-L, Wang Y-Z, Bian X-C, Li F (2009) Cellulose/soy protein isolate blend films prepared via room-temperature ionic liquid. Ind Eng Chem Res 48(15):7132–7136CrossRef Wu R-L, Wang X-L, Wang Y-Z, Bian X-C, Li F (2009) Cellulose/soy protein isolate blend films prepared via room-temperature ionic liquid. Ind Eng Chem Res 48(15):7132–7136CrossRef
Zurück zum Zitat Xie H, Li S, Zhang S (2005) Ionic liquids as novel solvents for the dissolution and blending of wool keratin fibers. Green Chem 7(8):606–608CrossRef Xie H, Li S, Zhang S (2005) Ionic liquids as novel solvents for the dissolution and blending of wool keratin fibers. Green Chem 7(8):606–608CrossRef
Metadaten
Titel
Tri-component bio-composite materials prepared using an eco-friendly processing route
verfasst von
Rasike De Silva
Xungai Wang
Nolene Byrne
Publikationsdatum
01.10.2013
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 5/2013
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-013-0014-4

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