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2019 | OriginalPaper | Chapter

7. Coordination/Organometallic Compounds and Composites of Carbon Allotropes

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Authors: Boris Ildusovich Kharisov, Oxana Vasilievna Kharissova

Publisher: Springer International Publishing

Published in: Carbon Allotropes: Metal-Complex Chemistry, Properties and Applications

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Abstract

Metal complexes have a lot of useful applications in organic and organometallic chemistry, catalysis [1], medicine as anticancer pharmaceutics and for drug delivery [2], various biological systems [3], polymers [4] and dyes, separation of isotopes [5], and heavy metals [6], among many other uses. Sometimes they are applied for increasing solubility [7, 8] of classic objects, carbon nanotubes (CNTs), which form bundle-like structures with very complex morphologies with a high number of Van der Waals interactions, causing extremely poor solubility in water or organic solvents. Metal complexes are also able to serve as precursors to fill CNTs with metals [9] or oxides [10], to decorate CNTs with metal nanoparticles [11], as well as to be encapsulated by CNTs [12].

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The image (functionalization possibilities for SWCNTs: (a) defect-group functionalization, (b) covalent sidewall functionalization, (c) noncovalent functionalization with surfactants, (d) noncovalent exohedral functionalization with polymers, and (e) endohedral functionalization) is reproduced with permission of Intech (I.-Y. Jeon, D.W. Chang, N. Ashok Kumar, and J.-B. Baek. Functionalization of Carbon Nanotubes. IntechOpen, 2010, DOI: https://doi.org/10.5772/18396. Available from: https://www.intechopen.com/books/carbon-nanotubes-polymer-nanocomposites/functionalization-of-carbon-nanotubes).

The image above is reproduced with permission of Elsevier Science ( Chemical Physics Letters, 541, 81–84 (2012)).

Porphyrin and phthalocyanine composites with carbon nanotubes will be discussed below in separated sections.

See also information below about other terpyridine complexes, noncovalently attached to CNTs through pyrene moiety.

Reproduced with permission of the Royal Society of Chemistry

Terpyridine-containing complexes can also be covalently attached to CNTs; see above.

The image above is reproduced with permission of Nature ( Nat. Chem. 9(1), 33–38 (2017)).

See chapter above, dedicated to the graphene properties.

The image above is reproduced with permission of the American Chemical Society ( Inorg. Chem., 55(17), 8277–8280 (2016)).

The image above is reproduced with permission of the Elsevier Science ( International Journal of Pharmaceutics, 514(1), 41–51 (2016)).

The image above is reproduced with permission of the Wiley ( Chemistry – A European Journal, 12(2), 376–387 (2005)).

The image above is reproduced with permission of Nature ( Nat. Nanotech., 2, 156–161 (2007)).

The image above is reproduced with permission of the American Chemical Society ( ACS Nano, 9(8), 8194–8205 (2015)).

The image above is reproduced with permission of the Royal Society of Chemistry ( J. Mater. Chem. A, 3, 24,428–24,436 (2015)).

The image above is reproduced with permission of the Wiley ( ChemPhysChem, 16(15), 3214–3232(2015)).

See also the section on the MOF-derived nanocarbons.

UMCM-1 (University of Michigan Cryst. Material-1), a mesoporous material with unprecedented levels of microporosity, arises from the coordination copolymn. of a dicarboxylate and a tricarboxylate linker mediated by Zn. See details in: A crystalline mesoporous coordination copolymer with high microporosity. Angewandte Chemie, International Edition, 2008, 47 (4), 677–680.

HKUST-1 (“Hong Kong University of Science and Technology”) is a metal organic framework (MOF) made up of copper nodes with 1,3,5-benzenetricarboxylic acid struts between them (see http://www.chemtube3d.com/solidstate/MOF-HKUST-1.html). This MOF is frequently used for obtaining graphite hybrid materials ( Langmuir, 2011, 27, 10234–10242).

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Title

Coordination/Organometallic Compounds and Composites of Carbon Allotropes

Book

Carbon Allotropes: Metal-Complex Chemistry, Properties and Applications

Print ISBN: 978-3-030-03504-4

Electronic ISBN: 978-3-030-03505-1

https://doi.org/10.1007/978-3-030-03505-1

DOI

https://doi.org/10.1007/978-3-030-03505-1_7

Authors:

Boris Ildusovich Kharisov
Oxana Vasilievna Kharissova

Publisher