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Published in: Rare Metals 6/2021

25-11-2020 | Review

A review on Ti3C2Tx-based nanomaterials: synthesis and applications in gas and humidity sensors

Authors: Qiu-Ni Zhao, Ya-Jie Zhang, Zai-Hua Duan, Si Wang, Can Liu, Ya-Dong Jiang, Hui-Ling Tai

Published in: Rare Metals | Issue 6/2021

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Abstract

Ti3C2Tx, which is a novel two-dimensional (2D) material, has received enormous interest in the field of sensor technology due to its large surface area, excellent electrical conductivity, and abundant active surface sites. In recent years, several Ti3C2Tx-based gases and humidity sensors have been developed and reported. In this review, we focus on the latest applications of Ti3C2Tx-based nanomaterials in gas and humidity sensors. First, the synthesis of Ti3C2Tx from the dangerous fluorine-containing etching process to the safe fluorine-free preparation method was discussed, and the structures of the Ti3C2Tx controlled by different delamination methods were also outlined. Subsequently, the functionalization of pristine Ti3C2Tx and composite strategies for enhancing its gas and humidity sensing performance were reviewed. In addition, the gas and humidity sensing mechanisms of sensors based on Ti3C2Tx were also summarized. Finally, the challenges and opportunities for the use of Ti3C2Tx gas and humidity sensors were discussed to provide guidance on the promising potential of Ti3C2Tx in this field.

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Literature
[1]
go back to reference Zhang YJ, Zhang JX, Jiang YD, Duan ZH, Liu BH, Zhao QN, Wang S, Yuan Z, Tai HL. Ultrasensitive flexible NH3 gas sensor based on polyaniline/SrGe4O9 nanocomposite with ppt-level detection ability at room temperature. Sens Actuators B Chem. 2020;319:128293. Zhang YJ, Zhang JX, Jiang YD, Duan ZH, Liu BH, Zhao QN, Wang S, Yuan Z, Tai HL. Ultrasensitive flexible NH3 gas sensor based on polyaniline/SrGe4O9 nanocomposite with ppt-level detection ability at room temperature. Sens Actuators B Chem. 2020;319:128293.
[2]
go back to reference Zhao QN, Duan ZH, Yuan Z, Li X, Wang S, Liu BH, Zhang YJ, Jiang YD, Tai HL. High performance ethylene sensor based on palladium-loaded tin oxide: application in fruit quality detection. Chin Chem Lett. 2020;31(8):2045. Zhao QN, Duan ZH, Yuan Z, Li X, Wang S, Liu BH, Zhang YJ, Jiang YD, Tai HL. High performance ethylene sensor based on palladium-loaded tin oxide: application in fruit quality detection. Chin Chem Lett. 2020;31(8):2045.
[4]
go back to reference Tai HL, Duan ZH, Wang Y, Wang S, Jiang YD. Paper-based sensors for gas, humidity, and strain detections: a review. ACS Appl Mater Interfaces. 2020;12(28):31037. Tai HL, Duan ZH, Wang Y, Wang S, Jiang YD. Paper-based sensors for gas, humidity, and strain detections: a review. ACS Appl Mater Interfaces. 2020;12(28):31037.
[5]
go back to reference Tu HL, Zhao HB, Wei F, Zhang QZ, Fan YY, Du J. Research progress in advanced sensing materials and related devices. Chin J Rare Met. 2019;43(1):1. Tu HL, Zhao HB, Wei F, Zhang QZ, Fan YY, Du J. Research progress in advanced sensing materials and related devices. Chin J Rare Met. 2019;43(1):1.
[6]
go back to reference Zhang YJ, Zeng W. New insight into gas sensing performance of nanoneedle-assembled and nanosheet-assembled hierarchical NiO nanoflowers. Mater Lett. 2017;195:217. Zhang YJ, Zeng W. New insight into gas sensing performance of nanoneedle-assembled and nanosheet-assembled hierarchical NiO nanoflowers. Mater Lett. 2017;195:217.
[7]
go back to reference Zhao QN, Yuan Z, Duan ZH, Jiang YD, Li X, Li ZM, Tai HL. An ingenious strategy for improving humidity sensing properties of multi-walled carbon nanotubes via poly-l-lysine modification. Sens Actuators B Chem. 2019;289:182. Zhao QN, Yuan Z, Duan ZH, Jiang YD, Li X, Li ZM, Tai HL. An ingenious strategy for improving humidity sensing properties of multi-walled carbon nanotubes via poly-l-lysine modification. Sens Actuators B Chem. 2019;289:182.
[8]
go back to reference Zhang YJ, Zeng W, Li YQ. New insight into gas sensing performance of nanorods assembled and nanosheets assembled hierarchical WO3·H2O structures. Mater Lett. 2018;235:49. Zhang YJ, Zeng W, Li YQ. New insight into gas sensing performance of nanorods assembled and nanosheets assembled hierarchical WO3·H2O structures. Mater Lett. 2018;235:49.
[9]
go back to reference Xu YS, Zheng LL, Yang C, Zheng W, Liu XH, Zhang J. Oxygen vacancies enabled porous SnO2 thin films for highly sensitive detection of triethylamine at room temperature. ACS Appl Mater Interfaces. 2020;12(18):20704. Xu YS, Zheng LL, Yang C, Zheng W, Liu XH, Zhang J. Oxygen vacancies enabled porous SnO2 thin films for highly sensitive detection of triethylamine at room temperature. ACS Appl Mater Interfaces. 2020;12(18):20704.
[10]
go back to reference Li J, Lu YJ, Ye Q, Cinke M, Han J, Meyyappan M. Carbon nanotube sensors for gas and organic vapor detection. Nano Lett. 2003;3(7):929. Li J, Lu YJ, Ye Q, Cinke M, Han J, Meyyappan M. Carbon nanotube sensors for gas and organic vapor detection. Nano Lett. 2003;3(7):929.
[11]
go back to reference Zhang YJ, Zeng W, Li YQ. Porous MoS2 microspheres decorated with Cu2O nanoparticles for ammonia sensing property. Mater Lett. 2019;241:223. Zhang YJ, Zeng W, Li YQ. Porous MoS2 microspheres decorated with Cu2O nanoparticles for ammonia sensing property. Mater Lett. 2019;241:223.
[12]
go back to reference Zhang YJ, Zeng W, Li YQ. Hydrothermal synthesis and controlled growth of hierarchical 3D flower-like MoS2 nanospheres assisted with CTAB and their NO2 gas sensing properties. Appl Surf Sci. 2018;455:276. Zhang YJ, Zeng W, Li YQ. Hydrothermal synthesis and controlled growth of hierarchical 3D flower-like MoS2 nanospheres assisted with CTAB and their NO2 gas sensing properties. Appl Surf Sci. 2018;455:276.
[13]
go back to reference Zhao QN, He ZZ, Jiang YD, Yuan Z, Wu HR, Su CL, Tai HL. Enhanced acetone-sensing properties of PEI thin film by GO-NH2 functional groups modification at room temperature. Front Mater. 2019;5:82. Zhao QN, He ZZ, Jiang YD, Yuan Z, Wu HR, Su CL, Tai HL. Enhanced acetone-sensing properties of PEI thin film by GO-NH2 functional groups modification at room temperature. Front Mater. 2019;5:82.
[14]
go back to reference Chen XW, Wang S, Su C, Han YT, Zou C, Zeng M, Hu NT, Su YJ, Zhou ZH, Yang Z. Two-dimensional Cd-doped porous Co3O4 nanosheets for enhanced room-temperature NO2 sensing performance. Sens Actuators B Chem. 2020;305:127393. Chen XW, Wang S, Su C, Han YT, Zou C, Zeng M, Hu NT, Su YJ, Zhou ZH, Yang Z. Two-dimensional Cd-doped porous Co3O4 nanosheets for enhanced room-temperature NO2 sensing performance. Sens Actuators B Chem. 2020;305:127393.
[16]
go back to reference Zhang YJ, Zeng W, Li YQ. The hydrothermal synthesis of 3D hierarchical porous MoS2 microspheres assembled by nanosheets with excellent gas sensing properties. J Alloys Compd. 2018;749:355. Zhang YJ, Zeng W, Li YQ. The hydrothermal synthesis of 3D hierarchical porous MoS2 microspheres assembled by nanosheets with excellent gas sensing properties. J Alloys Compd. 2018;749:355.
[17]
go back to reference Tai HL, Duan ZH, He ZZ, Li X, Xu JL, Liu BH, Jiang YD. Enhanced ammonia response of Ti3C2T nanosheets supported by TiO2 nanoparticles at room temperature. Sens Actuators B Chem. 2019;298:126874. Tai HL, Duan ZH, He ZZ, Li X, Xu JL, Liu BH, Jiang YD. Enhanced ammonia response of Ti3C2T nanosheets supported by TiO2 nanoparticles at room temperature. Sens Actuators B Chem. 2019;298:126874.
[18]
go back to reference Fowler JD, Allen MJ, Tung VJ, Yang Y, Kaner RB, Weiller BH. Practical chemical sensors from chemically derived graphene. ACS Nano. 2009;3(2):301. Fowler JD, Allen MJ, Tung VJ, Yang Y, Kaner RB, Weiller BH. Practical chemical sensors from chemically derived graphene. ACS Nano. 2009;3(2):301.
[19]
go back to reference Gupta Chatterjee S, Chatterjee S, Ray AK, Chakraborty AK. Graphene–metal oxide nanohybrids for toxic gas sensor: a review. Sens Actuators B Chem. 2015;221:1170. Gupta Chatterjee S, Chatterjee S, Ray AK, Chakraborty AK. Graphene–metal oxide nanohybrids for toxic gas sensor: a review. Sens Actuators B Chem. 2015;221:1170.
[20]
go back to reference Tyagi D, Wang HD, Huang WC, Hu LP, Tang YF, Guo ZN, Ouyang ZB, Zhang H. Recent advances in two-dimensional-material-based sensing technology toward health and environmental monitoring applications. Nanoscale. 2020;12(6):3535. Tyagi D, Wang HD, Huang WC, Hu LP, Tang YF, Guo ZN, Ouyang ZB, Zhang H. Recent advances in two-dimensional-material-based sensing technology toward health and environmental monitoring applications. Nanoscale. 2020;12(6):3535.
[21]
go back to reference Fan YY, Tu HL, Pang Y, Wei F, Zhao HB, Yang Y, Ren TL. Au-decorated porous structure graphene with enhanced sensing performance for low-concentration NO2 detection. Rare Met. 2020;39(6):651. Fan YY, Tu HL, Pang Y, Wei F, Zhao HB, Yang Y, Ren TL. Au-decorated porous structure graphene with enhanced sensing performance for low-concentration NO2 detection. Rare Met. 2020;39(6):651.
[22]
go back to reference Subhan F, Khan I, Hong J. Two-dimensional graphitic carbon nitride (g-C4N3) for superior selectivity of multiple toxic gases (CO, NO2, and NH3). Nanotechnology. 2020;31(14):145501. Subhan F, Khan I, Hong J. Two-dimensional graphitic carbon nitride (g-C4N3) for superior selectivity of multiple toxic gases (CO, NO2, and NH3). Nanotechnology. 2020;31(14):145501.
[23]
go back to reference Abbas AN, Liu BL, Chen L, Ma YQ, Cong S, Aroonyadet N, Köpf M, Nilges T, Zhou CW. Black phosphorus gas sensors. ACS Nano. 2015;9(5):5618. Abbas AN, Liu BL, Chen L, Ma YQ, Cong S, Aroonyadet N, Köpf M, Nilges T, Zhou CW. Black phosphorus gas sensors. ACS Nano. 2015;9(5):5618.
[24]
go back to reference Naguib M, Kurtoglu M, Presser V, Lu J, Niu JJ, Heon M, Hultman L, Gogotsi Y, Barsoum MW. Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv Mater. 2011;23(37):4248. Naguib M, Kurtoglu M, Presser V, Lu J, Niu JJ, Heon M, Hultman L, Gogotsi Y, Barsoum MW. Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv Mater. 2011;23(37):4248.
[25]
go back to reference Zhang YJ, Wang L, Zhang NN, Zhou ZJ. Adsorptive environmental applications of MXene nanomaterials: a review. RSC Adv. 2018;8(36):19895. Zhang YJ, Wang L, Zhang NN, Zhou ZJ. Adsorptive environmental applications of MXene nanomaterials: a review. RSC Adv. 2018;8(36):19895.
[26]
go back to reference Zhu J, Ha E, ZhaoL G, Zhou Y, Huang D, Yue G, Hu LS, Sun N, Wang Y, Lee LYS, Xu C, Wong KY, Astric D, Zhao PX. Recent advance in MXenes: a promising 2D material for catalysis, sensor and chemical adsorption. Coordin Chem Rev. 2017;352:306. Zhu J, Ha E, ZhaoL G, Zhou Y, Huang D, Yue G, Hu LS, Sun N, Wang Y, Lee LYS, Xu C, Wong KY, Astric D, Zhao PX. Recent advance in MXenes: a promising 2D material for catalysis, sensor and chemical adsorption. Coordin Chem Rev. 2017;352:306.
[27]
go back to reference Malaki M, Maleki A, Varma RS. MXenes and ultrasonication. J Mater Chem A. 2019;7(18):10843. Malaki M, Maleki A, Varma RS. MXenes and ultrasonication. J Mater Chem A. 2019;7(18):10843.
[28]
go back to reference Lee E, Kim DJ. Review—recent exploration of two-dimensional MXenes for gas sensing: from a theoretical to an experimental view. J Electrochem Soc. 2020;167(3):037515. Lee E, Kim DJ. Review—recent exploration of two-dimensional MXenes for gas sensing: from a theoretical to an experimental view. J Electrochem Soc. 2020;167(3):037515.
[29]
go back to reference Soleymaniha M, Shahbazi MA, Rafieerad AR, Maleki A, Amiri A. Promoting role of MXene nanosheets in biomedical sciences: therapeutic and biosensing innovations. Adv Healthc Mater. 2019;8(1):1801137. Soleymaniha M, Shahbazi MA, Rafieerad AR, Maleki A, Amiri A. Promoting role of MXene nanosheets in biomedical sciences: therapeutic and biosensing innovations. Adv Healthc Mater. 2019;8(1):1801137.
[30]
go back to reference Lee E, VahidMohammadi A, Yoon YS, Beidaghi M, Kim DJ. Two-dimensional vanadium carbide MXene for gas sensors with ultrahigh sensitivity toward nonpolar gases. ACS Sens. 2019;4(6):1603. Lee E, VahidMohammadi A, Yoon YS, Beidaghi M, Kim DJ. Two-dimensional vanadium carbide MXene for gas sensors with ultrahigh sensitivity toward nonpolar gases. ACS Sens. 2019;4(6):1603.
[31]
go back to reference Liu F, Liu Y, Zhao X, Liu X, Fan LZ. Pursuit of a high-capacity and long-life Mg-storage cathode by tailoring sandwich-structured MXene@carbon nanosphere composites. J Mater Chem A. 2019;7(28):16712. Liu F, Liu Y, Zhao X, Liu X, Fan LZ. Pursuit of a high-capacity and long-life Mg-storage cathode by tailoring sandwich-structured MXene@carbon nanosphere composites. J Mater Chem A. 2019;7(28):16712.
[32]
go back to reference Halim J, Cook KM, Naguib M, Eklund P, Gogotsi Y, Rosen J, Barsoum MW. X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes). Appl Surf Sci. 2016;362:406. Halim J, Cook KM, Naguib M, Eklund P, Gogotsi Y, Rosen J, Barsoum MW. X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes). Appl Surf Sci. 2016;362:406.
[33]
go back to reference Kim SJ, Koh HJ, Ren CE, Kwon O, Maleski K, Cho SY, Anasori B, Kim CK, Choi YK, Kim J, Gogotsi Y, Jung HT. Metallic Ti3C2Tx MXene gas sensors with ultrahigh signal-to-noise ratio. ACS Nano. 2018;12(2):986. Kim SJ, Koh HJ, Ren CE, Kwon O, Maleski K, Cho SY, Anasori B, Kim CK, Choi YK, Kim J, Gogotsi Y, Jung HT. Metallic Ti3C2Tx MXene gas sensors with ultrahigh signal-to-noise ratio. ACS Nano. 2018;12(2):986.
[34]
go back to reference Yang ZJ, Liu A, Wang CL, Liu FM, He JM, Li SQ, Wang J, You R, Yan X, Sun P, Duan Y, Lu GY. Improvement of gas and humidity sensing properties of organ-like MXene by alkaline treatment. ACS Sens. 2019;4(5):1261. Yang ZJ, Liu A, Wang CL, Liu FM, He JM, Li SQ, Wang J, You R, Yan X, Sun P, Duan Y, Lu GY. Improvement of gas and humidity sensing properties of organ-like MXene by alkaline treatment. ACS Sens. 2019;4(5):1261.
[35]
go back to reference Lin H, Chen Y, Shi JL. Insights into 2D MXenes for versatile biomedical applications: current advances and challenges ahead. Adv Sci. 2018;5(10):1800518. Lin H, Chen Y, Shi JL. Insights into 2D MXenes for versatile biomedical applications: current advances and challenges ahead. Adv Sci. 2018;5(10):1800518.
[36]
go back to reference Wang HW, Naguib M, Page K, Wesolowski DJ, Gogotsi Y. Resolving the structure of Ti3C2Tx MXenes through multilevel structural modeling of the atomic pair distribution function. Chem Mater. 2015;28(1):349. Wang HW, Naguib M, Page K, Wesolowski DJ, Gogotsi Y. Resolving the structure of Ti3C2Tx MXenes through multilevel structural modeling of the atomic pair distribution function. Chem Mater. 2015;28(1):349.
[37]
go back to reference Sang XH, Xie Y, Lin MW, Alhabeb M, Van Aken KL, Gogotsi Y, Kent PRC, Xiao K, Unocic RR. Atomic defects in monolayer titanium carbide (Ti3C2Tx) MXene. ACS Nano. 2016;10(10):9193. Sang XH, Xie Y, Lin MW, Alhabeb M, Van Aken KL, Gogotsi Y, Kent PRC, Xiao K, Unocic RR. Atomic defects in monolayer titanium carbide (Ti3C2Tx) MXene. ACS Nano. 2016;10(10):9193.
[38]
go back to reference Hope MA, Forse AC, Griffith KJ, Lukatskaya MR, Ghidiu M, Gogotsi Y, Grey CP. NMR reveals the surface functionalisation of Ti3C2 MXene. Phys Chem Chem Phys. 2016;18(7):5099. Hope MA, Forse AC, Griffith KJ, Lukatskaya MR, Ghidiu M, Gogotsi Y, Grey CP. NMR reveals the surface functionalisation of Ti3C2 MXene. Phys Chem Chem Phys. 2016;18(7):5099.
[39]
go back to reference Tang Q, Zhou Z. Graphene-analogous low-dimensional materials. Prog Mater Sci. 2013;58(8):1244. Tang Q, Zhou Z. Graphene-analogous low-dimensional materials. Prog Mater Sci. 2013;58(8):1244.
[40]
go back to reference Sun ZM, Music D, Ahuja R, Li S, Schneider JM. Bonding and classification of nanolayered ternary carbides. Phys Rev B. 2004;20(9):2516. Sun ZM, Music D, Ahuja R, Li S, Schneider JM. Bonding and classification of nanolayered ternary carbides. Phys Rev B. 2004;20(9):2516.
[41]
go back to reference Wang XF, Kajiyama S, Iinuma H, Hosono E, Oro S, Moriguchi I, Okubo M, Yamada A. Pseudocapacitance of MXene nanosheets for high-power sodium-ion hybrid capacitors. Nat Commun. 2015;6:6544. Wang XF, Kajiyama S, Iinuma H, Hosono E, Oro S, Moriguchi I, Okubo M, Yamada A. Pseudocapacitance of MXene nanosheets for high-power sodium-ion hybrid capacitors. Nat Commun. 2015;6:6544.
[42]
go back to reference Xiao Y, Hwang JY, Sun YK. Transition metal carbide-based materials: synthesis and applications in electrochemical energy storage. J Mater Chem A. 2016;4(27):10379. Xiao Y, Hwang JY, Sun YK. Transition metal carbide-based materials: synthesis and applications in electrochemical energy storage. J Mater Chem A. 2016;4(27):10379.
[43]
go back to reference Naguib M, Mashtalir O, Carle J, Presser V, Lu J, Hultman L, Gogotsi Y, Barsoum MW. Two-dimensional transition metal carbides. ACS Nano. 2012;6(2):1322. Naguib M, Mashtalir O, Carle J, Presser V, Lu J, Hultman L, Gogotsi Y, Barsoum MW. Two-dimensional transition metal carbides. ACS Nano. 2012;6(2):1322.
[44]
go back to reference Ghidiu M, Lukatskaya MR, Zhao MQ, Gogotsi Y, Barsoum MW. Conductive two-dimensional titanium carbide 'clay' with high volumetric capacitance. Nature. 2014;516(7529):78. Ghidiu M, Lukatskaya MR, Zhao MQ, Gogotsi Y, Barsoum MW. Conductive two-dimensional titanium carbide 'clay' with high volumetric capacitance. Nature. 2014;516(7529):78.
[45]
go back to reference Lipatov A, Alhabeb M, Lukatskaya MR, Boson A, Gogotsi Y, Sinitskii A. Effect of synthesis on quality, electronic properties and environmental stability of individual monolayer Ti3C2 MXene flakes. Adv Electron Mater. 2016;2(12):1600255. Lipatov A, Alhabeb M, Lukatskaya MR, Boson A, Gogotsi Y, Sinitskii A. Effect of synthesis on quality, electronic properties and environmental stability of individual monolayer Ti3C2 MXene flakes. Adv Electron Mater. 2016;2(12):1600255.
[46]
go back to reference Li TF, Yao LL, Liu QL, Gu JJ, Luo RC, Li JH, Yan XD, Wang WQ, Liu P, Chen B, Zhang W, Abbas W, Naz R, Zhang D. Fluorine-free synthesis of high-purity Ti3C2Tx (T = OH, O) via alkali treatment. Angew Chem Int Ed Engl. 2018;57(21):6115. Li TF, Yao LL, Liu QL, Gu JJ, Luo RC, Li JH, Yan XD, Wang WQ, Liu P, Chen B, Zhang W, Abbas W, Naz R, Zhang D. Fluorine-free synthesis of high-purity Ti3C2Tx (T = OH, O) via alkali treatment. Angew Chem Int Ed Engl. 2018;57(21):6115.
[47]
go back to reference Li GN, Tan L, Zhang YM, Wu BH, Li L. Highly efficiently delaminated single-layered MXene nanosheets with large lateral size. Langmuir. 2017;33(36):9000. Li GN, Tan L, Zhang YM, Wu BH, Li L. Highly efficiently delaminated single-layered MXene nanosheets with large lateral size. Langmuir. 2017;33(36):9000.
[48]
go back to reference Xiong DB, Li XF, Bai ZM, Lu SG. Recent advances in layered Ti3C2Tx MXene for electrochemical energy storage. Small. 2018;14(17):1703419. Xiong DB, Li XF, Bai ZM, Lu SG. Recent advances in layered Ti3C2Tx MXene for electrochemical energy storage. Small. 2018;14(17):1703419.
[49]
go back to reference Mishra A, Srivastava P, Carreras A, Tanaka I, Mizuseki H, Lee KR, Singh AK. Atomistic origin of phase stability in oxygen-functionalized MXene: a comparative study. J Phys Chem C. 2017;121(34):18947. Mishra A, Srivastava P, Carreras A, Tanaka I, Mizuseki H, Lee KR, Singh AK. Atomistic origin of phase stability in oxygen-functionalized MXene: a comparative study. J Phys Chem C. 2017;121(34):18947.
[50]
go back to reference Lipatov A, Lu H, Alhabeb M, Anasori B, Gruverman A, Gogotsi Y, Sinitskii A. Elastic properties of 2D Ti3C2Tx MXene monolayers and bilayers. Sci Adv. 2018;4(6):eaat0491. Lipatov A, Lu H, Alhabeb M, Anasori B, Gruverman A, Gogotsi Y, Sinitskii A. Elastic properties of 2D Ti3C2Tx MXene monolayers and bilayers. Sci Adv. 2018;4(6):eaat0491.
[51]
go back to reference Mashtalir O, Naguib M, Mochalin VN, Dall'Agnese Y, Heon M, Barsoum MW, Gogotsi Y. Intercalation and delamination of layered carbides and carbonitrides. Nat Commun. 2013;4:1716. Mashtalir O, Naguib M, Mochalin VN, Dall'Agnese Y, Heon M, Barsoum MW, Gogotsi Y. Intercalation and delamination of layered carbides and carbonitrides. Nat Commun. 2013;4:1716.
[52]
go back to reference Zang XB, Wang JL, Qin YJ, Wang T, He CP, Shao QG, Zhu HW, Cao N. Enhancing capacitance performance of Ti3C2Tx MXene as electrode materials of supercapacitor: from controlled preparation to composite structure construction. Nano Micro Lett. 2020;12(1):1. Zang XB, Wang JL, Qin YJ, Wang T, He CP, Shao QG, Zhu HW, Cao N. Enhancing capacitance performance of Ti3C2Tx MXene as electrode materials of supercapacitor: from controlled preparation to composite structure construction. Nano Micro Lett. 2020;12(1):1.
[53]
go back to reference Sugahara A, Ando Y, Kajiyama S, Yazawa K, Gotoh K, Otani M, Okubo M, Yamada A. Negative dielectric constant of water confined in nanosheets. Nat Commun. 2019;10(1):850. Sugahara A, Ando Y, Kajiyama S, Yazawa K, Gotoh K, Otani M, Okubo M, Yamada A. Negative dielectric constant of water confined in nanosheets. Nat Commun. 2019;10(1):850.
[54]
go back to reference Gao LF, Li C, Huang WH, Mei S, Lin H, Ou Q, Zhang Y, Guo J, Zhang F, Xu SX, Zhang H. MXene/polymer membranes: synthesis, properties, and emerging applications. Chem Mater. 2020;32(5):1703. Gao LF, Li C, Huang WH, Mei S, Lin H, Ou Q, Zhang Y, Guo J, Zhang F, Xu SX, Zhang H. MXene/polymer membranes: synthesis, properties, and emerging applications. Chem Mater. 2020;32(5):1703.
[55]
go back to reference Halim J, Lukatskaya MR, Cook KM, Lu J, Smith CR, Naslund LA, May SJ, Hultman L, Gogotsi Y, Eklund P, Barsoum MW. Transparent conductive two-dimensional titanium carbide epitaxial thin films. Chem Mater. 2014;26(7):2374. Halim J, Lukatskaya MR, Cook KM, Lu J, Smith CR, Naslund LA, May SJ, Hultman L, Gogotsi Y, Eklund P, Barsoum MW. Transparent conductive two-dimensional titanium carbide epitaxial thin films. Chem Mater. 2014;26(7):2374.
[56]
go back to reference Wang BX, Zhou AG, Liu FF, Cao JL, Wang LB, Hu QK. Carbon dioxide adsorption of two-dimensional carbid MXenes. J Adv Ceram. 2018;7(3):237. Wang BX, Zhou AG, Liu FF, Cao JL, Wang LB, Hu QK. Carbon dioxide adsorption of two-dimensional carbid MXenes. J Adv Ceram. 2018;7(3):237.
[57]
go back to reference Wang X, Garnero C, Rochard G, Magne D, Morisset S, Hurand S, Chartier P, Rousseau J, Cabioc'h T, Coutanceau C, Mauchamp V, Célérier S. A new etching environment (FeF3/HCl) for the synthesis of two-dimensional titanium carbide MXenes: a route towards selective reactivity vs. water. J Mater Chem A. 2017;5(41):22012. Wang X, Garnero C, Rochard G, Magne D, Morisset S, Hurand S, Chartier P, Rousseau J, Cabioc'h T, Coutanceau C, Mauchamp V, Célérier S. A new etching environment (FeF3/HCl) for the synthesis of two-dimensional titanium carbide MXenes: a route towards selective reactivity vs. water. J Mater Chem A. 2017;5(41):22012.
[58]
go back to reference Lukatskaya MR, Mashtalir O, Ren CE, Dall'Agnese Y, Rozier P, Taberna PL, Naguib M, Simon P, Barsoum MW, Gogotsi Y. Cation intercalation and high volumetric capacitance of two-dimensional titanium carbide. Science. 2013;341(6153):1502. Lukatskaya MR, Mashtalir O, Ren CE, Dall'Agnese Y, Rozier P, Taberna PL, Naguib M, Simon P, Barsoum MW, Gogotsi Y. Cation intercalation and high volumetric capacitance of two-dimensional titanium carbide. Science. 2013;341(6153):1502.
[59]
go back to reference Wang BL, Zhang H, Wang B, Shen CJ, Zhang CX, Hu QK, Zhou AG, Liu BZ. Synthesis and electrochemical performance of Ti3C2Tx with hydrothermal process. Electron Mater Lett. 2016;12(5):702. Wang BL, Zhang H, Wang B, Shen CJ, Zhang CX, Hu QK, Zhou AG, Liu BZ. Synthesis and electrochemical performance of Ti3C2Tx with hydrothermal process. Electron Mater Lett. 2016;12(5):702.
[60]
go back to reference Feng AH, Yu Y, Wang Y, Jiang F, Yu Y, Mi L, Song LX. Two-dimensional MXene Ti3C2 produced by exfoliation of Ti3AlC2. Mater Des. 2017;114:161. Feng AH, Yu Y, Wang Y, Jiang F, Yu Y, Mi L, Song LX. Two-dimensional MXene Ti3C2 produced by exfoliation of Ti3AlC2. Mater Des. 2017;114:161.
[61]
go back to reference Yang S, Zhang PP, Wang FX, Ricciardulli AG, Lohe MR, Blom PWM, Feng XL. Fluoride-free synthesis of two-dimensional titanium carbide (MXene) using a binary aqueous system. Angew Chem Int Ed Engl. 2018;57(47):15491. Yang S, Zhang PP, Wang FX, Ricciardulli AG, Lohe MR, Blom PWM, Feng XL. Fluoride-free synthesis of two-dimensional titanium carbide (MXene) using a binary aqueous system. Angew Chem Int Ed Engl. 2018;57(47):15491.
[62]
go back to reference Yuan W, Yang K, Peng H, Li F, Yin F. A flexible VOCs sensor based on a 3D Mxene framework with a high sensing performance. J Mater Chem A. 2018;6(37):18116. Yuan W, Yang K, Peng H, Li F, Yin F. A flexible VOCs sensor based on a 3D Mxene framework with a high sensing performance. J Mater Chem A. 2018;6(37):18116.
[63]
go back to reference An H, Habib T, Shah S, Gao H, Patel A, Echols I, Zhao XF, Radovic M, Green MJ, Lutkenhaus JL. Water sorption in MXene/polyelectrolyte multilayers for ultrafast humidity sensing. ACS Appl Nano Mater. 2019;2(2):948. An H, Habib T, Shah S, Gao H, Patel A, Echols I, Zhao XF, Radovic M, Green MJ, Lutkenhaus JL. Water sorption in MXene/polyelectrolyte multilayers for ultrafast humidity sensing. ACS Appl Nano Mater. 2019;2(2):948.
[64]
go back to reference Kim SJ, Choi J, Maleski K, Hantanasirisakul K, Jung HT, Gogotsi Y, Ahn CW. Interfacial assembly of ultrathin functional MXene films. ACS Appl Mater Interfaces. 2019;11(35):32320. Kim SJ, Choi J, Maleski K, Hantanasirisakul K, Jung HT, Gogotsi Y, Ahn CW. Interfacial assembly of ultrathin functional MXene films. ACS Appl Mater Interfaces. 2019;11(35):32320.
[65]
go back to reference Feng WL, Luo H, Wang Y, Zeng SF, Tan YQ, Zhang HB, Peng SM. Ultrasonic assisted etching and delaminating of Ti3C2 Mxene. Ceram Int. 2018;44(6):7084. Feng WL, Luo H, Wang Y, Zeng SF, Tan YQ, Zhang HB, Peng SM. Ultrasonic assisted etching and delaminating of Ti3C2 Mxene. Ceram Int. 2018;44(6):7084.
[66]
go back to reference Alhabeb M, Maleski K, Anasori B, Lelyukh P, Clark L, Sin S, Gogotsi Y. Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti3C2Tx MXene). Chem Mater. 2017;29(18):7633. Alhabeb M, Maleski K, Anasori B, Lelyukh P, Clark L, Sin S, Gogotsi Y. Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti3C2Tx MXene). Chem Mater. 2017;29(18):7633.
[67]
go back to reference Qian A, Seo JY, Shi H, Lee JY, Chung CH. Diverse surface functional groups and electrochemical behavior in dimethyl sulfoxide-delaminated Ti3C2Tx MXene. Chemsuschem. 2018;11(21):3719. Qian A, Seo JY, Shi H, Lee JY, Chung CH. Diverse surface functional groups and electrochemical behavior in dimethyl sulfoxide-delaminated Ti3C2Tx MXene. Chemsuschem. 2018;11(21):3719.
[68]
go back to reference Wang HB, Zhang JF, Wu YP, Huang HJ, Jiang QG. Achieving high-rate capacitance of multi-layer titanium carbide (MXene) by liquid-phase exfoliation through Li-intercalation. Electrochem Commun. 2017;81:48. Wang HB, Zhang JF, Wu YP, Huang HJ, Jiang QG. Achieving high-rate capacitance of multi-layer titanium carbide (MXene) by liquid-phase exfoliation through Li-intercalation. Electrochem Commun. 2017;81:48.
[69]
go back to reference Shahzad F, Alhabeb M, Hatter CB, Anasori B, Hong SM, Koo CM, Gogotsi Y. Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science. 2016;353(6304):1137. Shahzad F, Alhabeb M, Hatter CB, Anasori B, Hong SM, Koo CM, Gogotsi Y. Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science. 2016;353(6304):1137.
[70]
go back to reference Xuan JN, Wang ZQ, Chen YY, Liang DJ, Cheng L, Yang XJ, Liu Z, Ma RZ, Sasaki T, Geng FX. Organic-base-driven intercalation and delamination for the production of functionalized titanium carbide nanosheets with superior photothermal therapeutic performance. Angew Chem Int Ed. 2016;55(47):1456. Xuan JN, Wang ZQ, Chen YY, Liang DJ, Cheng L, Yang XJ, Liu Z, Ma RZ, Sasaki T, Geng FX. Organic-base-driven intercalation and delamination for the production of functionalized titanium carbide nanosheets with superior photothermal therapeutic performance. Angew Chem Int Ed. 2016;55(47):1456.
[71]
go back to reference Zhang CJ, Pinilla S, McEvoy N, Cullen CP, Anasori B, Long E, Park SH, Seral-Ascaso A, Shmeliov A, Krishnan D, Morant C, Liu XH, Duesberg GS, Gogotsi Y, Nicolosi V. Oxidation stability of colloidal two-dimensional titanium carbides (MXenes). Chem Mater. 2017;29(11):4848. Zhang CJ, Pinilla S, McEvoy N, Cullen CP, Anasori B, Long E, Park SH, Seral-Ascaso A, Shmeliov A, Krishnan D, Morant C, Liu XH, Duesberg GS, Gogotsi Y, Nicolosi V. Oxidation stability of colloidal two-dimensional titanium carbides (MXenes). Chem Mater. 2017;29(11):4848.
[72]
go back to reference Lee E, VahidMohammadi A, Prorok BC, Yoon YS, Beidaghi M, Kim DJ. Room temperature gas sensing of two-dimensional titanium carbide (MXene). ACS Appl Mater Interfaces. 2017;9(42):37184. Lee E, VahidMohammadi A, Prorok BC, Yoon YS, Beidaghi M, Kim DJ. Room temperature gas sensing of two-dimensional titanium carbide (MXene). ACS Appl Mater Interfaces. 2017;9(42):37184.
[73]
go back to reference Wu M, He M, Hu QK, Wu QH, Sun G, Xie LL, Zhang ZY, Zhu ZG, Zhou AG. Ti3C2 MXene-based sensors with high selectivity for NH3 detection at room temperature. ACS Sens. 2019;4(10):2763. Wu M, He M, Hu QK, Wu QH, Sun G, Xie LL, Zhang ZY, Zhu ZG, Zhou AG. Ti3C2 MXene-based sensors with high selectivity for NH3 detection at room temperature. ACS Sens. 2019;4(10):2763.
[74]
go back to reference Khakbaz P, Moshayedi M, Hajian S, Soleimani M, Narakathu BB, Bazuin BJ, Pourfath M, Atashbar MZ. Titanium carbide MXene as NH3 sensor: realistic first-principles study. J Phys Chem C. 2019;123(49):29794. Khakbaz P, Moshayedi M, Hajian S, Soleimani M, Narakathu BB, Bazuin BJ, Pourfath M, Atashbar MZ. Titanium carbide MXene as NH3 sensor: realistic first-principles study. J Phys Chem C. 2019;123(49):29794.
[75]
go back to reference Shuck CE, Han M, Maleski K, Hantanasirisakul K, Kim SJ, Choi J, Reil WEB, Gogotsi Y. Effect of Ti3AlC2 MAX phase on structure and properties of resultant Ti3C2Tx MXene. ACS Appl Nano Mater. 2019;2(6):3368. Shuck CE, Han M, Maleski K, Hantanasirisakul K, Kim SJ, Choi J, Reil WEB, Gogotsi Y. Effect of Ti3AlC2 MAX phase on structure and properties of resultant Ti3C2Tx MXene. ACS Appl Nano Mater. 2019;2(6):3368.
[76]
go back to reference Huang S, Mochalin VN. Understanding chemistry of two-dimensional transition metal carbides and carbonitrides (MXenes) with gas analysis. ACS Nano. 2020;14(8):10251. Huang S, Mochalin VN. Understanding chemistry of two-dimensional transition metal carbides and carbonitrides (MXenes) with gas analysis. ACS Nano. 2020;14(8):10251.
[77]
go back to reference Chae Y, Kim SJ, Cho SY, Choi J, Maleski K, Lee BJ, Jung HT, Gogotsi Y, Lee Y, Ahn CW. An investigation into the factors governing the oxidation of two-dimensional Ti3C2 MXene. Nanoscale. 2019;11(17):8387. Chae Y, Kim SJ, Cho SY, Choi J, Maleski K, Lee BJ, Jung HT, Gogotsi Y, Lee Y, Ahn CW. An investigation into the factors governing the oxidation of two-dimensional Ti3C2 MXene. Nanoscale. 2019;11(17):8387.
[78]
go back to reference Dillon AD, Ghidiu MJ, Krick AL, Griggs J, May SJ, Gogotsi Y, Barsoum MW, Fafarman AT. Highly conductive optical quality solution-processed films of 2D titanium carbide. Adv Funct Mater. 2016;26(23):4162. Dillon AD, Ghidiu MJ, Krick AL, Griggs J, May SJ, Gogotsi Y, Barsoum MW, Fafarman AT. Highly conductive optical quality solution-processed films of 2D titanium carbide. Adv Funct Mater. 2016;26(23):4162.
[79]
go back to reference Muckley ES, Naguib M, Ivanov IN. Multi-modal, ultrasensitive, wide-range humidity sensing with Ti3C2 film. Nanoscale. 2018;10(46):21689. Muckley ES, Naguib M, Ivanov IN. Multi-modal, ultrasensitive, wide-range humidity sensing with Ti3C2 film. Nanoscale. 2018;10(46):21689.
[80]
go back to reference Pazniak H, Plugin IA, Loes MJ, Inerbaev TM, Burmistrov IN, Gorshenkov M, Polcak J, Varezhnikov AS, Sommer M, Kuznetsov DV, Bruns M, Fedorov FS, Vorobeva NS, Sinitskii A, Sysoev VV. Partially oxidized Ti3C2Tx MXenes for fast and selective detection of organic vapors at part-per-million concentrations. ACS Appl Nano Mater. 2020;3(4):3195. Pazniak H, Plugin IA, Loes MJ, Inerbaev TM, Burmistrov IN, Gorshenkov M, Polcak J, Varezhnikov AS, Sommer M, Kuznetsov DV, Bruns M, Fedorov FS, Vorobeva NS, Sinitskii A, Sysoev VV. Partially oxidized Ti3C2Tx MXenes for fast and selective detection of organic vapors at part-per-million concentrations. ACS Appl Nano Mater. 2020;3(4):3195.
[81]
go back to reference Sun Q, Wang J, Wang X, Dai J, Wang XS, Fan HC, Wang ZW, Li H, Huang X, Huang W. Treatment-dependent surface chemistry and gas sensing behavior of the thinnest member of titanium carbide MXenes. Nanoscale. 2020;12(32):16987. Sun Q, Wang J, Wang X, Dai J, Wang XS, Fan HC, Wang ZW, Li H, Huang X, Huang W. Treatment-dependent surface chemistry and gas sensing behavior of the thinnest member of titanium carbide MXenes. Nanoscale. 2020;12(32):16987.
[83]
go back to reference Koh HJ, Kim SJ, Maleski K, Cho SY, Kim YJ, Ahn CW, Gogotsi Y, Jung HT. Enhanced selectivity of MXene gas sensors through metal ion intercalation: in situ X-ray diffraction study. ACS Sens. 2019;4(5):1365. Koh HJ, Kim SJ, Maleski K, Cho SY, Kim YJ, Ahn CW, Gogotsi Y, Jung HT. Enhanced selectivity of MXene gas sensors through metal ion intercalation: in situ X-ray diffraction study. ACS Sens. 2019;4(5):1365.
[84]
go back to reference Muckley ES, Naguib M, Wang HW, Vlcek L, Osti NC, Sacci RL, Sang XH, Unocic RR, Xie Y, Tyagi M, Mamontov E, Page KL, Kent PRC, Nanda J, Ivanov IN. Multimodality of structural, electrical, and gravimetric responses of intercalated mxenes to water. ACS Nano. 2017;11(11):11118. Muckley ES, Naguib M, Wang HW, Vlcek L, Osti NC, Sacci RL, Sang XH, Unocic RR, Xie Y, Tyagi M, Mamontov E, Page KL, Kent PRC, Nanda J, Ivanov IN. Multimodality of structural, electrical, and gravimetric responses of intercalated mxenes to water. ACS Nano. 2017;11(11):11118.
[85]
go back to reference Shpigel N, Levi MD, Sigalov S, Mathis TS, Gogotsi Y, Aurbach D. Direct assessment of nanoconfined water in 2D Ti3C2 electrode interspaces by a surface acoustic technique. J Am Chem Soc. 2018;140(28):8910. Shpigel N, Levi MD, Sigalov S, Mathis TS, Gogotsi Y, Aurbach D. Direct assessment of nanoconfined water in 2D Ti3C2 electrode interspaces by a surface acoustic technique. J Am Chem Soc. 2018;140(28):8910.
[86]
go back to reference Zhu ZY, Liu CC, Jibng FX, Liu J, Ma XM, Liu P, Xu JK, Wang L, Huang R. Flexible and lightweight Ti3C2TxMXene@ Pd colloidal nanoclusters paper film as novel H2 sensor. J Hazard Mater. 2020;399:123054. Zhu ZY, Liu CC, Jibng FX, Liu J, Ma XM, Liu P, Xu JK, Wang L, Huang R. Flexible and lightweight Ti3C2TxMXene@ Pd colloidal nanoclusters paper film as novel H2 sensor. J Hazard Mater. 2020;399:123054.
[87]
go back to reference Sun SB, Wang MW, Chang XT, Jiang YC, Zhang DZ, Wang DS, Zhang YL, Lei YH. W18O49/Ti3C2Tx Mxene nanocomposites for highly sensitive acetone gas sensor with low detection limit. Sens Actuators B Chem. 2020;304:127274. Sun SB, Wang MW, Chang XT, Jiang YC, Zhang DZ, Wang DS, Zhang YL, Lei YH. W18O49/Ti3C2Tx Mxene nanocomposites for highly sensitive acetone gas sensor with low detection limit. Sens Actuators B Chem. 2020;304:127274.
[88]
go back to reference Hermawan A, Zhang B, Taufik A, Asakura Y, Hasegawa T, Zhu J, Shi P, Shu Y. CuO nanoparticles/ Ti3C2Tx MXene hybrid nanocomposites for detection of toluene gas. ACS Appl Nano Mater. 2020;3(5):4755. Hermawan A, Zhang B, Taufik A, Asakura Y, Hasegawa T, Zhu J, Shi P, Shu Y. CuO nanoparticles/ Ti3C2Tx MXene hybrid nanocomposites for detection of toluene gas. ACS Appl Nano Mater. 2020;3(5):4755.
[90]
go back to reference Li N, Jiang Y, Zhou CH, Xiao Y, Meng B, Wang Z, Hunag DZ, Xing CY, Peng ZH. High-performance humidity sensor based on urchin-like composite of Ti3C2 MXene-derived TiO2 nanowires. ACS Appl Mater Interfaces. 2019;11(41):38116. Li N, Jiang Y, Zhou CH, Xiao Y, Meng B, Wang Z, Hunag DZ, Xing CY, Peng ZH. High-performance humidity sensor based on urchin-like composite of Ti3C2 MXene-derived TiO2 nanowires. ACS Appl Mater Interfaces. 2019;11(41):38116.
[91]
go back to reference Chen WY, Jiang X, Lai SN, Peroulis D, Stanciu L. Nanohybrids of a MXene and transition metal dichalcogenide for selective detection of volatile organic compounds. Nat Commun. 2020;11(1):1302. Chen WY, Jiang X, Lai SN, Peroulis D, Stanciu L. Nanohybrids of a MXene and transition metal dichalcogenide for selective detection of volatile organic compounds. Nat Commun. 2020;11(1):1302.
[92]
go back to reference Lee SH, Eom W, Shin H, Ambade RB, Bang JH, Kim HW, Han TH. Room-temperature, highly durable Ti3C2Tx MXene/graphene hybrid fibers for NH3 gas sensing. ACS Appl Mater Interfaces. 2020;12(9):10434. Lee SH, Eom W, Shin H, Ambade RB, Bang JH, Kim HW, Han TH. Room-temperature, highly durable Ti3C2Tx MXene/graphene hybrid fibers for NH3 gas sensing. ACS Appl Mater Interfaces. 2020;12(9):10434.
[93]
go back to reference Wang Y, Zhou Y, Wang Y. Humidity activated ionic-conduction formaldehyde sensing of reduced graphene oxide decorated nitrogen-doped MXene/titanium dioxide composite film. Sens Actuators B Chem. 2020;323:128695. Wang Y, Zhou Y, Wang Y. Humidity activated ionic-conduction formaldehyde sensing of reduced graphene oxide decorated nitrogen-doped MXene/titanium dioxide composite film. Sens Actuators B Chem. 2020;323:128695.
[94]
go back to reference Zhao L, Wang K, Wei W, Wang L, Han W. High-performance flexible sensing devices based on polyaniline/MXene nanocomposites. InfoMat. 2019;1(3):407. Zhao L, Wang K, Wei W, Wang L, Han W. High-performance flexible sensing devices based on polyaniline/MXene nanocomposites. InfoMat. 2019;1(3):407.
[95]
go back to reference Li X, Xu JL, Jiang YD, He ZZ, Liu BH, Xie HK, Li H, Li ZM, Wang Y, Tai HL. Toward agricultural ammonia volatilization monitoring: a flexible polyaniline/Ti3C2Tx hybrid sensitive films based gas sensor. Sens Actuators B Chem. 2020;316:128144. Li X, Xu JL, Jiang YD, He ZZ, Liu BH, Xie HK, Li H, Li ZM, Wang Y, Tai HL. Toward agricultural ammonia volatilization monitoring: a flexible polyaniline/Ti3C2Tx hybrid sensitive films based gas sensor. Sens Actuators B Chem. 2020;316:128144.
[96]
go back to reference Wang X, Sun K, Li K, Li X, Gogotsi Y. Ti3C2Tx /PEDOT: PSS hybrid materials for room-temperature methanol sensor. Chin Chem Lett. 2020;31(4):1018. Wang X, Sun K, Li K, Li X, Gogotsi Y. Ti3C2Tx /PEDOT: PSS hybrid materials for room-temperature methanol sensor. Chin Chem Lett. 2020;31(4):1018.
[97]
go back to reference Zhao LJ, Zheng YQ, Wang K, Lv C, Wei W, Wang LL, Han W. Highly stable cross-linked cationic polyacrylamide/Ti3C2Tx MXene nanocomposites for flexible ammonia-recognition devices. Adv Mater Technol. 2020;5(7):2000248. Zhao LJ, Zheng YQ, Wang K, Lv C, Wei W, Wang LL, Han W. Highly stable cross-linked cationic polyacrylamide/Ti3C2Tx MXene nanocomposites for flexible ammonia-recognition devices. Adv Mater Technol. 2020;5(7):2000248.
[98]
go back to reference Liu LX, Chen W, Zhang HB, Wang QW, Guan F, Yu ZZ. Flexible and multifunctional silk textiles with biomimetic leaf-like MXene/silver nanowire nanostructures for electromagnetic interference shielding, humidity monitoring, and self-derived hydrophobicity. Adv Funct Mater. 2019;29(44):1905197. Liu LX, Chen W, Zhang HB, Wang QW, Guan F, Yu ZZ. Flexible and multifunctional silk textiles with biomimetic leaf-like MXene/silver nanowire nanostructures for electromagnetic interference shielding, humidity monitoring, and self-derived hydrophobicity. Adv Funct Mater. 2019;29(44):1905197.
[99]
go back to reference Pomerantseva E, Gogotsi Y. Two-dimensional heterostructures for energy storage. Nat Energy. 2017;2(7):17089. Pomerantseva E, Gogotsi Y. Two-dimensional heterostructures for energy storage. Nat Energy. 2017;2(7):17089.
[101]
go back to reference Zhan XX, Si C, Zhou J, Sun ZM. MXene and MXene-based composites: synthesis, properties and environment-related applications. Nanoscale Horiz. 2020;5(2):235. Zhan XX, Si C, Zhou J, Sun ZM. MXene and MXene-based composites: synthesis, properties and environment-related applications. Nanoscale Horiz. 2020;5(2):235.
[102]
go back to reference Liu YH, Zhang JK, Zhang X, Li YF, Wang JT. Ti3C2Tx filler effect on the proton conduction property of polymer electrolyte membrane. ACS Appl Mater Interfaces. 2016;8(31):20352. Liu YH, Zhang JK, Zhang X, Li YF, Wang JT. Ti3C2Tx filler effect on the proton conduction property of polymer electrolyte membrane. ACS Appl Mater Interfaces. 2016;8(31):20352.
[104]
go back to reference Wu W, Xu J, Tang XW, Xie PW, Liu XH, Xu JS, Zhou H, Zhang D, Fan TX. Two-dimensional nanosheets by rapid and efficient microwave exfoliation of layered materials. Chem Mater. 2018;30(17):5932. Wu W, Xu J, Tang XW, Xie PW, Liu XH, Xu JS, Zhou H, Zhang D, Fan TX. Two-dimensional nanosheets by rapid and efficient microwave exfoliation of layered materials. Chem Mater. 2018;30(17):5932.
[105]
go back to reference Han F, Luo SJ, Xie LY, Zhu JJ, Wei W, Chen X, Liu FW, Chen W, Zhao JL, Dong L, Yu K, Zeng XR, Rao F, Wang L, Huang Y. Boosting the yield of MXene 2D sheets via a facile hydrothermal-assisted intercalation. ACS Appl Mater Interfaces. 2019;11(8):8443. Han F, Luo SJ, Xie LY, Zhu JJ, Wei W, Chen X, Liu FW, Chen W, Zhao JL, Dong L, Yu K, Zeng XR, Rao F, Wang L, Huang Y. Boosting the yield of MXene 2D sheets via a facile hydrothermal-assisted intercalation. ACS Appl Mater Interfaces. 2019;11(8):8443.
[106]
go back to reference Mashtalir O, Cook KM, Mochalin VN, Crowe M, Barsoum MW, Gogotsi Y. Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media. J Mater Chem A. 2014;2(35):14334. Mashtalir O, Cook KM, Mochalin VN, Crowe M, Barsoum MW, Gogotsi Y. Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media. J Mater Chem A. 2014;2(35):14334.
[107]
go back to reference Zhao X, Vashisth A, Prehn E, Sun W, Shah SA, Habib T, Chen YX, Tan ZY, Lutkenhaus JL, Radovic M, Green MJ. Antioxidants unlock shelf-stable Ti3C2Tx (MXene) nanosheet dispersions. Matter. 2019;1(2):513. Zhao X, Vashisth A, Prehn E, Sun W, Shah SA, Habib T, Chen YX, Tan ZY, Lutkenhaus JL, Radovic M, Green MJ. Antioxidants unlock shelf-stable Ti3C2Tx (MXene) nanosheet dispersions. Matter. 2019;1(2):513.
[108]
go back to reference Wang ZG, Yu K, Feng Y, Qi RJ, Ren J, Zhu ZQ. Stabilizing Ti3C2Tx-MXenes with TiOF2 nanospheres intercalation to improve hydrogen evolution reaction and humidity-sensing performance. Appl Surf Sci. 2019;496:143729. Wang ZG, Yu K, Feng Y, Qi RJ, Ren J, Zhu ZQ. Stabilizing Ti3C2Tx-MXenes with TiOF2 nanospheres intercalation to improve hydrogen evolution reaction and humidity-sensing performance. Appl Surf Sci. 2019;496:143729.
Metadata
Title
A review on Ti3C2Tx-based nanomaterials: synthesis and applications in gas and humidity sensors
Authors
Qiu-Ni Zhao
Ya-Jie Zhang
Zai-Hua Duan
Si Wang
Can Liu
Ya-Dong Jiang
Hui-Ling Tai
Publication date
25-11-2020
Publisher
Nonferrous Metals Society of China
Published in
Rare Metals / Issue 6/2021
Print ISSN: 1001-0521
Electronic ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-020-01602-2

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