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Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 24/2019

11-11-2019

Binary strontium–copper oxide nanostructures doped with potassium as electrode material for supercapacitor application

Authors: Hasi Rani Barai, Nasrin Siraj Lopa, Paritosh Barai, Md. Mahbubur Rahman, Ashis K. Sarker, Sang Woo Joo

Published in: Journal of Materials Science: Materials in Electronics | Issue 24/2019

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Abstract

Recently, binary metal-oxide--based electrode materials with and without doping have attracted growing interest for application to supercapacitors (SCs). Herein, we demonstrate the synthesis of a K-doped (ca. 9%) binary Sr–Cu metal oxide (K-SrCu2O2; KSCO) by a simple solid-state reaction with good crystallinity. The KSCO-modified carbon-cloth (CC) electrode showed a wide electrochemical potential window (− 0.2 to 0.8 V) and delivered a specific capacitance (Cs) of 438 F g−1 at 1 A g−1, compared to the low value (14.5 F g−1 at 1 A g−1) for the undoped SrCu2O2 (SCO)-modified electrode. This substantially improved Cs for SCO upon K-doping can be attributed to the increased conductivity, which enhanced the rate of ion intercalation/deintercalation into the tunnels of KSCO. Furthermore, the KSCO-modified electrode exhibited high-electrochemical stability with a capacitance loss of only 10% after 5000 charge–discharge cycles.
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Appendix
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Metadata
Title
Binary strontium–copper oxide nanostructures doped with potassium as electrode material for supercapacitor application
Authors
Hasi Rani Barai
Nasrin Siraj Lopa
Paritosh Barai
Md. Mahbubur Rahman
Ashis K. Sarker
Sang Woo Joo
Publication date
11-11-2019
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 24/2019
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-02500-9

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